AISI 316L Steel Research Articles

The Laser Processing of the Stainless-Steel Surface Layer of a Heat Exchanger Membrane in Order to Enhance Its Heat Transfer Coefficient

Research on temperature regulation is essential for ensuring thermal comfort and optimizing machine performance. Effective cooling systems are critical in industrial processes and everyday electronic devices in order to prevent overheating. Laser-modified heat exchangers can enhance heat dissipation without increasing weight, addressing the need for energy-efficient solutions in the market. The main aim of this experimental research was to establish an efficient method for altering the surface layer of AISI 316L stainless steel with laser pulses and to determine the effectiveness of the laser alterations to the surface layer in the context of intensifying the convective heat transfer. A series of laser-texturing processes was performed on the surface layer of AISI 316L steel using a Nd: YAG pulse laser. Selected samples were subjected to a series of measurements using a recuperator-type heat exchanger. Based on the measurements’ results, the heat transfer coefficients, α, obtained from the modified surfaces were determined. The results were compared with other data from the existing literature and those obtained from unmodified reference samples. The intensification of the convective heat transfer was achieved for 43% of the modifications conducted with a pulsed laser. The highest observed average increase in the heat transfer coefficient, α, was 16.53%. However, the effective intensification of the convective heat transfer, in some cases, was only observed for a certain range of temperatures or flow dynamics parameters.

Surface roughness assessment of zinc oxide nanostructures formed on biomedical steel

This investigation explores the effect of hydrothermal time on the topographical characteristics of zinc oxide nanostructures-based coating formed on AISI 316L steel. First, a Zn adhesion layer was deposited and later a ZnO film. Next, the ZnO nanostructures were grown by the hydrothermal method at a temperature of 90 °C for 60 and 120 minutes. Elemental analysis was conducted at the surface and its topographic characteristics were assessed by atomic force microscopy. After images acquisition of the surface of the samples, arithmetic roughness (Ra), root mean square roughness (Rq), kurtosis (Rk) and skewness (Rsk) were determined. The arithmetic roughness Ra varied from ~26 nm to ~41 nm when hydrothermal time increased from 60 to 120 min, whereas Rq increased from ~35 nm to ~53 nm. Regarding the kurtosis and skewness parameters, when varying the hydrothermal time, a decrease in their values was found.

Determination of Diffusion Coefficients of Nickel and Vanadium into Stainless and Duplex Steel and Titanium

When heterogeneous joints are created, problems with the formation of intermetallic phases arise. There are various ways to reduce the formation of intermetallics. One of the ways that is discussed in this article is to use a suitable interlayer of appropriate thickness when forming the joint. A too-thin interlayer does not protect against the formation of brittle intermetallic phases. On the other hand, a too-thick interlayer increases the heterogeneity of the joint and, thus, decreases its useful properties. Within this paper, the formation of diffusion joints between the base material (AISI 304 steel, duplex steel, AISI 316L steel, or titanium grade 2) and the 0.2 mm thick intermediate layer (nickel or vanadium) was studied. Initial diffusion joints were prepared in a Gleeble 3500 machine, and samples for the study of diffusion kinetics were subsequently heat-treated in a vacuum furnace. The result of the research was the determination of specific diffusion parameters of nickel and vanadium into all four tested base materials. The initial diffusion depth (simple heating to the target temperature without holding at this temperature) of nickel was 4.46 µm into duplex steel and 5.48 µm into Ti Gr. 2 at 950 °C. At the same temperature, the initial diffusion depth of vanadium was 14.54 µm into duplex steel and 14.32 µm into Ti Gr. 2. In addition, general equations for the calculation of diffusion coefficients for the mentioned materials in the temperature range of 850 to 1150 °C were established.

Surface morphological studies on hot corrosion behaviour of pre-oxidized plasma sprayed WC-CoCr coating on AISI316L steel in Na2SO4/NaCl molten salt environment

Abstract The hot corrosion behaviour of plasma sprayed WC-CoCr coatings on AISI 316 L steel substrate is studied in two corrosive salt environments namely 100% Na2SO4 and 75% Na2SO4+25%NaCl at 1000 °C. Also, on WC-CoCr coated AISI 316L steel substrate, a persistent Cr2O3 barrier scale is created employing pre-oxidation at 1200 °C for ten hours with the expectation that it would withstand hot corrosion in a Na2SO4 salt environment at 900 °C. X-ray diffraction (XRD), energy dispersive spectroscopy (EDS), electron micro probe analysis (EPMA) and scanning electron microscopy (SEM) are performed on samples to examine the pre oxidation and hot corrosion characteristics of plasma sprayed WC-CoCr coatings at elevated temperatures. The findings indicate that the presence of both salt environment affects the degradation process of WC-CoCr coatings. The coatings in 100% Na2SO4 and the mixture of 75% Na2SO4+25%NaCl has a weight change of 0.14 mg cm−2 and 0.33 mg cm−2, respectively, after hot corrosion at 1000 °C for 50 cycles. Each cycle includes 1 h heating in furnace and 20 min cooling in ambient air. Corrosion kinetics using thermogravimetric method showed that non-pre-oxidized samples gained 52.5% more weight and more severely affected by hot corrosion than pre-oxidized ones. During hot corrosion after 2 h, there was relatively negligible corrosion, but after 4 and 8 h, deposits of Na2WO4, WO3, Cr2O3 and CoSO4 were produced. Oxides were primarily composed of Cr2O3 and WO3. Cr2O3 and WO3 acted as barriers to the penetration and diffusion of corrosive elements through coatings, which contributed to the hot corrosion resistance in the corrosive area. The hot corrosion deterioration of WC-CoCr coatings may be effectively reduced by introducing pre oxidation. Slower reaction rate of pre oxidized Cr2O3 scale may operate as a barrier which separates hot corrosion by Na2SO4 salt.

Barkhausen Noise‐ and Eddy Current‐Based Measurements for Online Detection of Deformation‐Induced Martensite During Flow Forming of Metastable Austenitic Steel AISI 304L

ABSTRACTThis paper deals with micromagnetic measurements for online detection of strain‐induced α′‐martensite during plastic deformation of metastable austenitic steel AISI 304L. The operating principles of the sensors are magnetic Barkhausen noise (MBN) and eddy currents (EC), which are suitable for detection of microstructure evolution due to formation of ferromagnetic phases. The focus of this study was put on the qualification of different micromagnetic techniques and different measurement systems under conditions similar to the real ones during production, which is crucial for implementation of a property‐controlled flow forming process. The investigation was carried out on tubular specimens produced by flow forming, which have different content of α′‐martensite. To characterize the sensitivity of the sensors, different contact conditions between sensors and workpieces were reproduced. MBN sensors are suitable for detecting amount of α′‐martensite, but the measurements are affected by the surface roughness. This entails that the calibration models for MBN sensors must take account of these effects. EC sensors show a closer match with the amount of α′‐martensite without having major affectation by other effects.

POTENTIALITY OF HIGH-SPEED LASER CLADDING (HSLC) PROCESS FOR METAL DEPOSITION IN THE BRAZILIAN SCENARIO

This study explores the potential of High-Speed Laser Cladding (HSLC) within the Brazilian context. Given the nascent stage of HSLC technology in Brazil, preliminary experiments were conducted to assess its technical feasibility. AISI 316L tubes served as substrates for AISI 316L steel coatings, with the thickness of the deposited layers thoroughly analyzed. Results showed consistently continuous and adherent coatings without delamination. The findings suggest that HSLC is well-suited for high-quality, efficient applications in Brazil's oil, mining, and automotive industries, highlighting its potential to meet the demands of these sectors for innovation and precision.

The Influence of the Ratio of Circumference to Cross-Sectional Area of Tensile Bars on the Fatigue Life of Additive Manufactured AISI 316L Steel

The static and dynamic loading capacities of components depend on the stress level to which the material is exposed. The fatigue behavior of materials manufactured using additive technology is accompanied by a pronounced scatter between the number of cycles at the same stress level, which is significantly greater than the scatter from a material with the same chemical composition, e.g., AISI 316L, but produced by rolling or forging. An important reason lies in the fact that fatigue cracks are initiated almost always below the material surface of the loaded specimen. Thus, in the article, assuming that a crack will always initiate below the surface, we analyzed the fatigue behavior of specimens with the same bearing cross section but with a different number of bearing rods. With a larger number of rods, the circumference around the supporting part of the rods was 1.73 times larger. Thus, experimental fatigue of specimens with different sizes showed that the dynamic loading capacity of components with a smaller number of bars is significantly greater and can be monitored by individual stress levels. Although there are no significant differences in loading capacity under static and low-cycle loading of materials manufactured with additive technologies, in high-cycle fatigue it has been shown that the ratio between the circumference and the loading cross section of tensile-loaded rods plays an important role in the lifetime. This finding is important for setting a strategy for manufacturing components with additive technologies. It shows that a better dynamic loading capacity can be obtained with a larger loading cross section.

Electrochemical synthesis, physical properties and corrosion behavior of electropolymerized polyaniline films developed on 316L stainless steel

AbstractPolyaniline (PANI) films may be developed on metallic substrates by a variety of electrochemical techniques. In the present work, PANI films were electrodeposited on AISI 316L stainless steel substrates by cyclic voltammetry (CV), chronoamperometry (CA), and chronopotentiometry (CP) with the objective of comparing the efficacy of each method, based on the integrity of the developed films. Cyclic voltammetry and anodic polarization were used to determine optimal electrodeposition parameters for the development PANI films using the CA and CP methods. The structure and morphology of the coatings were characterized by scanning electron microscopy, energy‐dispersive x‐ray spectroscopy, Fourier‐transform infrared spectroscopy, and ultraviolet–visible spectroscopy. Among the evaluated techniques, CV led to the formation PANI films with the best homogeneity as well as the lowest number of defects, such as cracks or pores. Subsequently, the corrosion resistance of AISI 316L steels with and without PANI was compared in a physiological saline solution (0.9% NaCl). Potentiodynamic polarization tests indicated that the PANI‐coated samples exhibited lower corrosion current density values (0.012 vs. 0.018 μA/cm2) and lower passive current density values (0.04 vs. 0.06 μA/cm2) in comparison to the bare AISI 316L steel. Additionally, long‐term monitoring by electrochemical impedance spectroscopy revealed that PANI films consistently exhibited superior polarization resistance up to 32 days of exposure in the 0.9%NaCl solution (233,000 vs. 207,000 Ωcm2).

Effect of laser power during laser powder bed fusion on microstructure of joining interface between Tungsten and AISI 316L steel

This study investigates the deposition of tungsten (W) onto a 316L steel substrate by laser powder bed fusion (L-PBF), to optimize process parameters and analyze the interface between W and 316L. To obtain high-density W structure (98.89%), the optimal laser power was 350 W, and scan speed was 500 mm/s, but these parameters cause significant dilution of W in the W-316L interface; as a result, Fe7W6 intermetallics form, despite L-PBF being a non-equilibrium solidification process. These intermetallics which are brittle could degrade joint strength. By reducing laser power below 250 W, the dilution of W can be mitigated, and potentially minimize formation of intermetallics and increase joint stability for advanced manufacturing applications.

Failure investigation of an AISI 316L pipe of the flare system in an off-shore oil platform

The oil and gas industries have severe operations conditions, which impose several failures in off-shore equipment. The Flare System is a pipe designed to safely dispose of relieving hydrocarbon gases and liquids during start-up, operational upsets, emergency shutdown, and maintenance activities. This work reported the failure investigation in a pipe of a high-pressure flare system. The pipe has a diameter of 220 mm and 4 mm of thickness, and according to the equipment datasheet, it was made in AISI 316L stainless steel. Two cracks were detected during the previous non-destructive inspection. Those failures were repaired, but another crack was detected after some months. Chemical composition was investigated using optical emission spectroscopy and elemental analysis, and the results are compatible with AISI 316L steel. The microstructure observed by light optical and scanning electron microscopes shows an austenitic matrix with deformation bands. The microhardness measurements and the XRD analysis show the martensite formation in those deformation bands. The tensile properties are in accordance with the standards. The fracture surface was investigated using scanning electron microscopy, the results point to fatigue failure.

Causes of damage to a pipeline of AISI 316L steel

Causes of damage to a pipeline of AISI 316L steel

Heat Transfer Enhancement in a 3D-Printed Compact Heat Exchanger

The study describes experimental data on thermal tests during the condensation of HFE7100 refrigerant in a compact heat exchanger. The heat exchanger was manufactured using the additive 3D printing in metal. The material is AISI 316L steel. MPCM slurry was used as the heat exchanger coolant, and water was used as the reference medium. The refrigerant was condensed on a bundle of circular tubes made of steel with an internal/external diameter of di/de = 2/3 mm, while a mixture of water and phase change materials as the coolant flowed through the channels. Few studies consider the heat exchange in condensation using phase change materials; furthermore, there is also a lack of description of heat exchange in small-sized exchangers printed from metal. Most papers deal with computer research, including flow simulations of heat exchange. The study describes the process of heat exchange enhancement using the phase transition of coolant. Experimental data for the mPCM slurry coolant flow was compared to the data of pure water flow as a reference liquid. The tests were carried out under the following thermal and flow conditions: G = 10–450 [kg m−² s−1], q = 2000–25,000 [W m−²], and ts = 30–40 [°C]. The conducted research provided many quantities describing the heat exchange in compact heat exchangers, including heat exchanger heat power, heat exchange coefficient, and heat exchange coefficients for working media. Based on these factors, the thermal performance of the heat exchanger was described. External characteristics include the value of the thermal power and the heat exchange coefficient as a function of the mass flow density of the working medium and the average logarithmic temperature difference. The performance of the heat exchanger was presented as the dependencies of the heat exchange coefficients on the mass flux density and the heat flux density on the heat exchange surface. The thickness of the refrigerant’s condensate film was also determined. Furthermore, a model was proposed to determine the heat exchange coefficient value for the condensing HFE7100 refrigerant on the outer surface of a bundle of smooth tubes inside a compact heat exchanger. According to experimental data, the calculation results were in good agreement with each other, with a range of 25%. These data can be used to design mini condensers that are widely used in practice.

Influence of Reinforcing nano-Al<sub>2</sub>O<sub>3</sub> Particles on Microstructure and Hardness Properties of HVOF Sprayed 80Ni20Cr Coatings

80Ni20Cr coatings produced by high-velocity oxygen fuel (HVOF) thermal spray technique are novel and widely used to improve the corrosion and wear resistance of metal and steel components in many applications, especially in coal-fired power plants. The present study investigated the effects of nano-Al2O3 at 0.5 wt.% on the microstructure of HVOF-sprayed 80Ni20Cr coating deposited on AISI 304L steels corresponding to its coating hardness. The coating was successfully sprayed with a thickness of 150 – 180 µm. The microstructure and phase formed by the coating were analyzed by a field emission electron microscope (FE-SEM) and an X-ray diffractometer (XRD). Synchrotron X-ray fluorescence spectroscopy (SRXRF) was used to confirm the Cr solid solution in the Ni-based coating. The presence of the nano-Al2O3 phase in the 80Ni20Cr coating was characterized by electron backscattered diffraction (EBSD). The nano-Al2O3 particles were homogenously distributed in the coating layers. The incorporation of nano-Al2O3 into 80Ni20Cr enhanced coating characteristics by decreasing surface roughness by 23% and increasing coating hardness by around 4%.

Experimental and numerical examination of low cycle fatigue behaviour on AISI304L steel

The integrity of the components of nuclear power plants must be guaranteed under operating and emergency conditions. It is necessary to evaluate all possible degradation mechanisms that could impact the structural integrity of nuclear power plant structures such as the pipelines and other components of the cooling systems. Environmental fatigue significantly influences the degradation mechanisms of steel components operating in water, which eventually affects the operational lifetime of the components. Exploring non-codified methods for more precise assessment of fatigue phenomena can pave the way for developing safer nuclear power plants with longer operational lifetimes. This is very important as the global demand for cleaner energy is increasing. This research study deals with a numerical investigation of the low-cycle fatigue behaviour of steel used for those nuclear reactor components where environmental fatigue plays a major role. The numerical simulation methodology is proposed to study the dependence of the kinematic hardening parameter on the strain amplitude to investigate the low-cycle fatigue behaviour of AISI 304L steel for the prediction of the fatigue curves that can be used for the estimation of nuclear power plant safety and its lifetime.The experimental data was used to estimate the parameters required to define the material model for the numerical simulation and to validate the results of the numerical simulation of the low cycle fatigue behaviour. The presented methodology can be used for fully reversed constant-amplitude strain loading low cycle fatigue simulations for various strain ranges to predict the low-cycle fatigue behaviour of steel under repetitive loading.

On the effect of salt bath nitrocarburizing on the cavitation erosion behavior of AISI 304L stainless steel

In this study, salt bath nitrocarburizing was applied on austenitic stainless steel AISI 304L to stabilize austenite at the surface exposed to cavitation attack. Samples were treated at 470 °C and 500 °C for 6 h, giving an average thickness of the nitrocarburized layer of 6 µm and 26 µm, respectively. The thickness of the nitrocarburized layer is found to influence the formation of deformation-induced martensite (DIM) in the material and, thereby, the cavitation erosion resistance. The mass loss vs. time plot shows that the nitrocarburized specimens performed significantly better than the base material under ultrasonic vibratory cavitation erosion test (ASTM G32). Cross-sectional micrographs show that the phenomenon responsible for the failure in the base material is the formation of DIM. The specimen, nitrocarburized at 470 °C, showed a reduction of about 90 % in mass loss when compared to the base material (AISI 304L SS), owing to a higher yield strength (/resilience) after the formation of more stable austenite.

Modeling of LCF Behaviour on AISI316L Steel Applying the Armstrong-Frederick Kinematic Hardening Model.

The combination of kinematic and isotropic hardening models makes it possible to model the behaviour of cyclic elastic-plastic steel material, though the estimation of the hardening parameters and catching the influence of those parameters on the material response is a challenging task. In the current work, an approach for the numerical simulation of the low-cycle fatigue of AISI316L steel is presented using a finite element method to study the fatigue behaviour of the steel at different strain amplitudes and operating temperatures. Fully reversed uniaxial LCF tests are performed at different strain amplitudes and operating temperatures. Based on the LCF test experimental results, the non-linear isotropic and kinematic hardening parameters are estimated for numerical simulation. On comparing, the numerical simulation results were in very good agreement with those of the experimental ones. This presented method for the numerical simulation of the low-cycle fatigue on AISI316 stainless steel can be used for the approximate prediction of the fatigue life of the components under different cyclic loading amplitudes.

Experimental Characterization and Phase-Field Damage Modeling of Ductile Fracture in AISI 316L

(1) Modeling and characterization of ductile fracture in metals is still a challenging task in the field of computational mechanics. Experimental testing offers specific responses in the form of crack-mouth (CMOD) and crack-tip (CTOD) opening displacement related to applied force or crack growth. The main aim of this paper is to develop a phase-field-based Finite Element Method (FEM) implementation for modeling of ductile fracture in stainless steel. (2) A Phase-Field Damage Model (PFDM) was coupled with von Mises plasticity and a work-densities-based criterion was employed, with a threshold to propose a new relationship between critical fracture energy and critical total strain value. In addition, the threshold value of potential internal energy—which controls damage evolution—is defined from the critical fracture energy. (3) The material properties of AISI 316L steel are determined by a uniaxial tensile test and the Compact Tension (CT) specimen crack growth test. The PFDM model is validated against the experimental results obtained in the fracture toughness characterization test, with the simulation results being within 8% of the experimental measurements. (4) The novel implementation offers the possibility for better control of the ductile behavior of metallic materials and damage initiation, evolution, and propagation.

The Effect of Nitriding Temperature of AISI 316L Steel on Sub-Zero Corrosion Resistance in C2H5OH.

In this paper, glow nitriding processes at cathode potential are used at various temperatures to investigate how they affect the corrosion resistance of 316L steel in ethanol at temperatures of 22 °C and -30 °C. Lowering the test temperature reduces the corrosion rate of the nitrided layers. Conversely, glow nitriding at 450 °C improves the corrosion resistance of the tested steel. Increasing the nitriding temperature to 520 °C increases the corrosion rate. It should be noted that the ethyl alcohol solution, due to the lack of aggressive ions, does not cause significant changes in the corrosion rate of the steel. The value of the corrosion current varies in the range of 10-2-10-3 µA/cm2. Nitrided layers increase the contact angle measured for water and are entirely wettable for ethanol. The objective of this study is to evaluate the effect of the nitriding temperature of AISI 316L steel on its corrosion resistance in an ethanol solution at room temperature and at -30 °C.

Quaternary nitrate and chloride molten salts for the next concentrating solar power plants: Corrosion considerations for the use of AISI 304L steel

The study addresses the advancement in concentrating solar power (CSP) plants by transitioning from binary nitrate salts to nitrate and chloride quaternary salts, focusing on the corrosivity of four salts as evaluated by immersion testing of AISI 304L stainless steel. Four compositions of salts were evaluated, from solar salt to equimolar NaNO3‐KNO3‐NaCl‐KCl, up to 21 days (500 h) at 500 °C in an open atmosphere, determining the corrosion kinetics using gravimetry. The morphology, chemical composition, and microstructure of the corrosion products were characterized using XRD, FESEM-EDS, and GD-OES. Exposure to the molten salt with 0 mol% Cl‐ (Solar Salt) resulted in negligible corrosion kinetics, consistent with previous studies. The salt with 14 mol% Cl‐ caused a stable corrosion product with a corrosion rate 30 times higher than without chloride. All quaternary salts exhibited a multilayer structure of the top surface with selective chromium (Cr) removal. Specimens exposed to salts with more than 29 mol% Cl‐ displayed a similar structure with Cr and iron (Fe) removal, resulting in more brittle layers and corrosion rates 90 to 250 times higher than the salt without chloride. GD-OES analysis confirmed Cl diffusion into the oxide layer, highlighting the role of pCl2(g) and pO2(g) in driving corrosivity. Based on the results, using in salts with 29 mol% Cl‐ at 500 °C is discouraged, while using 304L with 14 mol% Cl‐ in a cold tank may be considered.

NiCrBSi/WC Composite Claddings Processed on AISI 316L Steel Alloy by the Direct Laser Deposition Process: Studies on Dry Sliding Wear Behavior and Wear Mechanism Maps

Abstract This study presented the wear behavior of the NiCrBSi/WC composite claddings processed on an AISI 316L steel alloy substrate by laser cladding approach. The scanning electron microscope (SEM) morphology of the claddings has shown excellent substrate–cladding interface bonding, good WC particulate distribution, and no noticeable cracks and voids. The electron dispersion spectroscope (EDS) spectra have confirmed the presence of respective NiCrBSi alloy matrix and WC elements. The XRD spectra have identified various phases and compounds such as gamma-Ni, FeNi3, Ni3B, Cr23C6, Ni3Si, and W2C commonly in all the processed composite claddings. The microhardness of the claddings was measured between 791 and 1086 HV0.2 for increasing the reinforcement WC particulate percentage from 15 wt% to 60 wt%. It is about 470% surface hardness enhancement with the processed composite claddings compared with the substrate alloy. The reinforcement of WC from 15 wt% to 60 wt% with the composite claddings resulted in wear resistance enhancement from 21.85% to 60.64% and the coefficient of friction from 56.87% to 77.92% against the substrate. The wear-rate maps and their respective cladding's worn surface morphology have described the wear mechanisms typically as adhesive, abrasive, oxidation, and delamination. The wear mechanisms are mainly influenced by the WC particulate percentage. The increased WC particulate content has increased the dominance of the abrasive wear mechanism while reducing the window of the adhesive wear mechanism. The windows of various wear mechanisms and their ranges, such as adhesive 0.0033 to 0.028, abrasion 0.010 to 0.067, oxidation 0.012 to 0.093, and delamination 0.015 to 0.120 mm3/m, for NiCrBSi/WC composite claddings comprehensibly represented the wear behavior for the varied conditions of dry sliding wear parameters.