Athabasca Oil Sands Research Articles

Enhanced Catalytic Hydrogenation of Olefins in Sulfur-Rich Naphtha Using Molybdenum Carbide Supported on γ-Al2O3 Spheres under Steam Conditions: Simulating the Hot Separator Stream Process.

Spheres comprising 10 wt.% Mo2C/γ-Al2O3, synthesized through the sucrose route, exhibited unprecedented catalytic activity for olefin hydrogenation within an industrial naphtha feedstock that contained 23 wt.% olefins, as determined by supercritical fluid chromatography (SFC). The catalyst demonstrated resilience to sulfur, exhibiting no discernible deactivation signs over a tested 96 h operational period. The resultant hydrogenated naphtha from the catalytic process contained only 2.5 wt.% olefins when the reaction was conducted at 280 °C and 3.44 × 106 Pa H2, subsequently blended with Athabasca bitumen to meet pipeline specifications for oil transportation. Additionally, the carbide catalyst spheres effectively hydrogenated olefins under steam conditions without experiencing any notable hydrogenation in the aromatics. We propose the supported carbide catalyst as a viable alternative to noble metals, serving as a selective agent for olefin elimination from light petroleum distillates in the presence of steam and sulfur, mitigating the formation of gums and deposits during the transportation of diluted bitumen (dilbit) through pipelines.

Low adsorption affinity of athabasca oil sands naphthenic acid fraction compounds to a peat-mineral mixture

Much of the toxicity in oil sands process-affected water in Athabasca oil sands tailings has been attributed to naphthenic acids (NAs) and associated naphthenic acid fraction compounds (NAFCs). Previous work has characterized the environmental behaviour and fate of these compounds, particularly in the context of constructed treatment wetlands. There is evidence that wetlands can attenuate NAFCs in natural and engineered contexts, but relative contributions of chemical, biotic, and physical adsorption with sequestration require deconvolution. In this work, the objective was to evaluate the extent to which prospective wetland substrate material may adsorb NAFCs using a peat-mineral mix (PMM) sourced from the Athabasca Oil Sands Region (AOSR). The PMM and NAFCs were first mixed and then equilibrated across a range of NAFC concentrations (5–500 mg/L) with moderate ionic strength and hardness (∼200 ppm combined Ca2+ and Mg2+) that approximate wetland water chemistry. Under these experimental conditions, low sorption of NAFCs to PMM was observed, where sorbed concentrations of NAFCs were approximately zero mg/kg at equilibrium. When NAFCs and PMM were mixed and equilibrated together at environmentally relevant concentrations, formula diversity increased more than could be explained by combining constituent spectra. The TOC present in this PMM was largely cellulose-derived, with low levels of thermally recalcitrant carbon (e.g., lignin, black carbon). The apparent enhancement of the concentration and diversity of components in PMM/NAFCs mixtures are likely related to aqueous solubility of some PMM-derived organic materials, as post-hoc combination of dissolved components from PMM and NAFCs cannot replicate enhanced complexity observed when the two components are agitated and equilibrated together.

The impact of reclamation and vegetation removal on compositional and functional attributes of soil microbial communities in the Athabasca Oil Sands Region

Large-scale mining for oil extraction in the boreal forests of Northern Alberta has led to a disturbance footprint of ~900 km2 of land; which must be reclaimed to equivalent land capabilities. Microorganisms are sensitive to anthropogenic disturbances and play an essential role in the cycling of soil nutrients and plant growth, making them potential indicators of ecosystem function. Thus, the objective of this work was to determine the impact of land reclamation on the composition and function of soil microbial communities in the Athabasca Oil Sands Region (AOSR). We evaluated bacterial community composition via high throughput sequencing of 16S rRNA genes and soil functional diversity by community-level physiological profiling (CLPP). The ranges of variability for these factors observed in soils reclaimed with either peat-mineral mix (PMM), forest floor-mineral mix (FFM), or FFM diluted with sand (Sand-FFM), were compared to that of undisturbed reference soils (NS) and a vegetation removed soil (VR). Differences between reclamation soils and natural soils were clearly discernible, with reclamation imposing a more drastic disturbance to the boreal forest than that of removal of vegetation alone. VR changed the structure of the soil microbial community and increased the overall diversity, within-community interactions, and heterogeneity; while reclamation shifted the microbial community structure to an even greater extent, placing it outside the range of natural variability. Among reclamation substrates, FFM showed the highest level of similarity to the range of natural variability and PMM showed the least. Altogether, our findings underscore the profound impact of anthropogenic activities associated with large-scale mining on soil biological activity, microbial communities, and edaphic profiles. These alterations are of such magnitude that they render the affected soils significant divergent from the reference undisturbed boreal forest soil.

Geochemical and microbiological variability of aerobic and anaerobic sediments along a bifurcated sulphate‐saturated brine spring in western Canada

AbstractA tufa mound developed at La Saline Lake, an oxbow of the Athabasca River in the Athabasca Oil Sands deposit of north‐east Alberta, is characterised by an unusual emplacement of a gypsum caprock. This two‐tiered architecture resulted from the bicarbonate‐saturated groundwater flow along Upper Devonian limestone being redirected deeper and encountering the halite–anhydrite dissolution trend within the underlying Middle Devonian Prairie Evaporite Formation, 175 to 200 m below. Migrations up‐section of sulphate‐saturated brine resulted in the gypsum caprock on the tufa mound and discharge of a sulphate‐saturated brine spring with total dissolved solids of ca 80,000 mg/L. The brine spring is bifurcated with flows to the south‐west and north‐west. Calcite–gypsum thrombolytic bottom sediments along the south‐western branch were covered by a halite deposit and subsequently a gypsum crust with a microbial community dominated by the cyanobacteria Coleofasciculus chthonoplastes. The thrombolite contact zone with the halite–gypsum encrustation has a more diversified community with the cyanobacteria Dactylococcopsis. Cyanobacterial mats that wrap around the bulbous gypsum crust protuberances distributed along the brine pool bottom surfaces have significant eukaryotic diversity, represented by the heterotrophic Ochrophyte Paraphysomonas. In contrast, sediments accumulated along the adjacent spring branch flow to the north‐west were thicker and clogged by abundant decomposed and fermented floral debris, unlike the deposit accumulated along the south‐western branch. This resulted in an oxygen‐depleted anaerobic environment dominated by sulphate‐reducing bacteria resulting in a calcite‐rich and sulphate‐starved anaerobic sediment with ca 20% elemental sulphur and emanation of H2S gas.

Towards a high-performance asphalt concrete for extreme climatic conditions using asphaltenes and polyethylene terephthalate fibres

Asphalt pavement experiences various deteriorations in different weather conditions due to the viscoelastic nature of asphalt binder. This study aims to develop a high-performance asphalt concrete (HPAC) for extreme temperature conditions by incorporating waste polyethylene terephthalate (PET) fibres and asphaltenes, a by-product from Alberta oil sands. First, performance of asphalt binder modified with asphaltenes is evaluated according to the Superpave performance grading (PG) system. Next, to improve low-temperature properties, HPAC mixtures modified with PET fibre at percentages of 0.05–0.30% are tested for compactibility to reflect field construction considerations. Then, performance tests including dynamic modulus; indirect tensile strength test at low temperatures; and Hamburg wheel-track at high temperature are conducted for an effective evaluation of the unmodified and modified mixtures that are prepared using a combination of the dry and wet mix methods. Results of binder PG tests reveal that with 12% asphaltenes, the modified binder is suitable for HPAC applications. The mixes with and without PET fibres exhibit similar compactibility and meet air void requirements of a maximum 6%, and incorporating PET fibres increases stiffness by up to 3.3%. Compared with the unmodified mixes, an optimum dosage of 0.15% PET fibre increases fracture energy by up to 27% at −10 °C and enhances tensile strength by up to 18% at 0 °C. The mixture with the optimum dosage also exhibits excellent rut resistance at 60 °C showing no signs of moisture damage sensitivity. As a result, it boasts a remarkable rutting resistance index that is five times higher than that of the control unmodified mix.

Measurement constrained emission estimates of alkylated polycyclic aromatic hydrocarbons in the Canadian Athabasca oil sands region

Alkylated polycyclic aromatic hydrocarbons (APAH) are important contaminants of crude oil production and exhibit similar toxicity to their parent compounds. This study developed an emission inventory of APAH in a major oil sands development region of Alberta, Canada, and validated the inventory with ambient concentration measurements through dispersion modeling. The initial estimate of regional total annual emissions of 21 APAH species was 362 tonnes/year in the last decade, of which 309 and 53 tonnes/year were in particle-bound and gas-phase APAH, respectively. Fugitive dust from oil sands mining activities is the primary source of particle-bound APAH, emitting 274 tonnes/year. Other major sources of APAH include point sources (31), tailings ponds (21), anthropogenic fuel consumption from mine fleet (17), and local transportation (13). The group of species with highest emissions was C1–C4 alkylnaphthalenes (53%), followed by C1–C4 alkylphenanthrenes/anthracenes (19%), C1–C4 fluorenes (13%), and C1–C4 fluoranthenes/pyrenes and C1–C4 benz[a]anthracenes/chrysene/triphenylenes (7% each).CALPUFF dispersion modeling was performed using the APAH emissions as model input. The model-predicted annual average ambient APAH concentrations at 17 monitoring sites were 1%–52% (19% on average) lower than the measurements. Inverse dispersion modeling was then applied to adjust APAH emissions higher by 19% for each of the 21 APAH species, which resulted in a revised estimate of APAH emissions to 431 tonnes/year. With the revised emissions as model input, model bias in the predicted ambient concentration was reduced from −19% to −8%. The model results showed the highest concentrations of APAH were near tailings ponds and open mining faces and downwind areas, with total APAH concentrations being higher than 50 ng/m3.

Modeling below-cloud scavenging of size-resolved particles in GEM-MACHv3.1

Abstract. Below-cloud scavenging (BCS) is the process of aerosol removal from the atmosphere between cloud base and the ground by precipitation (e.g., rain or snow), and affects aerosol number or mass concentrations, size distribution, and lifetime. An accurate representation of precipitation phases is important in treating BCS as the efficiency of aerosol scavenging differs significantly between liquid and solid precipitation. The impact of different representations of BCS on existing model biases was examined through implementing a new aerosol BCS scheme in the Environment and Climate Change Canada (ECCC) air quality prediction model GEM-MACH and comparing it with the existing scavenging scheme in the model. Further, the current GEM-MACH employs a single-phase precipitation for BCS: total precipitation is treated as either liquid or solid depending on a fixed environment temperature threshold. Here, we consider co-existing liquid and solid precipitation phases as they are predicted by the GEM microphysics. GEM-MACH simulations, in a local-area domain over the Athabasca oil sands areas, Canada, are compared with observed precipitation samples, with a focus on the particulate base cation NH4+; acidic anions NO3-, SO4=, HSO3- in precipitation; and observed ambient particulate sulfate, ammonium, and nitrate concentrations. Overall, the introduction of the multi-phase approach and the new scavenging scheme enhances GEM-MACH performance compared to previous methods. Including a multi-phase approach leads to altered SO4= scavenging and impacts the BCS of SO2 into the aqueous phase over the domain. Sulfate biases improved from +46 % to −5 % relative to Alberta Precipitation Quality Monitoring Program wet sulfate observations. At Canadian Air and Precipitation Monitoring Network stations the biases became more negative, from −10 % to −30 % for the tests carried out here. These improvements contrast with prior annual average biases of +200 % for SO4=, indicating enhanced model performance. Improvements in model performance (via scores for correlation coefficient, normalized mean bias, and/or fractional number of model values within a factor of 2 of observations) could also be seen between the base case and the two simulations based on multi-phase partitioning for NO3-, NH4+, and SO4=. Whether or not these improvements corresponded to increases or decreases in NO3- and NH4+ wet deposition varied over the simulation region. The changes were episodic in nature – the most significant changes in wet deposition were likely at specific geographic locations and represent specific cloud precipitation events. The changes in wet scavenging resulted in a higher formation rate and larger concentrations of atmospheric particle sulfate.

In-situ solvents generation enhanced steam assisted gravity drainage (ISSG-SAGD): A low carbon and high-efficiency approach for heavy oil recovery

The primary bottleneck in heavy oil production lies in the significant energy consumption and CO2 emissions associated with steam injection for recovery. To address this challenge, we propose the ISSG-SAGD (in-situ solvent generation enhanced steam assisted gravity drainage) technique. The recovery mechanisms and operational strategies are investigated using a numerical simulation with an Athabasca bitumen reservoir model, affirming the considerable environmental and economic potential of ISSG-SAGD. The results demonstrate that ISSG-SAGD integrates the recovery mechanisms of both SAGP (steam and gas push) and ES-SAGD (expanding solvent SAGD). Moreover, employing cyclic steam injection, maintaining low operating pressure, and initiating ISSG-SAGD at an early stage enable a 33.79 % reduction in steam consumption, a 39 % decrease in average carbon intensity, a 5.40 % increase in oil production, and a 61.28 % rise in net present value compared to conventional SAGD. This study proves that the ISSG-SAGD approach offers a sustainable and efficient alternative for future heavy oil recovery endeavors, addresses the challenges of high energy consumption and carbon emissions, and paves the way towards a green and economically viable future for the heavy oil development.

A Simple Normalized Analytical Model for Oil Production of SAGD Process and Its Applications in Athabasca Oil Sands

Summary Since the late 1980s, when the Alberta Oil Sands Technology and Research Authority Underground Test Facility project first demonstrated the feasibility of the steam-assisted gravity drainage (SAGD) technology, many commercial SAGD projects were brought online in Western Canada. Now, many of these projects have late-life SAGD wells approaching their ultimate SAGD recovery factors. Although these projects have demonstrated highly variable production performance, there is an opportunity to use the industry production data to find what they have in common and develop a normalized SAGD model. For this paper, we collected oil production history from several leading SAGD projects with late-life production in the Athabasca oil sands area and confirmed the three stages in an SAGD project lifespan: chamber rising, chamber spreading, and chamber falling stages. By normalizing the field data, all SAGD projects converged to one type curve, regardless of reservoir quality and operating conditions. Based on this observation, a new simple normalized model is derived to model the bitumen production in a typical SAGD process for Athabasca oil sands. The new model bridges the gap between the existing SAGD analytical model and conventional decline analysis and provides oil production forecasts based on the inputs for the five-component recovery factor method defined in the Canadian Oil and Gas Evaluation Handbook(Society of Petroleum Evaluation Engineers 2018). The model has been applied to one of the thermal projects to history match the field production. By running a Monte Carlo simulation, this model further demonstrates its capability to capture the uncertainty of the production forecast for the project at different stages of SAGD operation. In addition, by properly modifying the type curve of the analytical model, a similar workflow can be used to model cases with special reservoir quality or different operational limitations.

Temporal Assessment of GCM-Driven Hydroclimatic Conditions for the Alberta Oil Sands Region, Canada

Abstract Freshwater supplies in most western Canadian watersheds are threatened by the warming of temperatures because it alters the snow-dominated hydrologic patterns that characterize these cold regions. In this study, we used datasets from 12 climate simulations, which are associated with seven global climate models and four future scenarios and are participating in phase 6 of the Coupled Model Intercomparison Project, to calculate and assess the historical and future temporal patterns of 13 hydroclimate indicators relevant to water resources management. We conducted linear long-term trend and change analyses on their annual time series to provide insight into the potential regional impacts of the detected changes on water availability for all users. We implemented our framework on the Alberta oil sands region in Canada to support the monitoring of environmental changes in this region, relative to the established baseline 1985–2014. Our analysis indicates a persistent increase in the occurrence of extreme hot temperatures, fewer extreme cold temperatures, and an increase in warm spells and heatwaves, while precipitation-related indices show minor changes. Consequently, deficits in regional water availability during summer and water-year periods, as depicted by the standardized precipitation evapotranspiration indices, are expected. The combined effects of the strong climate warming signals and the small increases in precipitation annual amounts generally detected in this study suggest that drier conditions may become severe and frequent in the Alberta oil sands region. The challenging climate change risks identified for this region should therefore be continuously monitored, updated, and integrated to support a sustainable management for all water users.

Biodegradation in oil sands process-affected water: A comprehensive laboratory analysis of the in situ biodegradation of dissolved organic acids

Oil sands process-affected water (OSPW) is a by-product of the extraction of bitumen, and volumes of OSPW have accumulated across the Alberta oil sands region due to the governments zero-discharge policy. Some dissolved organics in OSPW, including toxic naphthenic acids (NAs), can be biodegraded in oxic conditions, thereby reducing the toxicity of OSPW. While there has been much focus on degradation of NAs, the biodegradation of other dissolved organic chemicals by endogenous organisms remains understudied. Here, using the HPLC–ultrahigh resolution Orbitrap mass spectrometry, we examined the microbial biodegradation of dissolved organic acids in OSPW. Non-targeted analysis enabled the estimation of biodegradation rates for unique heteroatomic chemical classes detected in negative ion mode. The microcosm experiments were conducted with and without nutrient supplementation, and the changes in the microbial community over time were investigated. Without added nutrients, internal standard–adjusted intensities of all organics, including NAs, were largely unchanged. The addition of nutrients increased the biodegradation rate of O2− and SO2− chemical classes. While anoxic biodegradation can occur in tailings ponds and end pit lakes, microbial community analyses confirmed that the presence of oxygen stimulated biodegradation of the OSPW samples studied. We detected several aerobic hydrocarbon-degrading microbes (e.g., Pseudomonas and Brevundimonas), and microbes capable of degrading sulfur-containing hydrocarbons (e.g., Microbacterium). Microbial community diversity decreased over time with nutrient addition. Overall, the results from this study indicate that toxic dissolved organics beyond NAs can be biodegraded by endogenous organisms in OSPW, but reaffirms that biological treatment strategies require careful consideration of how nutrients and dissolved oxygen may impact efficacy.

Wetlands as integral parts of surface water–groundwater interactions in the Athabasca Oil Sands Area: Review and synthesis

Wetlands comprise unique water storage and conveyance mechanisms that maintain landscape integrity under the sub-humid climate in the Athabasca Oil Sands Area. In addition to their internal function, wetlands support a two-way hydrological connection to adjacent uplands and provide water for downstream water courses. Understanding the role of wetlands as integral parts of surface water (SW)–groundwater (GW) exchange can provide insights into the functioning of the hydrological system as a whole and contribute to thoughtful water management strategies and better coordination of monitoring efforts in the areas affected by oil sands (OS) activities. As such, this study summarizes the current state of hydrological knowledge on the role of wetlands in SW–GW interactions based on studies conducted within the Western Boreal Plains. In particular, the role of wetland soils and their properties in SW–GW interactions, the effects of wetlands on landscape hydrological connectivity and watershed runoff, and features of “wetland–aquifer” and “wetland–open waterbody” interactions were reviewed. Given that alterations of SW–GW interactions in wetlands can occur as a result of anthropogenic disturbances, the coordination of GW, SW, and wetland monitoring efforts and targeting areas where increased SW–GW exchange occurs would be beneficial for the economic and logistical efficiency of the OS monitoring network.

Establishing peat-forming plant communities: A comparison of wetland reclamation methods in Alberta's oil sands region.

The Sandhill Wetland (SW) and Nikanotee Fen (NF) are two wetland research projects designed to test the viability of peatland reclamation in the Alberta oil sands post-mining landscape. To identify effective approaches for establishing peat-forming vegetation in reclaimed wetlands, we evaluated how plant introduction approaches and water level gradients influence species distribution, plant community development, and the establishment of bryophyte and peatland species richness and cover. Plant introduction approaches included seeding with a Carex aquatilis-dominated seed mix, planting C. aquatilis and Juncus balticus seedlings, and spreading a harvested moss layer transfer. Establishment was assessed 6 years after the introduction at SW and 5 years after the introduction at NF. In total, 51 species were introduced to the reclaimed wetlands, and 122 species were observed after 5 and 6 years. The most abundant species in both reclaimed wetlands was C. aquatilis, which produced dense canopies and occupied the largest water level range of observed plants. Introducing C. aquatilis also helped to exclude marsh plants such as Typha latifolia that has little to no peat accumulation potential. Juncus balticus persisted where the water table was lower and encouraged the formation of a diverse peatland community and facilitated bryophyte establishment. Various bryophytes colonized suitable areas, but the moss layer transfer increased the cover of desirable peat-forming mosses. Communities with the highest bryophyte and peatland species richness and cover (averaging 9 and 14 species, and 50%-160% cover respectively) occurred where the summer water level was between -10 and -40 cm. Outside this water level range, a marsh community of Typha latifolia dominated in standing water and a wet meadow upland community of Calamagrostis canadensis and woody species established where the water table was deeper. Overall, the two wetland reclamation projects demonstrated that establishing peat-forming vascular plants and bryophytes is possible, and community formation is dependent upon water level and plant introduction approaches. Future projects should aim to create microtopography with water tables within 40 cm of the surface and introduce vascular plants such as J. balticus that facilitate bryophyte establishment and support the development of a diverse peatland plant community.

Sources, spatial-distributions and fluxes of PAH-contaminated dusts in the Athabasca oil sands region

Atmospheric deposition of polycyclic aromatic hydrocarbons (PAHs) has increased in northern Alberta, Canada, due to industrial development in the Athabasca oil sands region (AOSR). However, the sources, summertime deposition fluxes and associated spatial patterns are poorly characterized, and the magnitude of contamination has not been directly contrasted with comparable measurements around large Canadian cities. PAHs were measured in Sphagnum moss collected from 30 bogs in the AOSR and compared with reference moss collected from various remote, rural and near-urban sites in Alberta and Ontario. At all 39 locations, strong correlations between depositional fluxes of PAHs and accumulation rates of ash (n = 117, r = 0.877, p < 0.001) implied that the main source of PAHs to moss was atmospheric deposition of particles. Average PAH concentrations at near-field AOSR sites (mean [SD], 62.4 [24.3] ng/g) were significantly higher than at far-field AOSR sites (44.9 [20.8] ng/g; p = 0.038) or the 7 reference sites in Alberta (20.6 [3.5] ng/g; p < 0.001). In fact, average PAH concentrations across the entire AOSR (7,850 km2) were approximately twice as high as in London, Ontario, or near petroleum upgrading and major traffic corridors in Edmonton, Alberta. A chemical mass balance model estimated that both delayed petcoke (33 % of PAHs) and fine tailings (38 % of PAHs) were the major sources of PAHs in the AOSR. Over the 2015 summer growing season, we estimate that 101–110 kg of PAHs (on 14,300–17,300 tonnes of PAH-containing dusts) were deposited to the AOSR within a 50 km radius of surface mining. Given that the highest PAH deposition was to the northern quadrant of the AOSR, which includes the First Nations community of Fort MacKay, further dust control measures should be considered to protect human and environmental health in the region.

Differences in Soil Fungal Communities between Forested Reclamation and Forestry Sites in the Alberta Oil Sands Region.

Fungi play key roles in forest soils and provide benefits to trees via mycorrhizal symbioses. After severe disturbance, forest regrowth can be impeded because of changes in fungal communities. In 2013-2014, soil fungi in forest floor and mineral soil were examined by Roche 454 pyrosequencing in undisturbed, harvested, and burned jack pine stands in a forested area near Fort Chipewyan, Alberta. These fungal communities were compared with jack pine, white spruce, and larch stands in Gateway Hill, a nearby certified reclaimed area. In 2014, a more detailed sampling of forestry and reclamation jack pine sites examined fungi in soil fractions using two high-throughput sequencing platforms and a sporocarp survey. The significances of compositional and functional differences in fungal communities between the forested and reclamation sites were assessed using permutation tests of partially constrained ordinations, accounting for confounding factors by variance partitioning. Taxa associated with the forestry area were primarily ectomycorrhizal. Fungal richness and diversity were greater in soils from the reclamation sites and included significantly more pathogenic taxa and taxa with unknown functional properties. Fungal community dissimilarities may have been artefacts of historical legacies or, alternatively, may have resulted from contrasting niche differentiation between forestry and reclamation sites.

Field intercomparison of continuous ambient FRM and FEM NO2 instruments in the Athabasca Oil Sands Region, Alberta, Canada and the potential impact on ambient regulatory compliance

ABSTRACT The Canadian Federal Government promulgated new and lower NO2 Ambient Air Quality Standards (CAAQS) that went into effect in 2020 with additional decreases scheduled for 2025. The new hourly and annual NO2 CAAQS are 60 and 17 ppb, respectively, and the 2025 hourly and annual CAAQS are 42 and 12 ppb, respectively. The province of Alberta has also promulgated Ambient Air Quality Objectives (AAAQO) for NO2 currently set to 159 and 24 ppb on an hourly and annual basis, respectively. The Wood Buffalo Environmental Association (WBEA) in northeastern Alberta, Canada monitors NO2 at 21 community and industrial sites throughout the Athabasca Oil Sands Region (AOSR), for regulatory compliance using Thermo-Environmental (TEI) Model 42i Federal Reference Method (FRM) designated NO-NO2-NOx analyzers. The 42i measures NO directly via NO-O3 chemiluminescence, and NOx following the reduction of oxidized nitrogen to NO by a heated internal molybdenum converter. The difference between the NOx and NO channels is reported as NO2. This study presents the results of a three-year (2018–2021) WBEA comparison of four continuous NO2 analyzers: TEI 42i FRM; the API Model T500U cavity attenuated phase shift (CAPS) Federal Equivalent Method (FEM); a total reactive odd nitrogen analyzer (TEI Model 42i-Y); and a TEI 42i equipped with an external photolytic converter. The study showed that NO2 data from all analyzers were highly correlated and in general agreement, with r2 values (vs. the CAPS) ranging from 0.990–0.997 and slopes ranging from 0.933–0.992. Mean NO2 concentrations over the study period ranged from 7.2–7.5 ppb. Differences between the TEI 42i, TEI 42i-Y, and PhoNO, relative to the CAPS were all positive and highly significant (p < 0.0001), based upon nonparametric tests. The potential impact from the selection of different FRM/FEM measurement methods on current and future Canadian 2025 regulatory compliance in the region is evaluated. Implications: The study objective was to compare/evaluate different regulatory NO2 measurement techniques from a regional monitoring authority in a routine network operational context. Relatively small NO2 differences resulted in significant differences with respect to regulatory compliance triggers, particularly hourly standards based on daily extreme value statistics (e.g., 99th percentiles). For example, mean hourly NO2 △ differences ranged from 0.02–0.26 ppb over the study period but resulted in 2–3 ppb differences in the 3-year hourly CAAQS metrics. These differences could affect regulatory CAAQS and LARP compliance (management level) at monitoring sites observed during 2019 annual and 2020 hourly LARP trigger exceedances.

Ozone in the boreal forest in the Alberta Oil Sands Region

Abstract. Measurements of ozone were made using an instrumented tower and a tethersonde located in a forested region surrounded by oil sands production facilities in the Athabasca Oil Sands Region (AOSR). Our observations and modeling show that the concentration of ozone was modified by vertical mixing, photochemical reactions, and surface dry deposition. Measurements on the tower demonstrated that when winds are from the direction of anthropogenic emissions from oil sand extraction and processing facilities, there is no significant increase in ozone mixing ratio compared to when winds are from the direction of undisturbed forest. This suggests that ozone is destroyed by reaction with NOx from oil sands extraction operations (as well as NO resulting from photolysis of NO2). Vertical gradients of ozone mixing ratio with height were observed using instruments on a tethered balloon (up to a height of 300 m) as well as a pulley system and two-point gradients within the canopy. Strong gradients (ozone increasing with height near 0.35 ppb m−1) were measured in the canopy in the evening and overnight, while morning and daytime gradients were weaker and highly variable. A 1D canopy model was used to simulate the diurnal variation of the in-canopy gradient. Model results suggest an ozone dry deposition velocity between 0.2 and 0.4 cm s−1 for this location. Sensitivity simulations using the model suggest that the local NO concentration profile and coefficients of vertical diffusivity have a significant influence on the O3 concentrations and profiles in the region.

Climatic controls on the water balance of a pilot-scale oil sands mining pit lake in the Athabasca oil sands region, Canada

ABSTRACT Energy companies in the Athabasca Oil Sands Region in Alberta, Canada are evaluating the viability of incorporating pit lakes into reclamation closure designs to both sequester tailings and re-integrate the mining lease into the broader natural landscape. Lake Miwasin is a pilot-scale oil sands pit lake encompassed by a constructed catchment where the volume of the water cap is not actively managed. This study compared the water balance during the open water season over two consecutive years with contrasting levels of summertime precipitation. The first year had above average rainfall triggering surface water inflow events that diluted the over-winter water volume by ~ 25%. Flushing of the deepest layers of the water column was restricted from May – September as thermal stratification inhibited complete lake mixing. The second year had below average rainfall resulting in minimal surface water inflow and a drop in lake stage of ~ 30 cm. As the constructed catchment lacks both natural water bodies and connectivity to a legacy groundwater system, freshwater additions to the lake during the summer season were governed by rainfall. This research highlights challenges with constructing sustainable reclamation landscapes within a region characterised by variations in interannual and decadal water cycles.

Investigation of Moisture Sensitivity and Cracking Resistance of Granular Base Course Comprised of Tailing Solvent Recovery Unit Materials and Bitumen Froth Derived from Alberta Oil Sands

Investigation of Moisture Sensitivity and Cracking Resistance of Granular Base Course Comprised of Tailing Solvent Recovery Unit Materials and Bitumen Froth Derived from Alberta Oil Sands

Dissolved polycyclic aromatic compounds in Canada’s Athabasca River in relation to Oil Sands from 2013 through 2019

The Canada-Alberta Oil Sands Monitoring (OSM) Program began long-term surface water quality monitoring on the lower Athabasca River in 2012. Sampling of low level, bio-accumulative polycyclic aromatic compounds (PACs) targeted a suite of parent and alkylated compounds in the Athabasca River (AR) mainstem using semi-permeable membrane devices (SPMDs). Samples were collected along a gradient from upstream reference near Athabasca, Alberta, through exposure to the Athabasca oil sands deposit (AOSD), various tributary inflows, and mining activities within the OSMA, to downstream recovery near Wood Buffalo National Park (WBNP) and reference on the Slave River. The program adapted over the years, shifting in response to program review and environmental events. The AOSD chemical fingerprint was present in samples collected within the AOSD, through the oil sands mineable area (OSMA), downstream to recovery from 2013 to 2019. PACs were dominated by alkylated phenanthrenes/anthracenes (PAs) and dibenzothiophenes (Ds), with elevated levels of alkylated fluorenes (Fs), naphthalenes (Ns), fluoranthenes/pyrenes (FlPys) and benzo[a]anthracenes/chrysenes (BaACs), increasing in concentration from C1 < C2 < C3 < C4. Concentrations of these petrogenic PACs were at their highest within the OSMA and downstream of tributaries. The AOSD fingerprint was absent from sites located outside of the influence of the AOSD and downstream of the Peace-Athabasca Delta on the Slave River. PAC concentrations in the AR increased with mainstem discharge and loadings from tributaries, were moderated by the PAD, and diluted by the Peace River. This work bolsters the baseline PAC information previously reported for the Athabasca River and waters downstream, reporting 7 years of data, from all sites within the mainstem monitoring program, and exploring potential regional and hydrological drivers of these between sites and over time.