Curing Ages Research Articles

A Curing Agent for Facile Fabrication of Intrinsically Flame-Retardant Epoxy Vitrimers with Catalyst-Free Mixed Carboxylate/Phosphonate Transesterification

A Curing Agent for Facile Fabrication of Intrinsically Flame-Retardant Epoxy Vitrimers with Catalyst-Free Mixed Carboxylate/Phosphonate Transesterification

Evaluation of Celery Juice Powder as a Natural Curing Agent for Tocino

Evaluation of Celery Juice Powder as a Natural Curing Agent for Tocino

Study on mechanical behavior of inclined cemented tailings composite backfill (CTCB) under uniaxial compression

The goaf volume in the vacancy method of hard rock mines is significantly larger than the filling capacity, forming layered and inclined planes during the large-scale filling process. This results in unclear mechanical impact mechanisms on the backfill. To investigate the effect of interface inclination angle on the mechanical behavior of backfill, a set of cemented tailings composite backfill (CTCB) samples with interface inclination angles of 15°, 30°, and 45° are prepared. Uniaxial compression tests and digital image correlation techniques are used to investigate the influence of various interface inclination angles on the strength, deformation behavior, and failure mode of the CTCB. The results show that: (1) The uniaxial compressive strength (UCS) of the CTCB weakens with increasing interface inclination angle but consistently shows exponential growth with curing age (CA) regardless of the interface inclination angle. (2) The interface inclination angle controls the behavior and classification characteristics of the stress-strain curve of CTCB samples, and the increase of interface inclination angle weakens the elastic modulus. (3) The interface inclination angle significantly influences the failure mode and classification characteristics of the samples compared to CA and tailing-to-cement ratio (TCR), with shear slip failure induced by the former and axial splitting failure induced by the latter. The research provides a theoretical basis for understanding the mechanical behavior and stability control of inclined CTCB in underground mining.

Autonomous Self-Healing Agents in Cementitious Materials: Parameters and Impacts on Mortar Properties

The concept of self-healing materials and the development of encapsulated curing agents represent a cutting-edge approach to enhancing the longevity and reducing the maintenance costs of cementitious structures. This systematic literature review aims to shed light on the parameters involved in the autonomous self-healing of cementitious materials, utilizing various encapsulated healing agents such as pellets, granules, and capsules. This review also identifies and selects studies that offer additional insights into the efficacy of the self-healing process in cementitious materials and the influence of these specific encapsulated healing agents on the physical mechanical properties of mortars. This comprehensive approach provides a deep understanding of the interplay between self-healing and the physical–mechanical properties of mortars containing these encapsulated healing agents. The main findings indicate that the cement-to-sand ratio, characteristics of fine aggregates, and encapsulation methods significantly impact crack control, self-healing efficiency, and properties of mortar in both fresh and hardened states. The content of encapsulated healing agents within the cementitious matrix affects both the initial workability or flow and subsequent mechanical properties. While pellets coated with PVA film typically reduce workability in the fresh state and compressive strength, capsules coated with Portland cement and sodium silicate mitigate these effects and improve crack sealing in fresh and hardened states without compromising the self-healing capacity of cracks. The three-point flexural test has emerged as the preferred method for a pre-crack assessment over 28 days, with variations depending on the type of healing agent used. As noted in the literature, water has been identified as the optimal environment for autonomous healing. These findings underscore the potential of encapsulation techniques to enhance self-healing capabilities through the controlled release of agents within the cementitious matrix, thereby advancing the research on and development of intelligent construction materials and increasing the durability of cement-based structures.

Effect of alkaline rice straw fibers content and curing ages on static mechanical properties of cemented lithium mica tailings backfill

Alkaline rice straw fibers (ARSF), as a widely available and recyclable plant fiber source, can provide new insights for improving the mechanical properties of backfill and the treatment of agricultural waste resources research. Different amounts of ARSF were prepared to enhance the cemented lithium mica tailings backfill (CLMTB), and uniaxial compression strength (UCS) tests and Brazilian splitting tensile strength tests were conducted to study the influence of ARSF on the static mechanical properties of CLMTB samples. Firstly, the flowability of mortars with different ARSF content was tested, the results showed that the flowability decreased by a maximum of 5.4 %, which met the construction requirements of cement mortar in the construction process. The UCS showed an increasing trend and then reduced with the increased ARSF content, with 0.15 % being the optimal content, showing a maximum increase of 14.2 %. Under Brazilian splitting loading conditions, the tensile strength gradually increased with the increased ARSF content, with 0.60 % being the optimal content. The UCS of the CLMTB samples showed exponential growth with increased curing age. Additionally, there was a linear functional relationship between the curing age and the tensile strength of the CLMTB samples. The experimental results indicate that the ARSF improved the toughness and changed the failure mode of the CLMTB samples. In the meantime, it increased the residual bearing capacity and the peak tensile strain of the CLMTB samples.

Unveiling the combined influence of higher molecular weight polyethylene glycol and superplasticizer chemistry on fresh, mechanical, and microstructural performance of internally cured mortar

The limitations of conventional water curing in tall structures and arid regions necessitate alternative hydration strategies. Use of internal curing agents in high strength concrete can effectively mitigate evaporation and promote enhanced cement hydration in the concrete. However, because the superplasticizer is a required component in high strength concrete, compatibility of the internal curing agent with superplasticizer needs to be investigated. This study investigates the efficacy of internal curing (IC) using polyethylene glycols (PEGs)–PEG 4000 and PEG 6000, in conjunction with superplasticizer from two different families, polycarboxylate ether (PCE) and sulphonated naphthalene formaldehyde (SNF) in mortar mixes. A total of ten mixes were prepared for which samples from each mix were exposed to standard water curing, room curing, and internal curing. The research outcomes reveal a novel application of PEG 6000 and PEG 4000 in conjunction with PCE-based superplasticizers at optimized dosages, presenting a promising avenue for direct implementation in mortar mixes to meet both mechanical and durability prerequisites. Optimized IC mortar mixes displayed comparable or superior mechanical and durability performance to conventionally cured counterparts. This study demonstrates the potential of PEG 6000-PCE combinations as IC agents for improved fresh and hardened properties, offering a viable alternative for challenging construction environments. Further research is warranted to explore the long-term performance and economic feasibility of IC mortars in large-scale projects.

Micromechanical and chemical characteristics of interfacial transition zone in alkali-activated slag concrete containing lightweight iron-rich aggregates

This study explored the time-varying alkali-activation effects of the lightweight aggregates (LWA) on the interfacial transition zone (ITZ) of the alkali-activated slag concrete with different curing ages, molar ratios, and alkali concentrations from 28 to 300 d. The improved micromechanical performance of the ITZ at 28 d stemmed from the early-age internal curing effect of the porous LWA. However, the post-28 d internal curing effect diminished, with the alkali-activation dominating the performance of the ITZ from 28 to 300 d. Although alkali-activated cement possessed early strength characteristics, the deconvolved phase results illustrated that alkali activation persisted in the ITZ between the LWA and cement from 28 to 300 d, leading to a high proportion of calcium silica aluminate hydrate. As a marker, Fe from the lightweight iron-rich aggregates mitigated into the alkali-activated cement, demonstrating the alkali-activated reaction between the LWA and alkali-activated slag matrix. Molecular dynamics simulations further characterized that the low content of Fe did not decrease the overall strength of the ITZ. The interfacial interaction energy revealed the alkali-activation between the LWA and cement compensated for the weakening of mechanical properties caused by Fe ions on the ITZ.

Employing limestone and calcined clay for preserving the strain-hardening response of PET fiber-reinforced cementitious composites

The degradation of polyethylene terephthalate (PET) fibers in alkaline environments limits their use in strain-hardening cementitious composites (SHCC). Prolonged PET exposure to alkaline environments has a detrimental effect on its mechanical performance, mainly due to the physicochemical transformation caused by alkaline hydrolysis. This study presents a tailored cementitious matrix design containing high amounts of limestone and calcined clay, replacing 75 wt% of Portland cement, to attain and maintain the strain-hardening response of composites incorporating PET fibers as dispersed reinforcement. Analytical and mechanical tests were carried out at different curing ages, ranging from 7 to 60 days, to study the effects of aging on virgin PET fibers, both within the matrix and outside it (in the pore solution). The results showed a pronounced degradation of the PET fibers in the test pore solution at pH 12.5, manifested by a progressive reduction in the load-bearing capacity of the individual fibers with prolonged immersion. Conversely, when the PET fibers were aged in-matrix under laboratory conditions and tested under tension, the performance of the corresponding composites showed resilience to aging, exhibiting reasonable tensile strength and remarkable strain capacities that exceeded 4 %.

Dynamic response and deformation failure microscopic characteristics of cyclic impact-cemented tailing backfill.

Frequent blasting disruptions can lead to cumulative damage within the cemented tailing backfill (CTB), increasing the risks associated with mining operations and reducing the recovery rate of the pillar. To address this issue, the Split Hopkinson Pressure Bar (SHPB) was utilized to conduct cyclic impact tests on CTB containing various cement tailing ratios (CTR) at different curing ages. The tests analyzed the stress-strain curve law, dynamic compressive strength (DCS), dynamic strength increase factor (DIF), absorption energy, and deformation failure characteristics of CTB under different impact velocities. Additionally, nuclear magnetic resonance (NMR) and scanning electron microscopy (SEM) were employed to investigate the internal pore structural properties of CTB. The research findings indicate that (1) Average strain rate exhibits a linear relationship with the DCS and impact velocity. A lower number of impacts occurred at higher impact velocities and shorter curing age. The number of impacts was drastically reduced when the impact velocity surpassed 3m/s. As the CTR increased, the number of impacts also increased. When the number of impacts increased, the elastic modulus, dynamic impact strength, and peak strain initially increased before ultimately decreasing. (2) Under the cyclic impact load, the shear failure and axial splitting failure were the main failure modes of CTB. Increasing the CTR may be a more effective strategy for reducing the degree of CTB fragmentation compared to prolonging the curing age. When the impact velocity is lower than 3m/s, CTB can withstand multiple impacts and maintain high levels of integrity. When the DIF of the first shock is below 1.5, the CTB demonstrates a capability to withstand more than four shocks. If the DIF exceeds 2, the CTB can only endure a single shock. (3) NMR and SEM observations revealed that CTB itself contains more pores. A dense network structure will grow inside CTB as the curing age and CTR are increased, reducing the porosity. The pore size observed in the samples also support that increasing CTR may be a more effective strategy. Our findings contribute to a better understanding of the kinetic response of CTB in deep mines under frequent blasting disruption and offer a valuable reference point for future research in this area.

Dynamic properties of alkali residue-based foamed concrete under cyclic load

Alkali residue-based foamed concrete (A-FC), consisting of cement, alkali residue, blast furnace slag, and foam, has great potential for application in subgrade engineering. A series of dynamic triaxial tests were conducted, and the influences of confining pressure, vibration frequency, and curing age on the dynamic properties of A-FC was revealed. Test results indicated that the backbone curves of A-FC exhibit a hyperbolic shape, effectively captured by the H-D model. After 7 days of curing, A-FC possessed robust dynamic bearing capacity. As the dynamic strain increases, the dynamic elastic modulus of A-FC exhibits an initial rise followed by a gradual decline. Concurrently, the damping ratio demonstrates an initial decrease and subsequent gradual increase. Elevated confining pressure, prolonged curing age, and higher vibration frequency were found to contribute to a progressive increase in the dynamic elastic modulus of A-FC. Throughout the damping ratio growth stage, the increasing curing age and confining pressure led to the decrease of damping ratio, with minimal influence from vibration frequency. A calculation model for the maximum dynamic elastic modulus of A-FC was proposed, considering confining pressure, vibration frequency, and curing age. This research underscores the capacity of A-FC to withstand cyclic loading, thereby offering valuable support for its engineering applications.

The influence of blast furnace slag on the mechanical properties and mesoscopic damage mechanisms of recycled aggregate concrete compared to natural aggregate concrete at different ages

To improve the mechanical property defects caused by recycled aggregate (RCA) in recycled aggregate concrete (RAC) as well as the effect of blast furnace slag (BFS) addition on the mechanical properties and microscopic damage mechanisms of natural aggregate concrete (NAC) and RAC at long ages. In this paper, the effects of different curing ages (T = 7d, 14d, 28d, 56d, 90d, and 150d) and blast furnace slag contents on the mechanical properties and microscopic damage mechanisms under uniaxial compression of NAC and RAC were investigated, where the cement substitution rate of BFS was 0 % and 35 % (water-cement ratio of 0.46, water-reducing agent dosage of 0.25 %), respectively. Nuclear magnetic resonance (NMR) and scanning electron microscopy (SEM) were used to study the internal pore changes and the generation of hydration products in the specimens, and acoustic emission (AE) showed the microcrack development process. The results showed that the peak stress and modulus of elasticity of the specimens gradually increased with increasing age, the peak strain gradually decreased, and the internal porosity gradually decreased. It is worth noting that the addition of BFS caused the mechanical properties of RAC to decrease at 28 days but enhanced the mechanical properties of RAC at 56–120 days. This was attributed to the fact that the properties of BFS were not yet activated in the early stage, whereas it was activated in the later stage under an alkaline environment and reacted with CH to generate more C–S–H hydration products, which enhanced the interfacial transition zone and reduced the porosity. This highlights the potential of BFS to improve the performance of RCA over long periods of time. In contrast, BFS improved the mechanical properties of NAC throughout the age period and more significantly after 56 days. AE results showed that the peak ring counts lagged behind the peak stresses. Finally, combined with the statistical damage principal model, the fitting was performed by Matlab to analyze the microscopic damage mechanism of the specimen during uniaxial compression. It was found that the changes in the four characteristic parameters (εa, εb, εh and H) followed a certain regularity, reflecting the regular changes in fracture damage and yield damage. This revealed the intrinsic linkage between mesoscopic damage mechanisms and macroscopic mechanical properties. It was demonstrated that it was feasible to speculate on the law of the stress-strain curve at the macroscopic level by using the law of change of the four parameters (εa, εb, εh and H) at the microscopic level.

Experimental investigation on fractal mechanism and shear failure characteristics of cement mortar at different curing ages

In this paper, the NMR and direct shear tests were conducted successively on cement mortar specimens with different curing ages (7 days, 14 days and 28 days). The porosity, shear strength, shear stiffness and shear energy of cement mortar are measured and analyzed through interpreting the pore distribution patterns and their corresponding fractal dimensions. The cross-sections of shear surface were characterized into point cloud data via 3D laser scanning and quantified by three dimensionless parameters (the root mean square value of the first derivative, root mean square value and joint roughness coefficient). The grey relation analysis (GRA) method and principal component analysis (PCA) is employed to analyze the relationship between the pore structures (i.e., gel pores, transition pores, capillary pores and pores or cracks) and distribution and the fractal dimensions. The results indicate that the shear peak strength is linearly correlated with the joint roughness coefficient. Compared to the fractal characteristics of pore size (T2 spectra) and pore distribution (MRI), we demonstrated that there is a strong correlation between the peak shear strength and the fractal dimension of shear fracture surface, which suggests that the quantitative characterization of internal pores and shear strength variations in cement mortar specimens can be achieved through the numerical values of fractal dimensions.

Construction Management by Controlling the Design and Curing Time of a Concrete Mix

Abstract The interval of time after pouring concrete is an important factor, which directly affects the timing and cost of construction. The case study that was investigated in this research, is a tunnel project located in Iran. Eighteen mix designs were prepared using properties such as different water-cement ratios and the use of two types of superplasticizer with different dosages. The optimal mix designs among the samples were separately specified. Concrete mix designs with different curing ages were made to specify the minimum curing time in which the concrete could gain the required compressive strength. Moreover, the concrete’s compressive strength was measured for different ages in order to determine the minimum time interval. For a better insight, two mathematical equations were derived to estimate the minimum curing time and time interval. Finally, a statistical analysis was conducted in order to determine the proper time intervals. Moreover, the analysis specified the impact rate of the research parameters (i.e. the type and dosage of superplasticizer, curing time, and water-cement ratio) on the compressive strength

Preparation of a Flame-Retardant Curing Agent Based on Phytic Acid-Melamine Ion Crosslinking and Its Application in Wood Coatings.

To broaden the applications of wood, it is necessary to prepare flame-retardant coatings that can protect wood substrates during combustion. In this study, a bio-based, intumescent, flame-retardant phytic acid-melamine polyelectrolyte (PM) was prepared using phosphorus-rich biomass phytic acid and nitrogen-rich melamine as raw materials through an ion crosslinking reaction. Subsequently, a series of bio-based, flame-retardant wood coatings were prepared by optimizing the structure of urea-formaldehyde resin with the addition of melamine, sodium lignosulfonate, and PM as a flame-retardant curing agent. Woods coated with PM-containing coatings displayed significantly improved flame-retardant performances in comparison to uncoated woods. For PM-cured woods, the measured values of total heat release and total smoke production were 91.51% and 57.80% lower, respectively, compared with those of uncoated wood. Furthermore, the fire growth index decreased by 97.32%, indicating a lower fire hazard. This increase in flame retardancy and smoke suppression performance is due to the dense expanded carbon layer formed during the combustion of the coating, which isolates oxygen and heat. In addition, the mechanical properties of the flame-retardant coatings cured with PM are similar to those cured with a commercial curing agent, NH4Cl. In addition, the prepared flame-retardant coating can also stain the wood. This study proves the excellent flame-retarding and curing effect of ammonium phytate in urea-formaldehyde resin coatings and provides a new approach for the application of bio-based flame retardants in wood coatings.

Assessment of interface characteristics and durability aspects of manufactured sand (M-sand) in engineered cementitious composites

Concrete structures usually tend to crack and cause several distresses, thus resulting in regular maintenance activities. Engineered Cementitious Composites (ECC) in structural applications are becoming popular due to their cracking resistance and deformability. However, the conventional mix design of ECC with silica sand levied a negative influence on cost and drying shrinkage, thereby affecting their practical implementation. In this study, the matrix properties and interface characteristics of ECC tailored with Manufactured sand (M-sand) replacing the river sand at varying proportions were investigated. The study conducted mechanical characterization, matrix fracture toughness, and single-crack tension tests to evaluate the micro-mechanical properties and fiber-matrix interaction. Furthermore, the shrinkage characteristics and permeability properties of ECC mixtures were also evaluated at various replacement levels of M-sand. The natural river sand adhered to the finer gradation, characterized by a fineness modulus of 1.63, while the M-sand exhibits a coarser gradation, having a fineness modulus 2.74. The experimental results showed that the ECC mixtures with M-sand improved the compressive strength (up to 29 %) at 100 % replacement level and marginally influenced the tensile strength. However, the tensile ductility and fiber bridging characteristics showed a noticeable decrease as the percentage replacement increased in the mixtures. On the other hand, the drying shrinkage of all M-sand ECC mixtures showed a notable reduction irrespective of the curing ages. It is also seen that the permeability properties were slightly increased compared to that of the control mixture. In summary, the study observed a trade-off between mechanical strength and tensile ductility, highlighting the effects of fiber-matrix interface tailoring on the overall performance of ECC mixtures with M-sand for various structural applications.

Mechanical, durability and microstructural characterization of cost-effective polyethylene fiber-reinforced geopolymer concrete

Portland cement is widely used in the construction industry. Its production contributes to carbon dioxide emissions, urging the need for sustainable alternatives. The present study aims to evaluate the strength, durability, microstructural properties, and cost-effectivity of geopolymer (GP) concrete containing polyethylene (PE) fibers, with fly ash (FA), ground-granulated blast furnace slag (GGBFS), and calcium magnesium carbonate (CaMg(CO3)2 known as dolomite) as binders. PE fiber used has an ultra-high molecular weight. Six different mixtures were produced with FA, GGBFS, dolomite, and/or PE fiber. The control mix used only FA as a binder without PE fiber. Fresh and mechanical properties, including slump value, compressive strength, and split tensile strength, were determined, and non-destructive tests, such as electrical resistivity and ultrasonic pulse velocity, were conducted. The durability of GP was evaluated through initial surface absorption and capillary suction absorption tests at different curing ages. Microstructural and mineralogical characteristics were analyzed using scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier-transform infrared spectroscopy (FTIR). The results revealed that the addition of PE fibers and CaMg(CO3)2 reduced the workability of GP by 30.22% in comparison with that of PE fiber along with GGBFS. Compared to the reference mix at 28 days, incorporating 20% GGBFS resulted in the highest improvement of 76.89% and 104.86% in compressive and split tensile strength, respectively. GP sample with 20% GGBFS replacement of FA presented the highest reduction of 44.4–41.63% for initial and secondary rate of absorption. SEM analysis showed that the addition of GGBFS and CaMg(CO3)2 to fiber-reinforced FA-based geopolymer mixes developed a denser and more homogenous matrix with improved mechanical behavior due to the co-existence of C−S−H and aluminosilicate gel. PE fibers improve the toughness properties by helping to absorb energy and bridging cracks. The development of a stronger matrix was characterized by C−S−H, calcium aluminate oxide (carbonate) hydroxide (C4AHx) and quartz. A one-way ANOVA analysis and cost analysis demonstrate the cost-effectiveness of partially replacing FA with CaMg(CO3)2 and GGBFS in PE fiber-reinforced GP concrete.

Mitigation of zinc and organic carbon leached from end-of-life tire rubber in cementitious composites

End-of-life tire (ELT) rubber has been widely researched to replace fine or coarse aggregates in cementitious composites. While most studies paid attention to its effect on the engineering properties, very few considered chemical reactions with pore solution and the potential for environmental leachate. Recently the authors developed a methodology to remove zinc from the ELT rubber, since zinc can be toxic if it is leached into the environment. In this study, the authors utilized ELT rubber before and after the zinc extraction process to partially replace fine aggregate in a mortar. Flowability, compressive strength, flexural strength, and ultrasonic pulse velocity were measured for the engineering properties of rubberized mortars. Simultaneously, isothermal calorimetry was also employed to investigate the effects of ELT rubber on the hydration process of the rubberized mortars. In addition, the pore solution and leaching solutions were taken at different curing ages and then analyzed for elemental and total organic carbon (TOC) contents. The results showed a remarkable loss in engineering properties of rubberized mortar when ELT rubber was utilized, and the decrease in performance was more pronounced in the samples with zinc-extracted ELT rubber. The pore solution was found to contain significant quantities of zinc and TOC. However, the authors also found that using silica fume to partially replace cement could effectively recover the loss in strength and could reduce the leachability of zinc and TOC.

Study on Static Mechanical Properties and Numerical Simulation of Coral Aggregate Seawater Shotcrete with Reasonable Mix Proportion

This study aims to explore the static mechanical characteristics of coral aggregate seawater shotcrete (CASS) using an appropriate mix proportion. The orthogonal experiments consisting of four-factor and three-level were conducted to explore an optimal mix proportion of CASS. On a macro-scale, quasi-static compression and splitting tests of CASS with optimal mix proportion at various curing ages employed a combination of acoustic emission (AE) and digital image correlation (DIC) techniques were carried out using an electro-hydraulic servo-controlled test machine. A comparative analysis of static mechanical properties at different curing ages was conducted between the CASS and ordinary aggregate seawater shotcrete (OASS). On a micro-scale, the numerical specimens based on particle flow code (PFC) were subjected to multi-level microcracks division for quantitive analysis of the failure mechanism of specimens. The results show that the optimal mix proportion of CASS consists of 700 kg/m3 of cementitious materials content, a water–binder ratio of 0.45, a sand ratio of 60%, and a dosage of 8% for the accelerator amount. The tensile failure is the primary failure mechanism under uniaxial compression and Brazilian splitting, and the specimens will be closer to the brittle material with increased curing age. The Brazilian splitting failure caused by the arc-shaped main crack initiates from the loading points and propagates along the loading line to the center. Compared with OASS, the CASS has an approximately equal early and low later strength mainly because of the minerals’ filling or unfilling effect on coral pores. The rate of increase in CASS is swifter during the initial strength phase and decelerates during the subsequent stages of strength development. The failure in CASS is experienced primarily within the cement mortar and bonding surface between the cement mortar and aggregate.

An Experimental Study on the Mechanical Properties and Microstructure of the Cemented Paste Backfill Made by Coal-Based Solid Wastes and Nanocomposite Fibers under Dry-Wet Cycling.

The mechanical properties and microstructure of the cemented paste backfill (CPB) in dry-wet cycle environments are particularly critical in backfill mining. In this study, coal gangue, fly ash, cement, glass fiber, and nano-SiO2 were used to prepare CPB, and dry-wet cycle tests on CPB specimens with different curing ages were conducted. The compressive, tensile, and shear strength of CPB specimens with different curing ages under different dry-wet cycles were analyzed, and the microstructural damage of the specimens was observed by scanning electron microscopy (SEM). The results show that compared with the specimens without dry-wet cycles, the uniaxial compressive strength, tensile strength, and shear strength of the specimens with a curing age of 7 d after seven dry-wet cycles were the smallest, being reduced by 40.22%, 58.25%, and 66.8%, respectively. After seven dry-wet cycles, the compressive, tensile, and shear strength of the specimens with the curing age of 28 d decreased slightly. The SEM results show that with the increasing number of dry-wet cycles, the internal structure of the specimen becomes more and more loose and fragile, and the damage degree of the structural skeleton gradually increases, leading to the poor mechanical properties of CPB specimens. The number of cracks and pores on the specimen surface is relatively limited after a curing age of 28 d, while the occurrence of internal structural damage within the specimen remains insignificant. Therefore, the dry-wet cycle has an important influence on the both mechanical properties and microstructure of CPB. This study provides a reference for the treatment of coal-based solid waste and facilitates the understanding of the mechanical properties of backfill materials under dry-wet cycling conditions.

Experimental research on influence of curing environment on mechanical properties of coal gangue cementation

Abstract To investigate the impact of curing environments on the mechanical properties of coal gangue cementation (CGC), various curing methods were established, including standard bag curing, standard curing, natural sealing curing, natural curing, water curing, and varying curing ages. By examining the uniaxial compressive strength (UCS) and stress–strain relationship of CGC by applying axial loads, the influence mechanism was analyzed in terms of both physical and chemical reactions. Furthermore, a mechanistic structural model was established to illustrate the impact of the curing environment on the mechanical properties of CGC. The primary substances and reasons affecting the mechanical properties of CGC were analyzed through the use of scanning electron microscopy and X-ray diffraction techniques. Evaluation of influence factors on CGC mechanical properties by grey correlation degree. The findings indicate that curing temperature, humidity, and carbonization are the principal factors influencing the UCS. Maintaining constant temperature and humidity while isolating CO2 is conducive to improving the UCS. The hydration products, such as needle-like ettringite and white fibrous calcium silicate hydrogel, fill the internal voids of CGC and are the primary substances affecting UCS. The hydration products formed during standard curing and natural curing of CGC can undergo carbonation with CO2 to form CaCO3, which interacts with ettringite and hydrated calcium silicate to provide strength support for CGC. However, beyond a certain age, CO2 will progressively diminish the UCS; the larger the contact area and the longer the exposure time to the gel materials in CGC, the faster the UCS decreases.