In this study, the combustion chamber profiles were developed for spray, wall, and air-guided gasoline direct injection (GDI) engines. For each combustion chamber geometry of GDI engine, the piston crown surface was modified, from hemispherical bowl, to trapezoidal bowl, and a pent roof shape that included a scoop type bowl on one side (towards injector position) to impart better squish, swirl, tumble, and turbulence effects to improve the mixing characteristics. Also, the cylinder heads were modified for each combustion chamber geometry by changing the locations of the spark plug and fuel injector. Further, the fuel split injection timings with duration, ignition timing, and the percentage of exhaust gas recirculation were optimized to reduce an engine out emissions; especially soot and nitrogen oxides. Emission tests were conducted on the base diesel engine and the GDI engine with the three different combustion chamber geometries. It is clear from the results that the emission of nitrogen oxides in the wall-guided mode was reduced by 5% till 75% of the load when compared with spray-guided and air-guided combustion modes. Overall, the GDI engine with the wall-guided combustion chamber geometry produced better results at 150 bar fuel injection pressure when compared with the base diesel engine; nitrogen oxides emission was reduced from 377 to 77 ppm and soot emissions were reduced from 29.3 to 4.5 g/km at high torque.