Objectives : In this study, a learning-based optimization method is proposed and implemented for determining new monitoring sites when expanding the roadside air pollution monitoring network. Utilizing the bigdata available in Seoul, this decision-making tool is developed that takes into account the objectives of selecting new monitoring sites and incorporates social, economic, and environmental characteristics. The optimized results can suggest potential locations for new roadside air pollution monitoring sites. Additionally, the capability of this tool to facilitate objective decision-making processes is evaluated by determining the influence range providing reliable air pollution information with the addition of the new monitoring sites.Methods : The proposed learning-based optimization algorithm is a new approach for selecting the new optimal monitoring sites by comprehensively considering social, economic, and environmental factors aligned with the installation purpose of the monitoring system in Seoul. The algorithm starts with genetic algorithms to select candidate locations for new monitoring sites that maximize the influence area of the expanded monitoring network compared to the existing monitoring network, capture a high overall level of air pollution, and do not overlap with the existing monitoring network. After that, PROMETHEE method is applied to evaluate the solutions generated by the genetic algorithm and choose the final solution that best fits six evaluation factors (Information entropy, number of new monitoring sites, distance from point sources, wind speed, traffic volume, and population) to be considered when installing new monitoring sites.Results and Discussion : The learning-based optimization algorithm selects 10 potential new monitoring sites adding to the existing roadside air pollution monitoring network having 15 monitoring sites. The explainable spatiotemporal range of the air pollution information that can be expected after the installation of the new monitoring sites is quantified to cover 84.33% of Seoul, reducing the uncertainty of the air pollution information of existing monitoring network by 26.15%. The final solution, selected from several solutions, can get new optimal roadside air pollution monitoring sites reflecting the regional characteristics of Seoul and the installation purpose of the monitoring system by having a small number of newly established monitoring locations, being close to air pollution emissions facilities, and having a high population and traffic volume.Conclusion : The proposed learning-based optimization method, using relevant variables for the installation purpose of the monitoring system, can derive the objective solution for deciding new monitoring locations of the roadside air pollution monitoring network, considering additional social factors as opposed to urban air pollution monitoring network. The final solution obtained through the optimization algorithm has great potential for future use, as it can guide to determine practical and feasible new monitoring sites with additional on-site verification. Furthermore, this optimized approach can be applied widely during the decision-making process for the expansion of other environmental monitoring networks.