Agpaitic Index Research Articles

ГЕОХИМИЧЕСКИЕ ОСОБЕННОСТИ ГАББРОИДОВ И ГРАНИТОИДОВ НЯТЫГРАНСКОГО КОМПЛЕКСА (БУРЕИНСКИЙ МАССИВ)

Gneissic gabbros, gabbrodiorites, granodiorites, and granites of the Late Proterozoic Nyatygransky Complex, exposed by erosion in the eastern part of the Bureya massif, form small intrusive bodies within the boundaries of the Melgin metalliferous trough, as well as around it. Analysis of chemical and trace-element compositions of rocks from the Nyatygransky Complex revealed their geochemical features. The calculated agpaitic index values for gabbroids are very low and range from 0.11 to 0.33. Granodiorites have slightly higher index values ranging from 0.5 to 0.38, and only gneiss-granites are plumasitic with agpaitic index values between 0.45 and 0.75. Both gabbroids and granitoids are assigned to calc-alkaline rocks by their agpaitic index. Gneissic gabbros, dominated by dark-colored minerals (labradorite, hornblende), show enhanced alkalinity not common to gabbros (4%); in them, the magnesium content prevails over the iron content. They are characterized by high alumina content (15–18%), reaching 20.38%. Geochemically, they are interpreted as I-type igneous rocks. Gneissic granitoids with a slight predominance of the iron content over the magnesium content are less aluminous (Al2O3 12–15%). They are interpreted as S-type (sedimentary) and I-type (igneous) granitoids, formed in sedimentary and granitic layers of the earth’s crust. According to petrochemical diagrams, the gabbroids and granitoids of the Nyatigransky Complex belong to the volcanic arcs of the active continental margin.

Plumbing System Architecture and Differentiation Processes of the Nyiragongo Volcano, DR Congo

ABSTRACT The Nyiragongo volcano is one of the most alkali-rich volcanic centres on the planet (Na2O + K2O generally >10 wt.%, agpaitic index up to 1.34), characterized by a semi-permanently active lava lake which hosts silica-undersaturated (SiO2 < 40 wt.%), low viscosity lavas. To improve our understanding of this unique magmatic system, we present a set of 291 samples, acquired during new field excursions between 2017 and 2021. The major and trace element composition of all samples was measured, revealing a lithological range extending from primitive picrites (Mg# 82) erupted from parasitic cones to a variety of highly evolved nephelinites, leucitites, and melilitites erupted from the main edifice as recently as 2002, 2016, and 2021. We measured major and trace element compositions from the full spectrum of minerals present in all sampled lithologies. From these we calculated that the main magma reservoirs feeding Nyiragongo are at approximately 9–15 and 21–33 km depth, in agreement with recent seismic observations. Fractional crystallization modelling using observed mineral compositions and proportions was performed to quantitatively link the lithologies to specific residual liquid fractions assuming evolution from an olivine-melilite parental melt. Our modelling indicates that fractionation and cumulate formation in deep chambers reduces the remaining melt fraction to ~60%, after which melts are injected into upper, liquid dominated magma chambers where fractionation and accumulation of clinopyroxene, melilite, and feldspathoids dominates. Characterisation of mineral textures and geochemistry reveals high crystal mobility in a repeatedly recharging plumbing system split between liquid-dominated, evolved magma chambers and more solid-dominated, primitive mushes, decreasing in liquid fraction with depth.

Origin of silicic rocks of the Deccan Traps continental flood basalt province: Inferences from field observations, petrography, and geochemistry

The origin of silicic rocks (SiO2 > 65 wt%) in Continental Flood Basalt (CFB) provinces could be attributed to complex petrogenetic processes. The 65.5–66 Ma old Deccan Traps CFB contains eight sporadic but significant silicic rock exposures that are studied here in a comprehensive framework using field observations, petrography, major oxides (n = 56), and trace element chemistry. Rhyolite and granophyre, as well as subordinate felsite, ignimbrite, trachyte, pitchstone, and microgranite coexist with volcanic and plutonic mafic rocks such as basalt, basaltic andesite, and gabbro. Multiple isolated and circular/semi-circular hills and linear dykes of silicic rocks are present in the form of lavas with prominent flow folding, rheomorphic ignimbrite, and tuffs. The ‘Rheological Agpaitic Index’ (RAI) indicates that most of the silicic rocks in the Deccan Traps are effusive in nature, except for Rajpipla, Alech, Bombay, and Osham silicic rocks, which are marked by explosive volcanism. Thermodynamic-based Rhyolite-MELTS modelling suggests that the major oxide composition of Pavagadh and Barda basalt is a likely candidate for the parental melt composition of the silicic rocks of the Deccan Traps. Ba, Sr, P, Zr, and Ti anomalies are consistent with the fractionation of K-feldspar, plagioclase, apatite, zircon, and Fe-Ti oxides, respectively. Two broad REE patterns are noticed in the Deccan Traps silicic rocks: a flat pattern for Barda, Alech, and Chogat-Chamardi silicic rocks, and a steep REE pattern for Osham, Rajula, Pavagadh, Rajpipla, and Bombay silicic rocks. Trace element modelling reveals that 5–10 % partial melting of a spinel peridotite source could produce an REE pattern and abundances similar to the associated basalts. Further extensive fractional crystallization (60–90 %) of the parental mafic melt at a deeper depth (where spinel is stable) could produce the REE composition and pattern observed in most silicic rocks except for those of Barda, Alech, and Chogat-Chamardi, which require fractional crystallization of the same parental melt at a shallower depth (where spinel is not stable). The geochemical variability of Deccan Traps silicic rocks reveals an origin from a mantle-derived parental mafic melt that evolved via the assimilation and fractional crystallization (AFC) process to form the silicic exposures, which is typical of silicic volcanism in other global CFBs.

MINERALOGICAL AND PETROLOGICAL CHARACTERISTICS OF GRANITES OF THE SHPOLA-TASHLYK ORE DISTRICT (THE UKRAINIAN SHIELD)

Mineralogical and petrographical research of different types of granites of the Kirovohrad complex, such as of Lypniazhka, Berezivske, Yaroshivka, Dorofiivka, Hlodosy, in the Shpola-Tashlyk ore district of the Ukrainian Shield, has been conducted. It allows to identify them as rare-metal genetic type. The evidence comes from: High silica (SiO2 = 71.70—74.24%), agpaitic index (0.53—0.71) and low iron oxidation (0.16—0.59) in granites. Furthermore, they are enriched with fluorine and boron based on occurrence of accessory fluorite and tourmaline. Characteristic chemical feature of the granites is a prevalence of potassium over sodium. The contents of phosphorus, zirconium, cerium, lanthanum, and lithium in Berezivske granites exceed average contents for such elements of the Ukrainian Shield, due to accessory mineralization — apatite, monazite, and lithium-bearing mica. The most high lithium grades (55 ppm) are specific for Lypniazhka and Yaroshivka granites where at their exocontact zone the lithium deposits and occurrences of niobium, tantalum, and stannum were discovered. Based on structure and texture features, massive, porphyroblastic, gneiss-like, and aplite-pegmatoid types with gradual transitions were distinguished; it is an evidence of their genetic relation. It was defined that Lypniashka granites related to the lithium pegmatite deposit have mineralogical features comparing to other types of granites, such as: a) highest ВаО (0.44—0.53 %) content in microclines; b) most ferrous biotite (f = 0.64 %) with the highest content of fluorine (0.16 %). Isotopic and geochemical research of monazite was conducted. The granites age ranges from 2026 to 2042 Ma. The granites related to rare-metal mineralization yielded ages from 2026 to 2037 Ma comparing to the oreless granites (Smoline urban-type settlement) with age 2042 Ma. On biotite-garnet geothermometer study the granites’ formation temperatures were defined, such as: Dorofiivka granite — 625°С, Berezivske granite — 640ºС, Hlodosy granite — 640ºС, and Yaroshivka granite (Т = 640—750ºС, Р = 500—700 MPa). Considering field observations and facts mentioned above the Berezivske granites belong to rare-metal granite complex of S-type.

The anorogenic late Ediacaran granite-rhyolite porphyries of Gabal Abu Durba, Sinai: termination of magmatism in the Neoproterozoic Arabian-Nubian Shield crust

ABSTRACT Anorogenic magmatism in the northern Arabian-Nubian Shield occurred during a long-lasting crustal extension event (<580 Ma), which succeeded the formation of the Pan-African orogenic belt in NE Africa and Arabia. Late Neoproterozoic anorogenic felsic volcanic-subvolcanic rocks, along with post-collisional granitoid suites, are exposed in the Gabal Abu Durba mountain range along the eastern flank of the Gulf of Suez in Sinai. These rocks include granite and rhyolite porphyries, metaluminous to weakly peralkaline with distinct potassic alkaline and ferroan affinities. Major and trace element characteristics such as K2O/MgO >16, total alkalis >8.5 wt.%, (K2O + Na2O)/CaO >10, agpaitic index (NK/A) >0.85 and Zr (>250 ppm), Nb (>20 ppm), Y (>80 ppm), Zn (>100 ppm) and Ce (>100 ppm), and 10,000 × Ga/Al >2.6 and [Zr + Nb + Y + Ce] >350 ppm are suggestive of an A-type granite genesis. Zircon U-Pb dating of two representative samples returned crystallization ages of 569 ± 2.6 Ma and 561.7 ± 3.2 Ma for granite and rhyolite porphyries, respectively. The melting temperatures estimated at 997–1020°C are consistent with high-temperature liquidus conditions. Fractional crystallization, coupled with less significant crustal assimilation, was likely the main mechanism of formation of these rocks from a common primitive asthenospheric mantle-derived trachytic magma in an anorogenic intra-plate setting. The A-type alkali granite and rhyolite porphyries of Gabal Abu Durba are manifestations of mantle upwelling and lower crust underplating in the late Ediacaran anorogenic stage. These felsic subvolcanic intrusions (≈ 569–562 Ma) along with their volcanic counterparts constitute a new unmatched rock unit that most probably represent the last chapter of the anorogenic magmatism in the Neoproterozoic Arabian-Nubian Shield crust before the beginning of Phanerozoic era.

Isotopic-Geochemical Systematics (Sm–Nd, Lu–Hf) of Neoarchean Subalkaline and Alkaline Rocks of the Keivy Structure (Kola Peninsula): Their Age and Genetic Relations

The Neoarchean subalkaline magmatism of the Keivy structure is expressed in the formation of the volcanoplutonic latite–monzonite–granite association (LMGA). The formation of LMGA magmas is assumed to occur due to melting of metasomatically altered mafic rocks during intrusion into the lower crust of basaltic melts initial for rocks of the dike complex and gabbro–labradorite massifs. The alkaline granites associated with LMGA have a close U–Pb age but a later formation time based on the geological data. With respect to LMGA, alkali granites have increased concentrations of SiO2, alkalis (K2O/Na2O = 1.1–1.4), iron (F# = 84–98%), a high agpaitic index (Kagp = 0.86–1.2), and lower quantities of TiO2, MgO, Fetot, and Al2O3, which probably resulted from the higher degree of differentiation of their initial melts compared to LMGA.

Geochemical Constraints of the Ediacaran Volcano‐Sedimentary Succession of the Sa'al Metamorphic Complex at Wadi Zaghra, South Sinai, Egypt

AbstractThe volcano‐sedimentary succession around Wadi Zaghra in Sinai, at the northernmost segment of the Arabian Nubian Shield, comprises volcanic rocks interbedded with rather immature sediments. The succession is dominated by intermediate to silicic volcanics of medium‐ to high‐K calc‐alkaline affinity. It is divided into two units, the lower unit includes intermediate rocks and dacites interbedded with graywackes, semi‐pelites and pelites and topped by polymict conglomerates. This unit is subjected to folding and regional metamorphism (up to garnet zone) and is intruded by quartz diorite‐granodiorite inducing, locally, low‐pressure contact thermal metamorphism. The unmetamorphosed upper unit encompasses acid volcanics intercalated with litharenite, sublitharenite and minor arenite. The rhyolites of this unit pertain to the highly fractionated granites and are characterized by an agpaitic index (NK/A) ranging from 0.87 to 0.96. They may reflect either extensive interaction of subduction‐related magmas with the continental crust or a change in the tectonic regime. The present lithological and geochemical characteristics of the studied sediments together with available zircon ages indicate rather distal provenance of their detritus. This detritus comprises fluvial‐alluvial sediments accumulated in the intermontane basins, which are half‐grabens or tilted fault blocks. The tectonic setting of the depositional basins is active continental margin and continental island arcs. Geochemical patterns of the Zaghra volcano‐sedimentary succession indicate their correlation with the Dokhan Volcanics‐Hammamat Clastics sequence of the Eastern Desert of Egypt. Also, the Zaghra volcanics display geochemical similarities with those exposed in Sinai, at the Rutig, Ferani and Iqna Shar'a areas. The Zaghra succession is dated as Ediacaran but is not related either to the ensimatic island arc assemblage or to the rift‐related assemblage formed during the early stages of the break‐up of Rodinia as previously thought.

High‐silica Ediacaran volcanism in the Dom Feliciano Belt, southernmost Brazil

The Cerro Chato region is located in southernmost Brazil and is characterized by associations of acid volcanic and subvolcanic rocks. The region is affected by NW and NE‐ trending faults and is grouped into 2 geomorphologically distinct features: Cerro Chato and Cerro Partido. Cerro Chato is represented by ignimbrites that occur in 2 main facies: lithic‐rich ignimbrites and crystal‐rich ignimbrites. They are poorly sorted and consist of lapilli‐sized pyroclasts in a tuffaceous matrix with eutaxitic texture. Hemi‐crystalline rhyolitic flows represent effusive events, with porphyritic texture, flow structures, and spherulites. Cerro Partido is characterized by a subvolcanic rhyolitic body, with porphyritic texture, elongated in the NE–SW direction. Through geochemical data, the lithologies were characterized as high‐silica type rhyolites, correlated to the alkaline series, close to the subalkaline series limit; display metaluminous to peraluminous character and high contents of alkalis, FeOt/FeOt + MgO and agpaitic index. The Cerro Partido rhyolites were classified as high‐Ti with higher CaO, P2O5, FeOt, MgO, and K2O contents than the Cerro Chato low‐Ti rhyolites. The REE pattern is slightly enriched in LREE in relation to the HREE and has a strong negative Eu anomaly. U–Pb zircon dating indicates an age of 561 ± 2 Ma for Cerro Partido, suggesting contemporaneity with the granitoids of Dom Feliciano Suite. Additionally, Cerro Chato rhyolites indicate an age of 630.4 ± 2.8 Ma. These ages are in agreement with those obtained in the syn‐sedimentary volcanism at the base of the Maricá Formation, Camaquã Basin.

Petrology and Geochemistry of A-type granites from Khanak and Devsar Areas of Bhiwani District, Southwestern Haryana

ABSTRACT Petrological and geochemical characteristics of the granites from the Khanak and Devsar areas have been discussed in this paper. Based on field, petrographical and geochemical observations, three types of granites (grey, green and pink granite) have been identified in these areas. Grey granites consist of quartz, plagioclase, biotite, hornblende as essential minerals and hematite, zircon, annite, monazite &amp; rutile as accessory minerals. Petrographically, green granites are same as grey granites including perthite and zircon as accessory minerals. Pink granites consist of quartz, k-feldspar and biotite in Khanak whereas in Devsar granites alike as Khanak granites, but plagioclase is replaced by perthite and occurs as dominantly. Microscopically, granites of both areas show porphyritic, hypidiomorphic, granophyric, perthitic and micro granophyric textures. Geochemically, major oxide elements (except alkalies) and trace elements (Ba, Sr, Cr, Ni, V, Cu, Zn, Ga, Pb, Th and Zr) are more in green and grey granites of Khanak and Devsar areas than pink granites. Generally, they show enrichments in SiO2, Na2O+K2O, Fe/Mg, Rb, Zr, Y and and AI (Agpaitic Index) (ranges from 0.10 to 1.18) and depletion in MgO, CaO, P, Ti, Ni, Cr and V indicate their A-type affinity which is very similar to the A-type granites of MIS (Malani igneous suite) in northwestern peninsular India. Green and grey granites of Devsar area show high concentrations of Heat production (HP) 9.68 &amp; 11.70 μWm−3 and total Heat Generation Unit (HGU) i.e 23.04 &amp; 27.86 respectively. On the other hand, pink granites of Khanak area display a higher enrichment of HP (16.53 μWm−3) and HGU (39.37) than those granites of Devsar area. Overall, they have much a higher values of HP and HGU than the average value of continental crust (3.8 HGU), which imply a possible linear relationship with the surface heat flow and crustal heat generation in the rocks of MIS. From the petrography as well as the chemistry of Khanak and Devsar granites, it is suggested that they might have derived from the different degree of partial melting from the similar source of magma.

Viscosity of pantelleritic and alkali-silicate melts: Effect of Fe redox state and Na/(Na + K) ratio

The viscosity of two series of synthetic alkali silicates, corresponding to Al-bearing pantelleritic and Al-free tri-silicate compositions, has been investigated as a function of temperature, iron redox and Na/(Na+K) ratio. Low temperature (708–1000K) viscosities were determined by the micropenetration technique in the 109.6 to 1013.6Pas range. The effect of Fe2+/Fetot, from 0.15 to 0.86, was explored for [Na/(Na+K)] ratios from 0 to 1. The results demonstrate a strong decrease of viscosity with the replacement of Na for K in both the Al-bearing and Al-free compositions. In the Al-bearing pantelleritic glasses (Ebu) the viscosity as well as the activation energy for viscous flow decrease with an increase of Fe2+/Fetot from 0.15 to 0.76. In contrast, no measurable changes in viscosity occur in the Al-free tri-silicate glasses (NFS and KFS) as Fe2+/Fetot ratio varies from 0.15 to 0.86. The comparison of the pantelleritic glasses with peralkaline compositions from the literature stresses the strong influence of iron redox on the overall viscosity of such melts. This suggests that the contribution of iron species should be accounted for in the calculation of agpaitic index (AI) if magma Fe3+ contents are known.One peculiarity of peralkaline magmas is the excess of alkali to alumina, which generally results in lower viscosities of pantelleritic liquids compared with more common metaluminous rhyolites and exerts a primary control of the rheological behaviour of these melts.Our new viscosity data, combined with existing literature, allow more accurate constraints on the nature and eruption of the pantelleritic magmas. Moreover, the present experimental study can be used to improve the viscosity models that mostly do not take in consideration parameters as iron redox in the viscosity prediction.

Genesis and mechanisms of formation of rare-metal peralkaline granites of the Khaldzan Buregtey massif, Mongolia: Evidence from melt inclusions

Melt inclusions were studied by various methods, including electron and ion microprobe analysis, to determine the compositions of melts and mechanisms of formation of rare-metal peralkaline granites of the Khaldzan Buregtey massif in Mongolia. Primary crystalline and coexisting melt inclusions were found in quartz from the rare-metal granites of intrusive phase V. Among the crystalline inclusions, we identified potassium feldspar, albite, tuhualite, titanite, fluorite, and diverse rare-metal phases, including minerals of zirconium (zircon and gittinsite), niobium (pyrochlore), and rare earth elements (parisite). The observed crystalline inclusions reproduce almost the whole suite of major and accessory minerals of the rare-metal granites, which supports the possibility of their crystallization from a magmatic melt. Melt inclusions in quartz from these rocks are completely crystallized. Their daughter mineral assemblage includes quartz, microcline, aegirine, arfvedsonite, polylithionite, a zirconosilicate, pyrochlore, and a rare-earth fluorocarbonate. The melt inclusions were homogenized in an internally heated gas vessel at a temperature of 850°C and a pressure of 3 kbar. After the experiments, many inclusions were homogeneous and consisted of silicate glass. In addition to silicate glass, some inclusions contained tiny quench zircon crystals confined to the boundary of inclusions, which indicates that the melts were saturated in zircon. In a few inclusions, glass coexisted with a CO2 phase. This allowed us to estimate the content of CO2 in the inclusion as 1.5 wt %. The composition of glasses from the homogeneous melt inclusions is similar to the composition of the rare-metal granites, in particular, with respect to SiO2 (68–74 wt %), TiO2 (0.5–0.9 wt %), FeO (2.2–4.6 wt %), MgO (0.02 wt %), and Na2O + K2O (up to 8.5 wt %). On the other hand, the glasses of melt inclusions appeared to be strongly depleted compared with the rocks in CaO (0.22 and 4 wt %, respectively) and Al2O3 (5.5–7.0 and 9.6 wt %, respectively). The agpaitic index is 1.1–1.7. The melts contain up to 3 wt % H2O and 2–4 wt % F. The trace element analysis of glasses from homogenized melt inclusions in quartz showed that the rare-metal granites were formed from extensively evolved rare-metal alkaline melts with high contents of Zr, Nb, Th, U, Ta, Hf, Rb, Pb, Y, and REE, which reflects the metallogenic signature of the Khaldzan Buregtey deposit. The development of unique rare metal Zr–Nb–REE mineralization in these rocks is related to the prolonged crystallization differentiation of melts and assimilation of enclosing carbonate rocks.

Post-collisional Ediacaran volcanism in oriental Ramada Plateau, southern Brazil

Ediacaran volcanic sequences in southernmost Brazil are related to intense post-collisional magmatism of the Brasiliano Orogeny. A portion of this volcanism occurs in the oriental Ramada Plateau located in the center part of the Rio Grande Sul State and is correlated with Hilário and Acampamento Velho formations. The first one is represented dominantly by lava flows and dikes of shoshonitic andesitic composition, besides of volcanogenic sedimentary deposits. The acid rocks of the Acampamento Velho Formation are expressive in the area, comprising high-silica ignimbrites, usually densely welded. Dikes and domes are common too and rhyolitic lava flows occur at the top and intercalated to ignimbrites in the middle of the sequence. The acid rock association has a sodic alkaline affinity. In this unit we mapped a subvolcanic sill of trachyte showing evidence for magma mixing with the rhyolitic magma. It has sodic alkaline affinity, and FeOt/FeO + MgO ratios and agpaitic index lower than those recorded in the rhyolites/ignimbrites. The Acampamento Velho Formation includes in this area, subordinately, basalts as àà flows and dikes intercalated with acid rocks. They have sodic alkaline nature and characteristics of intraplate basic rocks. New zircon U-Pb dating indicates crystallization age of 560 ± 2 Ma in a densely welded ignimbrite, 560 ± 14 Ma for a mafic trachyte and 562 ± 2 Ma for a subvolcanic rhyolite. The sodic alkaline rocks in this region evolved by fractional crystallization processes and magma mixing with major crustal contribution at approximately 560 Ma. The chemical characteristics are similar to those of A-type granites associated with Neoproterozoic post-collision magmatism in the Sul-rio-grandense Shield.

Genesis and crystallization of ultramafic alkaline carbonatite magmas of Siberia: ore potential, mantle sources, and relationship with plume activity

This paper discusses the genesis of large Siberian alkaline massifs hosting major ore deposits. These reference massifs are grouped based on the predominance of alkalies (K or Na) and their agpaitic index (miaskitic and agpaitic). We proposed new emplacement schemes for the Tomtor, Murun, Burpala, Synnyr, and Bilibino massifs supported by petrochemical and geochemical data, as well as new age estimates. Types of their ore potential and genesis of rare-metal mineralization are discussed. The formational types of carbonatites as the main ore-bearing rocks are given. The depth of magma generation and types of mantle sources are determined using isotopic data from previous studies. A model of plume-related generation of ultramafic alkaline magmas is proposed.

Post-collisional subvolcanic rhyolites associated with the Neoproterozoic Pelotas Batholith, southern Brazil

Neoproterozoic volcanic and subvolcanic rhyolitic systems in southernmost Brazil are correlated with acid magmatism linked to different petrotectonic associations of the Sul-Rio-Grandense Shield. A portion of this volcanism in the Dom Feliciano Belt is associated with the Pelotas Batholith, which resulted from magmatic episodes associated with the Ediacaran post-collisional evolution of southern Brazil. Ana Dias Rhyolite is the main subvolcanic occurrence of this volcanism that took place in the Quitéria region, in the central part of Rio Grande do Sul State. The acid magmatism has been commonly associated with the most differentiated granite suite phases during the final stages of emplacement of the Pelotas Batholith. The Ana Dias Rhyolite is characterized as an intrusive body with rocks that present a porphyritic to seriated texture and a gradational variation to fine-grained equigranular rocks. New zircon U–Pb dating indicates crystallization age of 581.9 ± 1.9 Ma for the Ana Dias Rhyolite. Geochemistry data characterize the rhyolites as belonging to the alkaline series; they present a metaluminous to peraluminous character; elevated SiO2 and alkali concentrations, high FeOt/FeOt + MgO ratios and agpaitic index; and low Al2O3, CaO, and MgO contents. The Zr, Rb, Y, Nb, and Ga concentrations are moderate when compared with the relatively low Ba and Sr contents. These geochemistry characteristics are common in acid magmas with alkaline affinity. The behavior of certain trace elements and REE demonstrate enrichment in more incompatible elements, in addition to the negative anomaly of Ba, the slight enrichment in Ce relative to adjacent elements, as well as the enrichment in K2O and Rb relative to Nb, suggesting magmas derived from mantle sources enriched in incompatible elements with some crustal contamination. The chemical characteristics are similar to those of A-type granites associated with Neoproterozoic post-collision magmatism in the Sul-Rio-Grandense Shield.

Geochemistry of alkali and nepheline syenites of the Ukrainian Shield: ICP-MS data

We present new geochemical data on alkali and nepheline syenites from various complexes of different age within the Ukrainian Shield. The results reveal a correlation between the content of trace elements in the syenites, their assignment to a particular rock complex, the chemistry of primary melts, and the degree of their differentiation. The data also suggest regional geochemical heterogeneity in the ultramafic-alkaline complexes of the Ukrainian Shield. The alkali and nepheline syenites in the ultramafic-alkaline massifs from the eastern and western parts of the region exhibit similar REE contents and Eu/Eu* ratios but are markedly different in Nb, Ta, Zr, and Hf content and are of the miaskitic type. These rocks have lower REE, Nb, and Zr and higher Sr and Ba compared with early foidolites. The rocks of the gabbro-syenite complexes define a distinct Fe-enrichment fractionation trend from early syenitic intrusions to more differentiated varieties; they are also characterized by lower Sr, Ba, and Eu/Eu* and significantly lower contents of some major elements, e.g., Ti, Mg, and P. The agpaitic index and concentrations of Zr, Nb, Y, and REE increase in the same direction. A similar geochemical feature is observed in the alkali syenites genetically associated with anorthositerapakivi-granite plutons, which show incompatible-element enrichment and strong depletion in Sr and Ba. The distinctive evolutionary trends of alkali and nepheline syenites from different rock complexes of the Ukrainian Shield can be explained by different mechanisms of their formation. The main petrogenetic mechanism controlling the distribution of trace elements in the rocks of ultramafic-alkaline complexes was the separation of parent melts of melanephelinite and melilitite types into immiscible phonolite and carbonatite liquids. The gabbro-syenite complexes and alkali syenites from anorthosite-rapakivi granite plutons evolved via crystallization differentiation, which involved extensive feldspar fractionation.

GEOCHEMICAL AND PETROLOGICAL FEATURES OF THE ALKALINE GRANITES OF THE UKRAINIAN SHIELD

Alkaline granites in the Ukrainian Shield are not widespread and are only revealed in two areas. To first one belong the alkaline (with aegirine and ribekite) varieties among Proterozoic biotite-alkalic feldspathic Perga granites. Second area is Azov megablock where are found hypabyssal bodies of Devonian grorudites. Grorudites are of more melanocratic composition and have higher agpaitic index while low magnesity is the typical features for both types of alkaline granites. Perga alkaline granites and grorudites have different geochemical peculiarities. Grorudites have increased content of Ti, V, Cr, Ni, while Perga granites are enriched in Sn, Mo, Be, Rb, U. Like to alkaline granites over world alkaline granites of the Ukrainian Shield are, on the one hand enriched in HFSE and REE and, on the other hand – depleted in Sr and Ba. Chondrite normalized REE patterns from Perga granites have deep negative Eu-anomalus and enriched in HREE in comparison to grorudites. Geochemical peculiarities indicate that Perga granites are genetically related to granitic magmas of Korosten pluton and their formation have been attended by intensive feldspar fractionation. At the same time generation of grorudites are connected with subalkaline and alkaline basaltic melts differentiation during of the Dnieper-Donetsk depression formation.

Phlogopite/matrix, clinopyroxene/matrix and clinopyroxene/phlogopite trace-element partitioning in a calc-alkaline lamprophyre: new constrains from the Křižanovice minette dyke (Bohemian Massif)

Mineral/matrix and mineral/mineral partition coefficients were determined for clinopyroxene and phlogopite phenocrysts and their very fine-grained (chilled) groundmass from a Variscan calc-alkaline (agpaitic index = 0.6) lamprophyre dyke of minette composition from the Bohemian Massif (Krizanovice, Tepla-Barrandian Unit). This dyke is characterized by high MgO (8.9 wt. %; Mg-number = 69) at intermediate SiO2 content (53 wt. %). The partition coefficients (D) between clinopyroxene and matrix were determined for 23 elements by laser ablation-inductively coupled plasma-mass spectrometry. Calculated D-clinopyroxene/matrix values are very low, except for heavy rare earth elements (HREE) that range between 0.9 and 1.1. This suggests that HREE can be concentrated in clinopyroxene during crystallization from lamprophyre melt. In phlogopite, only 15 elements had contents above their respective detection limits. Phlogopite/matrix partition coefficients are on average higher than 1 (D-Ba = 1.1, D-Rb = 1.7 D-Ti = 1.5) and extremely low (<= 0.02) for light rare earth elements (LREE). On the other hand, D-phlogopite/matrix values for the majority of HREE could not be determined. Taken together, during simultaneous crystallization of clinopyroxene and phlogopite phenocrysts, Th, Zr, Hf, Y and LREE are preferentially partitioned into clinopyroxene and Ba with Rb and Ti into phlogopite.

Geology, petrography and geochemistry of the A-type granites from the Morro Redondo Complex (PR-SC), southern Brazil, Graciosa Province

The Morro Redondo Complex is one of the most important occurrences of the Graciosa A-type Province, southern Brazil. It consists of the Papanduva and Quiriri granitic plutons and a contemporaneous bimodal volcanic association. The Papanduva Pluton includes massive and deformed peralkaline alkali-feldspar granites with Na-Ca and Na-amphiboles and clinopyroxenes. The deformed types are the most evolved rocks in the province and carry rare ‘agpaitic’ minerals, some being described for the first time in granites from Brazil. The larger Quiriri Pluton comprises massive, slightly peraluminous, biotite syeno- and monzogranites with rare Ca-amphibole. Biotite compositions are relatively homogeneous, whereas sodic amphiboles and clinopyroxenes show increasing Na and Fe3+ evolving paths. The Morro Redondo granites are ferroan, with high SiO2, alkalis and HFSE contents; the peralkaline types registering the highest fe#. LILE and HFSE abundances increase with the agpaitic index and the most evolved are HHP granites, with radiogenic heat production up to 5.7 µWm–3. Geothermobarometric estimates indicate emplacement under low pressures (∼100 MPa), at temperatures up to 850-800 °C, and relatively reduced (QFM) and oxidized (+1 REPLACE_LT ΔQFM REPLACE_LT +3) environments for the Papanduva and Quiriri Plutons, respectively. In both cases, melts evolved to relatively high oxidation states upon crystallization progress.

Petrology and geochemistry of granitoids and their mafic micogranular enclaves (MME) in marginal part of the Małopolska Block (S Poland)

AbstractGranitic plutons (the Dolina Będkowska valley and Pilica area) were found in a few boreholes in the Małopolska Block (MB). These granitic rocks may represent apical parts (apophyses) of a great magmatic bodies (batholiths) located in deeper level of the Ediacaran/Paleozoic basement. They are described as ‘stitching intrusions’, generated during/after collision in Carboniferous/Permian period (~300 Ma) between the Upper Silesian Block (USB) and the Małopolska Block (MB).These rocks are fresh, unaltered granodiorites that are pale grey in colour. They have holocrystalline, medium- to coarse-grained structure and massive texture. For the first time, several mafic microgranular enclaves (MME), varying in size and colour, were found in the granodioritic host (HG). The occurrence of MME in the host granodioritic rocks is evidence of a mingling process between mafic and felsic magmas.The MME are pale/dark grey in colour, fine-grained rocks with ‘porphyritic’ textures. They consist of large megacrysts/xenocrysts of plagioclase, quartz, alkali feldspars and the fine-grained groundmass of pseudo-doleritic textures (lath-shaped plagioclases, blade-shaped amphiboles/biotites). According to their modal/mineral composition, they represent Q-diorites and tonalites.The MME, similar to the host granodiorites (HG), are I-type rocks, exhibit high Na2O content &gt;3.2 wt%; normative diopside or normative corundum occurs (mainly &lt;1%). They are metaluminous to slightly peraluminous (ASI &lt;1.1) and have calc-alkaline, medium-K to high-K character. They generally belong to magnesian series (#Mg=0.20-0.40) and have low agpaitic index (&lt;0.87). They are low evolved magmatic rocks. The rocks studied are enriched in LREEs (La, Ce, Sm) compared to HREEs. The Eu* negative anomaly and high Sr contents point to varying degrees of plagioclase fractionation connected to the mixing process rather than simple fractional crystallization. Both rocks studied (HG and MME) are characterized by a high content of LILEs (K, Ba, Rb) in normalized patterns and a low HFS/LIL elements ratio (Ta, Nb)/(K, Rb, La). The projection points of the rocks studied plot in different fields of various petrochemical diagrams: mainly in the arc granites that are rare in the pre-collisional granites as well as the syn-subductional to post-collisional granites fields.For the first time, inner textures in rock-forming minerals related to mixing processes are described both in the granodioritic host (HG) and in the MME. Mantled boxy cellular plagioclase megacrysts with ‘old cores’ of labradorite composition, and amphibole aggregates with titanite and opaque minerals, represent peritectic rather than primary residual minerals. The plagioclase, quartz and alkali feldspar megacrysts/xenocrysts were mechanically transferred from the granodioritic host (HG) to MME. The presence of lath-shaped plagioclases, blade-shaped amphiboles/biotites and acicular-shaped apatites in the groundmass of the MME is evidence of undercooling of hot mafic blobs in a relatively cold granodioritic magma chamber. The MME were hybridized by leucocratic melt squeezed from the granodioritic magma in a later stage of the mixing process (quartz and alkali crystals in the interstices in the MME groundmass). In the granodiorites (HG), the spike and spongy cellular zones as well as biotite/amphibole zones in plagioclase megacrysts are connected to the mixing process.Both of the rocks studied are characterized by different amounts of major elements (SiO2, Na2O and K2O), trace elements (Ni, Cr, V, Ti and P), #Mg and modified alkali-lime index (MALI) that is related to their origins from different sources. On the other hand, they have similar chondrite-normalized patterns (for trace elements and REE), LILEs contents (Sr, Ba, Rb), aluminum saturation index (ASI) and isotopic signatures (high 86Sr/87Sr (0.079-0.713) and low 143Nd/144Nd (0.512) values but lower than in continental crust), which are evidence of the strong hybridisation of mafic enclaves by the granodioritic host magma. The parental rocks of both rocks studied have a similar mafic signature but were generated in different sources: the host granodiorites (HG) magma in lower continental crust rocks, and the MME magma in enriched upper mantle. The MME crystallized from strongly hybridized magma of intermediate compositions (Q-diorite, tonalite) rather than from primary mafic magma. The host granodiorites (HG) originated from completely homogenized crustal granodioritic magma which inherited its geochemical signature from ancient arc-rocks in a subduction-related setting

Ordovician A-type plutons in the Antigonish Highlands, Nova Scotia1This article is one of a series of papers published in CJES Special Issue: In honour of Ward Neale on the theme of Appalachian and Grenvillian geology.

Previously unrecognized A-type granitoid and gabbroic rocks cover an area of ∼100 km2 in the central Antigonish Highlands in Avalonian northern mainland Nova Scotia. The granitoid rocks in this suite occur, together with minor gabbro, in separate mappable bodies named the Brora Lake, Haggarts Lake, West Barneys River, McGraths Mountain, and Leadbetter Road plutons and are the focus of this study. They are mainly alkali feldspar granite and quartz syenite with varied texture and modal mineralogy. Close spatial association, gradational contact relations, and magma-mingling relationships suggest that all of these rocks, including the gabbro, are coeval. Hence a U–Pb (zircon) age of 469.4 +/– 0.5 Ma obtained for a quartz syenite sample from the Brora Lake pluton is interpreted to indicate a Middle Ordovician age for all of these granitoid and gabbroic rocks. Most granitic and quartz syenitic samples have hypersolvus texture, characterized by strongly perthitic alkali feldspar, and some also contain interstitial granophyre, both features indicative of shallow emplacement. Mafic minerals include iron-rich calcic and calcic–sodic amphibole, hedenbergite, and in some samples fayalite. Most of the rocks have high concentrations of K, Na, P, Ti, and Fe and are alkalic, with agpaitic indices as high as 0.98. Discrimination diagrams indicate that they are A-type granitoid rocks formed in a within-plate extensional setting. Age correlatives of these A-type granitoid and gabbroic rocks are not yet known elsewhere in Avalonia. The available data suggest that this ca. 470 Ma magmatism occurred while Avalonia was a separate microcontinent in the Rheic Ocean.