Aeolian Islands Research Articles

Role of Bacterial Exopolysaccharides as Agents in Counteracting Immune Disorders Induced by Herpes Virus.

Extreme marine environments, such as the submarine shallow vents of the Eolian Islands (Italy), offer an almost unexplored source of microorganisms producing unexploited and promising biomolecules for pharmaceutical applications. Thermophilic and thermotolerant bacilli isolated from Eolian vents are able to produce exopolysaccharides (EPSs) with antiviral and immunomodulatory effects against Herpes simplex virus type 2 (HSV-2). HSV-2 is responsible for the most common and continuously increasing viral infections in humans. Due to the appearance of resistance to the available treatments, new biomolecules exhibiting different mechanisms of action could provide novel agents for treating viral infections. The EPSs hinder the HSV-2 replication in human peripheral blood mononuclear cells (PBMC) but not in WISH (Wistar Institute Susan Hayflic) cells line, indicating that cell-mediated immunity was involved in the antiviral activity. High levels of Th1-type cytokines were detected in PBMC treated with all EPSs, while Th2-type cytokines were not induced. These EPSs are water soluble exopolymers able to stimulate the immune response and thus contribute to the antiviral immune defense, acting as immunomodulators. As stimulants of Th1 cell-mediated immunity, they could lead to the development of novel drugs as alternative in the treatment of herpes virus infections, as well as in immunocompromised host.

New insights on the subsidence of Lipari island (Aeolian islands, southern Italy) from the submerged Roman age pier at Marina Lunga

Lipari island belongs to the Aeolian archipelago, located in the Southern Tyrrhenian Sea (Italy), which is one of the most active volcanic areas of the Mediterranean basin. Although this region has been settled since prehistory, only during Roman times were coastal installations built in these islands. In this study, we present and discuss data on the relative sea level change estimated from a submerged pier of Roman age dated 2100 ± 100 BP. This structure, about 140 × 60 m, is located along the coast of Marina Lunga, corresponding to the present location of the main harbor of Lipari island. This pier, which was accidentally discovered in 2008 during preliminary excavations for the construction of a new pier, is a valuable indicator of relative sea level changes and vertical land movements. Its top surface is presently located at −9.1 ± 0.05 m, while the foundations at the outer end of the pier are at −11.6 ± 0.05 m, above a shoreline placed at −13.0 ± 0.05 m. We studied this site through direct archaeological investigations and ultra-high resolution multibeam bathymetry.The current submergence of this pier can be explained by the cumulative effect of the relative sea level changes caused by the regional glacio-hydro-isostatic signal, active since the end of the last glacial maximum, and the local volcano-tectonic land subsidence. From our investigations, a relative sea level change at 12.3 ± 0.7 m with a subsidence rate at 5.79 ± 0.01 mm y−1 and an average value of volcano-tectonic contribution at 5.17 ± 0.01 m y−1 for the last 2100 ± 100 years BP, is estimated from comparison against the latest predicted sea level model for the Southern Tyrrhenian Sea. These rates of relative sea level change led to the disuse of the harbor after around the fourth century AD, in agreement with archaeological interpretations. Our results provide new insights on the recent evolution of this active volcanic area.

Campostriniite, (Bi3+,Na)3(NH4,K)2Na2(SO4)6·H2O, a new sulfate isostructural with görgeyite, from La Fossa Crater, Vulcano, Aeolian Islands, Italy

AbstractThe new mineral campostriniite, (Bi3+,Na)3(NH4,K)2Na2(SO4)6·H2O, was found in an active fumarole (fumarole FA, temperature ∼350°C) at La Fossa Crater, Vulcano, Aeolian Islands, Sicily, Italy. It occurs on a pyroclastic breccia as white prismatic crystals up to 0.2 mm long, in association with adranosite, demicheleite-(Br), demicheleite-(I), argesite and sassolite. The mineral is monoclinic, space group: C2/c (no. 15) with a = 17.748(3), b = 6.982(1) c = 18.221(3) Å, β = 113.97(1)°, V = 2063(1) Å3 and Z = 4. The six strongest reflections in the powder X-ray diffraction pattern are: [dobs in Å (I)(hkl)] 6.396(100)(110), 7.507(75)(202), 2.766(60)(316), 3.380(57)(312), 5.677(55)(111), 3.166(50)(4 0 2). The empirical formula (based on 25 anions p.f.u.) is Bi2.41N1.52Na2.41K0.48 S6.07H8.08O25. The calculated density is 3.87 g cm–3. Using single-crystal diffraction data, the structure was refined to a final R(F) = 0.051 for 3025 independent observed reflections [I > 2σ(I)]. Campostriniite is isostructural with görgeyite and belongs to the 7.CD group of the Strunz classification system. The structure contains two independent nine-fold coordinated sites, one of them located on a two-fold axis (M1) and the other one in general position (M2) essentially occupied by Bi3+ atoms and minor amounts of Na+ ions, an eight-fold coordinated site fully occupied by Na +ions and another eight-fold coordinated site occupied by NH+4 and K+ ions; three independent sulfate anions in a general position and a water molecule coordinated to M1 and located on a two-fold axis are also present.

Geophysical investigation of Pleistocene volcanism and tectonics offshore Capo Vaticano (Calabria, southeastern Tyrrhenian Sea)

Magma upwelling forming volcanic plumbing systems in back arc settings is typically controlled by extensional tectonic structures of the upper crust. Here we investigate this process in the area between the volcanic arc of the Aeolian Islands and the Calabrian arc (SE Tyrrhenian Sea) by integrating morpho-bathymetry and reflection seismic data with the outcomes of “Inverse 3D magnetic modeling” of previously gathered aeromagnetic data. Morpho-bathymetric data highlight the presence of a seamount ∼10km offshore Capo Vaticano Promontory (eastern Calabria). This feature, named Capo Vaticano seamount is composed of a series of NE-trending ridges, the greatest of which (R1) is ∼12km long, and 2.4km wide, displays asymmetric flanks with a landward steep slope, oblique morphological steps and elongated NE-trending rims. The position of the R1 ridge summit fits the Reduced-to-the-Pole peak of a high-intensity magnetic anomaly straddling Capo Vaticano Promontory and its offshore prolongation. Seismic and bathymetric data highlight two extensional fault systems affecting the offshore of Capo Vaticano Promontory during the Plio-Pleistocene: (a) a Pliocene NW-trending, SW-dipping normal fault system, and (b) a Pleistocene NE-trending, SE-dipping normal fault system. The younger system is composed of a series of en-echelon branching normal faults bounding the eastern side of the R1 ridge. Aeromagnetic data modeling imaged a complex 3D-magnetized body below the R1 ridge exhibiting a sub-vertical conduit-like structure in the shallow part, and a NE-striking, sheet-like shape inclined by 45° in depth. The location of the sub-vertical conduit coincides with the summit of the R1 ridge. The magma uprising at the root of the volcano was controlled by the Pliocene NW-trending faults whereas its further upwards migration was ostensibly controlled by the Pleistocene NE-trending faults. Both fault systems are responsible for the high level of fracturing that likely favored the upward migration of magma. The younger extensional systems also controls the present-day, mantle derived, fluid escapes observed at the summit of the R1 ridge. Relying on seismic stratigraphic evidence as well as the normal polarity of the magnetic anomaly, the R1 ridge probably started to form during the Olduvai chron (early Pleistocene, 1.81–1.96Ma). Accordingly, the Capo Vaticano volcano may represent the result of magmatic activity that predates the Aeolian volcanic arc.

Active upper crust deformation pattern along the southern edge of the Tyrrhenian subduction zone (NE Sicily): Insights from a multidisciplinary approach

Using a multidisciplinary dataset based on gravimetric, seismic, geodetic and geological observations, we provide an improved picture of the shallow structure and dynamics of the southern edge of the Tyrrhenian subduction zone. With a local earthquake tomography we clearly identify two main crustal domains in the upper 15km characterized by different P-wave velocity values: a high-velocity domain comprising southeasternmost Tyrrhenian Sea, NE Sicily and Messina Straits, and a low-velocity domain comprising Mt. Etna and eastern Sicily. The transition between the two domains shows a good spatial correspondence with a wider set of faults including the Taormina Fault System (TFS) and the Aeolian–Tindari–Letojanni Fault System (ATLFS), two nearly SE-striking fault systems crossing northeastern Sicily and ending on the Ionian shoreline of Sicily according to many investigators. Within this set of faults, most of the deformation/seismicity occurs along the northern and central segments of ATLFS, compared to low activity along TFS. A lack of seismicity (both recent and historical) is observed in the southern sector of ATLFS where, however, geodetic data reveal significant deformation. Our multidisciplinary dataset including offshore observations suggests the southeastward continuation of the ATLFS into the Ionian Sea until joining with the faults cutting the Ionian accretionary wedge described in the recent literature. Our findings imply the existence of a highly segmented crustal shear zone extending from the Aeolian Islands to the Ionian Abyssal plain, that we believe plays the role of accommodating differential motion between the Southern Tyrrhenian unit and the western compressional domain of Sicily. The ATLFS, which is a main part of the inferred shear zone, behaves similarly to what often observed at the edges of retreating subduction slabs, where the overriding plate drifts with a highly non-uniform transform motion along the lateral borders.

Spatial Distribution of Field Physico-Chemical Parameters in the Vulcano Island (Italy) Coastal Aquifer: Volcanological and Hydrogeological Implications

Vulcano, the southernmost of the Aeolian island arc (Italy), is characterized by a shallow coastal aquifer resulting from the mixing of seawater, meteoric recharge and volcanogenic fluids. The aquifer has been intensively studied during the last decades, but a comprehensive hydrogeological model has never been developed due to the lack of direct information about the litho-stratigraphic columns of the wells and the depth of water bearing levels. We present and discuss here the time and spatial analysis of water table elevation, temperature and electric conductivity data, acquired during the last 20 years in 33 wells located at Vulcano Island, with the aim of developing a groundwater circulation scheme able to fit the field observations. We retrieved a circulation scheme characterized by an intricate geometry of flow paths driven by horizontal and vertical permeability variations, accounting for the strong variability of geochemical data evidenced in this area by the related scientific literature. Extending these results to a general context, particular care must be taken in approaching the study of aquifers in volcanic islands, because a strong, small spatial scale variability of the hydrogeochemical parameters is expected, and a reliable knowledge of the local conditions is required for developing successful groundwater circulation schemes.

The first ultra-high resolution Digital Terrain Model of the shallow-water sector around Lipari Island (Aeolian Islands, Italy)

<p style="margin: 0cm 0cm 10pt; text-align: justify; line-height: 150%;"> </p><p>Very high resolution bathymetric map obtained through multibeam echo-sounders data are crucial to generate accurate Digital Terrain Models from which the morphological setting of active volcanic areas can be analyzed in detail. Here we show and discuss the main results from the first multibeam bathymetric survey performed in shallow-waters around the island of Lipari, the largest and the most densely populated of the Aeolian Islands (southern Italy). Data have been collected in the depth range of 0.1-150 m and complete the already existent high-resolution multibeam bathymetry realized between 100 and 1300 m water depth. The new ultra-high resolution bathymetric maps at 0.1-0.5 m provide new insights on the shallow seafloor of Lipari, allowing to detail a large spectrum of volcanic, erosive-depositional and anthropic features. Moreover, the presented data allow outlining the recent morphological evolution of the shallow coastal sector of this active volcanic island, indicating the presence of potential geo-hazard factors in shallow waters.</p><p style="margin: 0cm 0cm 10pt; text-align: justify; line-height: 150%;"><span style="line-height: 150%; font-family: 'Times New Roman','serif'; font-size: 12pt; mso-ansi-language: EN-US;" lang="EN-US"><span style="line-height: 150%; font-family: 'Times New Roman','serif'; font-size: 12pt; mso-ansi-language: EN-US;" lang="EN-US"><br /></span></span></p>

The crystal structure of balićžunićite, Bi2O(SO4)2, a new natural bismuth oxide sulfate

AbstractThe crystal structure of balićžunićite, Bi2O(SO4)2, a new mineral species from the La Fossa crater of Vulcano (Aeolian Islands, Italy), was solved from single-crystal X-ray diffraction data and refined to R = 0.0507. The structure is triclinic, space group P1, with a = 6.7386(3), b = 11.1844(5), c = 14.1754(7) Å, α = 80.082(2), β = 88.462(2)°, γ = 89.517(2)°, V = 1052.01(8) Å3 and Z = 6. The crystal structure consists of six independent Bi sites, six S sites and 27 O sites of which three are oxo oxygen atoms not bonded to sulfur. Bismuth and S atoms are arranged close to a eutectic pattern parallel to the (100) plane. The planes are stacked atom on atom such that Bi always overlays S and vice versa. This structural feature is shared with the known structure of the high-temperature polymorph of the same compound, stable at T >535°C. However, the sequences of Bi and S atoms in the two structures are different and so are the arrangements of oxygen atoms. Characteristic building blocks in the structure of balićžunićite are clusters of five Bi atoms which form nearly planar trapezoidal Bi5 groups with oxo oxygens located in the centres of the three Bi3 triangles, which form the trapezoids. The trapezoidal Bi5O39+ ions are joined along [100] with SO42– groups by means of strong bismuth-sulfate oxygen bonds, forming infinite [100] rods with composition Bi5O3(SO4)5–. One sixth of the Bi atoms do not participate in trapezoids, but form, with additional SO42– groups, rows of composition BiSO4+, also parallel to [100]. [Bi5O3(SO4)5–] rods form infinite layers parallel to (010) with [BiSO4+] rows located on the irregular surface of contact between adjacent layers. Bi atoms occur in four different coordination types, all showing the stereochemical influence of the Bi3+ lone electron pair. In this respect the crystal structure of balićžunićite shows greater variability than its high-temperature polymorph which has only two types of the Bi coordination spheres present in balićžunićite.

Geochemistry of selected lavas of the Panarea volcanic group, Aeolian Arc, Italy

The Panarea Volcanic Group (PVG) is a group of emergent islands rising from the truncated cone of an underwater edifice in the eastern sector of the Aeolian Island Arc in the Tyrrhenian Sea, Italy. Selected lava units from the main island of Panarea and some of the nearby islets were analysed for their major and trace element compositions to the dataset available in the literature. Major mineral phases were identified as plagioclase ± clinopyroxene ± orthopyroxene ± olivine ± amphibole ± mica. The lavas of this study range from andesite to rhyolite with major element compositions equivalent to previously published data. Pyroxene geobarometry suggests a polybaric distribution to crystal fractionation, beginning at the Moho, and continuing to a shallow magma reservoir, at approximately 0.8 km depth. A plot of Nd143/Nd144 vs. Sr87/Sr86 show the compositions of Panarea overlap with the compositions of the eastern and central Aeolian Arc, while Pb208/Pb204 vs. Pb206/Pb204 do not overlap, but fall between the central and eastern arc values. As major and trace element concentrations, and isotope compositions of the lavas of this study overlap most consistently with lava compositions from the central and eastern Aeolian Arc, indicating Panarea should be considered an “intermediate” volcano in the arc.

Blade production and the consumption of obsidian in Stentinello period Neolithic Sicily

This study explores obsidian consumption during the Early/Middle Neolithic Stentinello period (ca. 5600–4000cal B.C.) on the Italian island of Sicily through the analysis of 622 obsidian artifacts from eight sites in eastern Sicily and the Aeolian Islands. By combining obsidian sourcing by means of portable X-ray fluorescence (pXRF) spectrometry with techno-typological characterization, it is shown that distinctively wide Lipari blades were the primary artifact type used during this period. Our data suggest that the primary reduction of these materials occurred at the source area by local populations, with obsidian being transported from Lipari to eastern Sicily and Calabria in the form of preformed cores. Despite similarities between Sicily and southern Italy in the initial procurement of Lipari obsidian, there are distinct differences in how these materials were subsequently reduced.

Changes in prokaryotic community composition accompanying a pronounced temperature shift of a shallow marine thermal brine pool (Panarea Island, Italy).

Hot Lake is a recently described thermal brine pool off Panarea Island (Eolian Islands, Italy) where emitted fluids are highly saline and rich in CO2 and H2S. The prokaryotic community composition in surface sediment samples was analyzed by high-throughput Illumina sequencing targeting the V3 region of the 16S rRNA at two time points that differed mainly with respect to temperature conditions, high-temperature (94 °C, HT09) and low-temperature (28.5 °C, LT10). Bacterial richness and diversity were greater than those of Archaea under both temperature conditions. In contrast to Bacteria, diversity and evenness of Archaea greatly increased at LT10. While the phylogenetic analysis indicated the presence of members mostly affiliated with the same taxonomic groups, their relative abundances differed from HT09 to LT10, resulting in different bacterial and archaeal assemblages. Both HT09 and LT10 were dominated by members of the Epsilonproteobacteria. Within this subphylum, bacteria of the genus Sulfurimonas were most frequently detected at HT09, while Arcobacter prevailed at LT10. The abundance of other dominant taxonomic groups (≥1 % of Illumina reads) also correlated with temperature conditions. Members assigned to hyperthermophilic Euryarchaeota (Thermococci) or to thermophilic (Caldiserica) and thermoresistant (Firmicutes) bacterial taxa were dominant at HT09, while those related to non-thermophilic Bacteroidetes, Fusobacteria and Actinobacteria were dominant at LT10. Several, probably photosynthetic, members of the Alphaproteobacteria, Chlorobi, Cyanobacteria and Chloroflexi were recovered under both temperature conditions. The co-occurrence of photosynthetic and chemolithotrophic microorganisms represents a unique feature of shallow vents such as Hot Lake.

Vaghi e pendenti litici dell’età del bronzo dalla Sicilia e dalle Eolie

The present work is devoted to the study of stone beads and pendants from Bronze Age sites in Sicily and the Aeolian Islands. Macroscopic geological examination made it possible to identify the rock types and in some cases their probable provenance. A chronological and typological analysis of the objects as well as graphic and photographic documentation completes the study of the stone artifacts. Comparative research throughout the Mediterranean allows the distinction between local groups of beads and pendants (i.e. of local production and distribution) and groups of Near Eastern objects (mainly in carnelian) that arrived in Italy through Aegean contacts. This work enables a chronological classification of these objects, some of which arrived in Sicily via Mediterranean sea routes. As a result, it is possible to discuss in depth some issues regarding Aegean imports in Italy and the changing socio-economic role that ornaments played in the indigenous communities during the Bronze Age.

Poly-γ-Glutamic Acid from Bacillus Horneckiae Strain APA of Shallow Marine Vent Origin with Antiviral and Immunomodulatory Effects against Herpes Simplex Virus Type-2

The shallow vents of the Eolian Islands (Italy) are sources of almost unexplored microorganisms able to produce biomolecules with promising pharmaceutical applications. This work describes the characterization of an extracellular poly-γ-glutamic acid (γ-PGA) from the new Bacillus horneckiae strain APA, and its antiviral and immunomodulatory effects against Herpes simplex virus type 2 (HSV-2). The γ-PGA-APA was able to hinder HSV-2 replication in human peripheral blood mononuclear cells (PBMC), involving the cell-mediated immunity. The exopolymer induced the expression of high levels of Th1–type cytokines in PBMC, while it had no effects on Th2-type cytokines production. This is the first report on a γ-PGA produced by a marine thermotolerant B. horneckiae strain with antiviral and immunomodulator activities. As stimulator of Th1 cell-mediated immunity, this biopolymer could be potentially used in the treatment of immunocompromised hosts as well as in patients affected by herpes virus infections.

Tunable diode laser measurements of hydrothermal/volcanic CO<sub>2</sub> and implications for the global CO<sub>2</sub> budget

Abstract. Quantifying the CO2 flux sustained by low-temperature fumarolic fields in hydrothermal/volcanic environments has remained a challenge, to date. Here, we explored the potential of a commercial infrared tunable laser unit for quantifying such fumarolic volcanic/hydrothermal CO2 fluxes. Our field tests were conducted between April 2013 and March 2014 at Nea Kameni (Santorini, Greece), Hekla and Krýsuvík (Iceland) and Vulcano (Aeolian Islands, Italy). At these sites, the tunable laser was used to measure the path-integrated CO2 mixing ratios along cross sections of the fumaroles' atmospheric plumes. By using a tomographic post-processing routine, we then obtained, for each manifestation, the contour maps of CO2 mixing ratios in the plumes and, from their integration, the CO2 fluxes. The calculated CO2 fluxes range from low (5.7 ± 0.9 t d−1; Krýsuvík) to moderate (524 ± 108 t d−1; La Fossa crater, Vulcano). Overall, we suggest that the cumulative CO2 contribution from weakly degassing volcanoes in the hydrothermal stage of activity may be significant at the global scale.

Leguernite, Bi12.67O14(SO4)5, a new Bi oxysulfate from the fumarole deposit of La Fossa crater, Vulcano, Aeolian Islands, Italy

AbstractLeguernite, ideally Bi12.67O14(SO4)5, is a new mineral found in high-temperature fumarolic assemblages at La Fossa crater, Vulcano, Aeolian Islands, Italy. It occurs as aggregates of needleshaped crystals associated strictly with anglesite, balićžunićite and an unknown Bi sulfate. Leguernite is colourless to white, transparent, non-fluorescent, has a sub-adamantine lustre and a white streak. Electron microprobe data led to the chemical formula (on the basis of 34 anions p.f.u.) (Bi12.40Pb0.15)Σ=12.55S5.08O34. The calculated density is 7.375 g cm–3. A Raman spectrum collected on a single crystal of leguernite confirmed the anhydrous nature of the mineral.Leguernite is monoclinic, space group P2, with a = 11.2486(11), b = 5.6568(6), c = 11.9139(10) Å , β = 99.177(7)º, V = 748.39(12) Å3 and Z = 1. The crystal structure is built up of Bi–O blocks of a fluorite-like structure with Bi12O14 composition separated by a single sulfate ion along [100] and by Bi(SO4)45– groups along [101]. It can also be described as composed of (001) layers with composition [Bi12O14(SO4)6+]n alternating with layers of composition [Bi(SO4)4]n5– along [001]. Leguernite shows significant similarities with the synthetic Bi14O16(SO4)5 compound.The eight strongest reflections in the powder X-ray diffraction data [d in Å (I) (hkl)] are: 3.220 (100) (013), 3.100 (95) (11), 2.83 (30) (020), 2.931 (25) (302), 2.502 (25) (04), 2.035 (20) (322), 1.875 (20) (24) and 5.040 (15) (110).The name is in honour of Franc¸ois “Fanfan” Le Guern (1942–2011), who was a very active volcanologist and specialist in volcanic gases and sublimates. Both the mineral and the mineral name have been approved by the IMA-CNMNC (2013–051).

Developing a robust tephrochronological framework for Late Quaternary marine records in the Southern Adriatic Sea: new data from core station SA03-11

Tephra layers are assuming an increasingly important role in the dating and correlation of Late Quaternary marine sequences. Here we demonstrate their potential by reporting a new study of the sediment sequence of marine core SA03-11, recovered from the Southern Adriatic Sea, which spans the last c. 39 ka. A total of 28 discrete tephra layers are reported from this sequence, 10 of which are visible in the core and a further 18 are non-visible cryptotephra layers. These have been analysed using more than 1400 WDS-EPMA measurements of glass chemistry and results have been compared with published chemical measurements obtained from relevant proximal and distal sites which preserve eruptive material dating to within the same time interval. The data show that a high proportion of the layers originate from the Campi Flegrei volcanic field but more distinctive layers are sourced from Vesuvius, the Aeolian Islands and Vulcano, and these provide key marker horizons. The results show that the sequence extends in time to the Campanian Ignimbrite at the base, that a number of the layers have robust age estimates that permit a better constrained age–depth model to be constructed for the sequence, and that the potential exists for importing terrestrially-based age estimates into marine contexts, thereby circumventing problems of incorporating reservoir uncertainties associated with marine radiocarbon dates. The WDS-EPMA dataset generated here also provides important new data that constrain key Late Quaternary tephra layers in the central Mediterranean region.

Drilling Shallow-Water Massive Sulfides at the Palinuro Volcanic Complex, Aeolian Island Arc, Italy

A subseafloor replacement-style barite and sulfide occurrence was drilled in shallow waters at the Palinuro volcanic complex, the northernmost Aeolian arc volcano in the Tyrrhenian Sea, Italy. Using a lander-type drilling device, 11 successful drill holes yielded a total of 13.5 m of core from a sediment-filled depression located at a water depth of 630 to 650 m. The longest continuous drill core recovered consists of 4.84 m of massive to semimassive barite and sulfides with abundant late, native sulfur overprint. Seafloor observations suggest that the hydrothermal system associated with the formation of the subseafloor barite and sulfide ore zone is still active, although black smoker activity does not occur on the seafloor. The recovered drill core shows that the subseafloor deposit is zoned with depth. The top of the mineralized zone is comprised of a variably silicified vuggy barite-sulfide facies that shows notable polymetallic metal enrichment, while the deeper portion of the mineralized zone is dominated by massive pyrite having distinctly lower base and precious metal grades. Metal zonation of the barite and sulfide deposit is related to the evolution of the hydrothermal fluids in space and time. The barite cap and the massive pyrite present in the deeper portion of the mineralized zone appear to have formed early in the paragenesis. During the main stage of the mineralization, the barite cap was brecciated and cemented by a polymetallic assemblage of barite and pyrite with minor chalcopyrite and tetrahedrite, trace famatinite, and rare cinnabar. Lower temperature precipitates formed during the main stage of mineralization include sphalerite, galena, pyrite, opal-A, and barite, which are associated with traces of Pb-Sb-As sulfosalts such as bournonite-seligmannite, or semseyite. A distinct mineral assemblage of fine-grained anhedral enargite, hypogene covellite, chalcopyrite, and galena is commonly associated with colloform sphalerite, galena, and pyrite as a late phase of this main stage. Colloform pyrite and marcasite are the last sulfides formed in the paragenetic sequence. The deposit is interpreted to have formed from fluids having an intermediate-sulfidation state, although excursions to high- and very high sulfidation states are indicated by the presence of abundant enargite and hypogene covellite. Laser ablation and conventional sulfur isotope analyses show that pyrite formed close to the seafloor within the zone of polymetallic metal enrichment has a variable sulfur isotope composition (δ34S = −39 to +3‰), whereas a more narrow range is observed in the massive pyrite at depth (δ34S = −10 to 0‰). Similar variations were also documented for the late native sulfur overprint. Overall, the negative sulfur isotope ratios at depth, the intermediate- to very high sulfidation conditions during mineralization, and the abundance of native sulfur suggest contributions of magmatic volatiles to the mineralizing fluids from a degassing magma chamber at depth. Biological processes are interpreted to have played a major role during late stages of ore formation. The combination of a subseafloor replacement deposit with a massive to semimassive barite cap rock overlying massive pyrite, the intermediate- to high-sulfidation characteristics, and the strong biological influence on the late stages of mineralization are distinct from other modern seafloor massive sulfide deposits and represents a style of submarine mineralization not previously recognized in a modern volcanic arc environment. The barite and sulfide occurrence at Palinuro shares many characteristics with porphyry-related base metal veins and intermediate-sulfidation epithermal deposits, suggesting that metallogenic processes associated with arc-related magmatic-hydrothermal systems are not restricted to the subaerial environment.

Contributions to the fauna of reptilian chiggers (Acari: Trombiculidae) from the Central Mediterranean, with a description of one new species

A new species of chigger mite, Lacertacarus sardiniensis sp. nov., is described from a lizard Podarcis tiliguerta (Gmelin) collected in Sardinia. One species, Ericotrombidium caucasicum (Schluger, 1967), previously known from Southern Russia and Southern Ukraine, is recorded for the first time on the lizards Podarcis filfolensis (Bedriaga) and Podarcis siculus (Rafinesque-Schmaltz), and on Malta, Lipari Island and Alicudi Island (Aeolian Islands, Sicily, Italy).http://zoobank.org/urn:lsid:zoobank.org:pub:CD41E85B-1801-4FA3-BC42-28F5F1AC14C1

Balićžunićite, Bi2O(SO4)2, a new fumarole mineral from La Fossa crater, Vulcano, Aeolian Islands, Italy

AbstractBalićžunićite, ideally Bi2O(SO4)2, is a new mineral found as a high-temperature fumarole sublimate (T = 600°C) at La Fossa crater, Vulcano, Aeolian Islands, Italy. It occurs as aggregates of mm-sized prismatic and elongated crystals (∼50 μm across and up to 200 μm long) associated with anglesite, leguernite, one other potentially new Bi-oxysulfate mineral, lillianite, galenobismutite, bismoclite, Cd-rich sphalerite, wurtzite, pyrite and pyrrhotite. Balićžunićite is colourless to white or pale brown, transparent and non-fluorescent. It has a vitreous lustre and a white streak. Electron microprobe analysis gives the following average chemical composition (wt.%): Bi2O3 68.68 and SO3 23.73, total 92.41. The empirical chemical formula, calculated on the basis of 9 anions p.f.u., is Bi1.99S2O9. The calculated density is 5.911 g/cm3.Balićžunićite is triclinic, space group P, with a 6.7386(3), b 11.1844(5), c 14.1754(7) Å, α 80.082(2)°, β 88.462(2)°, γ 89.517(2)°, V = 1052.01(8) Å3 and Z = 6. The six strongest reflections in the X-ray powder-diffraction data [d in Å(I) (hkl)] are: 3.146 (100) (033), 3.486 (21) (004), 3.409 (12) (01), 3.366 (7) (200), 5.562 (4) (11), 5.433 (4) (111). Balićžunićite is the natural analogue of the stable low-temperature a form of synthetic Bi2O(SO4)2. The name is in honour of Tonci Balić-Žunić(born 1952), Professor of Mineralogy at the Natural History Museum of the University of Cophenagen. Both the mineral and the mineral name have been approved by the IMA-CNMNC Commission (IMA2012-098).

LE FUMAROLE DI VULCANO (EOLIE): UN LABORATORIO CHIMICO NATURALE

he minerals from volcanic fumaroles have long attracted the interest of scientists: among these persons, we find not only geologists or volcanologists in the strict sense, but chemists and physicists as well, with a long series of publications spanning an interval of more than three centuries. Whereas Vesuvius was the most “classical” locality for such observations until the last half of the 20th century, in recent times Vulcano in the Aeolian islands has become instead the most promising locality in Europe for such studies, which provide a series of important observations involving several disciplines.