This research addresses the critical need for a highly stable and transparent electromagnetic shielding coating for aircraft PMMA windows and canopies, crucial for safeguarding against electromagnetic interference and enhancing aircraft stealth capabilities. The study presents the novel design, deposition and investigation of transparent coatings, specifically TiO2/Au, on PMMA organic glass cockpit canopies. Optimization of TiO2 and Au film thicknesses is achieved through simulation using TFcalc software, incorporating polarization and optical constants data obtained in this study. The experiments reveal that the deposition of TiO2/Au/TiO2 on PMMA results in fogging, reducing transparency, while novel TiO2/Au coating does not exhibit this issue. The TiO2/Au configuration, featuring a TiO2 layer approximately 30 nm thick and an Au film ranging from 11 to 15 nm in thickness, demonstrates outstanding attributes, including a remarkable transparency level of approximately 70–80% and robust electromagnetic interference shielding efficiency within the range of 19–29 dB across S, C, X, and Ku bands of electromagnetic waves. These exceptional performance characteristics position it as an ideal choice for aviation applications. The synergy of the stable Au and durable TiO2 components, with their high hardness and self-cleaning properties, extends its potential utility to a diverse array of applications.