Advection Of Water Masses Research Articles

Seasonal variability of the Arabian Sea intermediate circulation and its impact on seasonal changes of the upper oxygen minimum zone

Abstract. Oxygen minimum zones (OMZs) in the open ocean occur below the surface in regions of weak ventilation and high biological productivity with associated sinking organic matter. Very low levels of dissolved oxygen alter biogeochemical cycles and significantly affect marine life. One of the most intense though poorly understood OMZs in the world ocean is located in the Arabian Sea between 300 and 1000 m of depth. An improved understanding of the physical processes that have an impact on the OMZ in the Arabian Sea is expected to increase the reliability of assessments of its future development. This study uses reanalysis velocity fields from the ocean model HYCOM (Hybrid Coordinate Ocean Model), which are verified with observational data, to investigate advective pathways of Lagrangian particles into the Arabian Sea OMZ at intermediate depths between 200 and 800 m. In the eastern basin, the vertical expansion of the OMZ is strongest during the winter monsoon, revealing a core thickness 1000 m deep and oxygen values below 5 µmol kg−1. The minimum oxygen concentration might be favoured by a maximum water mass advection that follows the main advective pathway of Lagrangian particles along the perimeter of the basin into the eastern basin of the Arabian Sea during the winter monsoon. These water masses pass regions of high primary production and respiration, contributing to the transport of low-oxygenated water into the eastern part of the OMZ. The maximum oxygen concentration in the western basin of the Arabian Sea in May coincides with a maximum southward water mass advection in the western basin during the spring intermonsoon, supplying the western core of the OMZ with high-oxygenated water. The maximum oxygen concentration in the eastern basin of the Arabian Sea in May might be associated with the northward inflow of water across 10∘ N into the Arabian Sea, which is highest during the spring intermonsoon. The Red Sea outflow of advective particles into the western and eastern basin starts during the summer monsoon associated with the northeastward current during the summer monsoon. On the other hand, waters from the Persian Gulf are advected with little variation on seasonal timescales. As the weak seasonal cycle of oxygen concentration in the eastern and western basin can be explained by seasonally changing advection of water masses at intermediate depths into the Arabian Sea OMZ (ASOMZ), the simplified backward-trajectory approach seems to be a good method for prediction of the seasonality of advective pathways of Lagrangian particles into the ASOMZ.

Influence of intraseasonal eastern boundary circulation variability on hydrography and biogeochemistry off Peru

Abstract. The intraseasonal evolution of physical and biogeochemical properties during a coastal trapped wave event off central Peru is analysed using data from an extensive shipboard observational programme conducted between April and June 2017, and remote sensing data. The poleward velocities in the Peru–Chile Undercurrent were highly variable and strongly intensified to above 0.5 m s−1 between the middle and end of May. This intensification was likely caused by a first-baroclinic-mode downwelling coastal trapped wave, excited by a westerly wind anomaly at the Equator and originating at about 95∘ W. Local winds along the South American coast did not impact the wave. Although there is general agreement between the observed cross-shore-depth velocity structure of the coastal trapped wave and the velocity structure of first vertical mode solution of a linear wave model, there are differences in the details of the two flow distributions. The enhanced poleward flow increased water mass advection from the equatorial current system to the study site. The resulting shorter alongshore transit times between the Equator and the coast off central Peru led to a strong increase in nitrate concentrations, less anoxic water, likely less fixed nitrogen loss to N2 and a decrease of the nitrogen deficit compared to the situation before the poleward flow intensification. This study highlights the role of changes in the alongshore advection due to coastal trapped waves for the nutrient budget and the cumulative strength of N cycling in the Peruvian oxygen minimum zone. Enhanced availability of nitrate may impact a range of pelagic and benthic elemental cycles, as it represents a major electron acceptor for organic carbon degradation during denitrification and is involved in sulfide oxidation in sediments.

On the control of subantarctic stratification by the ocean circulation

A shallow mixed layer depth bias in Austral winter in the Subantarctic Zone is a common feature of Coupled Model Intercomparison Project (CMIP5) models, including the Community Earth System Model (CESM). The bias is related to other deficiencies in the model solution, including too-weak Subantarctic Mode water formation and excessive leakage of Agulhas waters into the Atlantic instead of into the Indian Ocean and Subantarctic Frontal Zone. This work investigates the hypothesis that the shallow bias is due to errors in the simulated ocean circulation. Results from a model with low resolution ocean component (1° grid) are compared against: (i) an experiment with an eddy resolving (0.1°) grid and (ii) experiments using the 1° grid and employing an adiabatic nudging of the ocean pressure field to observations that is referred to as a semi-prognostic method. For both the higher resolution and semi-prognostic experiments, improved horizontal advection of warm and salty water near the surface leads to a more realistic sea surface temperature (SST) and salinity front associated with the Agulhas Return Current and Antarctic Circumpolar Current. The warmer surface waters in the high-resolution model and semi-prognostic model lead to stronger air–sea heat loss, with a response of about 40 Wm−2 °C−1 in winter in the area of deep mixed layers. Budgets of the temperature and salinity stratification show that the deeper mixed layers in the high-resolution experiment are primarily a result of the increased surface heat loss, whereas in the semi-prognostic case salinity advection is the main factor leading to destabilization of the water column. Both results indicate that ocean circulation is a key factor in wintertime deep Southern Ocean mixing, associated with advection of water masses and air–sea feedbacks.

Coupled analysis of seawater and sedimentary 231Pa/230Th in the tropical Atlantic

The 231Pa/230Th ratio of seawater and in ocean sediments is a potentially powerful tool in tracing oceanic processes such as the ocean circulation and marine primary productivity. However, 231Pa/230Th reflects the combined signal of multiple controls associated with scavenging and oceanic transport, limiting its use as a paleo-proxy. Given that links between seawater and sedimentary 231Pa and 230Th distributions are crucial for understanding the cycling and removal fluxes of these nuclides, we carry out analysis of 231Pa and 230Th in both seawater (dissolved phase) and modern sediment samples acquired from five depth transects across the northern tropical Atlantic open ocean. Overall, the sediment data support the dominance of 231Pa export in the deep Atlantic Ocean (>2.5 km) associated with the southward advection of North Atlantic Deep Water. However, the seawater data provide evidence for locally enhanced scavenging of 231Pa and 230Th near the western seamounts that is likely to be associated with the influence of hydrothermal activity or episodic formation of transient nepheloid layers. At shallower depths (0.5–1.5 km), paired sediment and seawater 231Pa/230Th data reveal enhanced burial of 231Pa at the eastern and mid-Atlantic sites that is likely related to elevated marine primary productivity and/or influence of boundary scavenging at the African margin, and a net input of 231Pa potentially maintained by the northward advection of intermediate water masses and an additional mechanism of upward diffusion. Our findings provide greater insights into the range of oceanic processes that play a significant role in the cycling of 231Pa and 230Th, with implications for the controls of 231Pa/230Th distribution in the Atlantic Ocean.

Reconstruction of Holocene oceanographic conditions in eastern Baffin Bay

Abstract. Baffin Bay is a semi-enclosed basin connecting the Arctic Ocean and the western North Atlantic, thus making out a significant pathway for heat exchange. Here we reconstruct the alternating advection of relatively warmer and saline Atlantic waters versus the incursion of colder Arctic water masses entering Baffin Bay through the multiple gateways in the Canadian Arctic Archipelago and the Nares Strait during the Holocene. We carried out benthic foraminiferal assemblage analyses, X-ray fluorescence scanning, and radiocarbon dating of a 738 cm long marine sediment core retrieved from eastern Baffin Bay near Upernavik, Greenland (Core AMD14-204C; 987 m water depth). Results reveal that eastern Baffin Bay was subjected to several oceanographic changes during the last 9.2 kyr. Waning deglacial conditions with enhanced meltwater influxes and an extensive sea-ice cover prevailed in eastern Baffin Bay from 9.2 to 7.9 ka. A transition towards bottom water amelioration is recorded at 7.9 ka by increased advection of Atlantic water masses, encompassing the Holocene Thermal Maximum. A cold period with growing sea-ice cover at 6.7 ka interrupts the overall warm subsurface water conditions, promoted by a weaker northward flow of Atlantic waters. The onset of the neoglaciation at ca. 2.9 ka is marked by an abrupt transition towards a benthic fauna dominated by agglutinated species, likely in part explained by a reduction of the influx of Atlantic Water, allowing an increased influx of the cold, corrosive Baffin Bay Deep Water originating from the Arctic Ocean to enter Baffin Bay through the Nares Strait. These cold subsurface water conditions persisted throughout the Late Holocene, only interrupted by short-lived warmings superimposed on this cooling trend.

Solenosmilia variabilis-bearing cold-water coral mounds off Brazil

Cold-water corals (CWC), dominantly Desmophyllum pertusum (previously Lophelia pertusa), and their mounds have been in the focus of marine research during the last two decades; however, little is known about the mound-forming capacity of other CWC species. Here, we present new 230Th/U age constraints of the relatively rarely studied framework-building CWC Solenosmilia variabilis from a mound structure off the Brazilian margin combined with computed tomography (CT) acquisition. Our results show that S. variabilis can also contribute to mound formation, but reveal coral-free intervals of hemipelagic sediment deposits, which is in contrast to most of the previously studied CWC mound structures. We demonstrate that S. variabilis only occurs in short episodes of < 4 kyr characterized by a coral content of up to 31 vol%. In particular, it is possible to identify distinct clusters of enhanced aggradation rates (AR) between 54 and 80 cm ka−1. The determined AR are close to the maximal growth rates of individual S. variabilis specimens, but are still up to one order of magnitude smaller than the AR of D. pertusum mounds. Periods of enhanced S. variabilis AR predominantly fall into glacial periods and glacial terminations that were characterized by a 60–90 m lower sea level. The formation of nearby D. pertusum mounds is also associated with the last glacial termination. We suggest that the short-term periods of coral growth and mound formation benefited from enhanced organic matter supply, either from the adjacent exposed shelf and coast and/or from enhanced sea-surface productivity. This organic matter became concentrated on a deeper water-mass boundary between South Atlantic Central Water and the Antarctic Intermediate Water and may have been distributed by a stronger hydrodynamic regime. Finally, periods of enhanced coral mound formation can also be linked to advection of nutrient-rich intermediate water masses that in turn might have (directly or indirectly) further facilitated coral growth and mound formation.

Timing of juvenile fish settlement at offshore oil platforms coincides with water mass advection into the Santa Barbara Channel, California

Recent pathways taken by pelagic juvenile fishes to offshore oil platforms were reconstructed from remotely sensed and in situ measurements of currents and hydrography. Juvenile fishes comprised 52.8% (16,952 of 23 species) of all individuals (32,080 juveniles and adults of 35 species) observed during scuba surveys conducted about twice per week at two platforms in the eastern Santa Barbara Channel from May to August 2004. Blacksmith, Chromis punctipinnis (Cooper, 1863), and rockfishes (genus Sebastes, at least 18 taxa) comprised 95.1% of the recruits. Almost all rockfishes recruited to the deepest part of the platforms surveyed (26 and 31 m), while most blacksmith recruited in shallower waters. The onset of the recruitment season for juvenile rockfishes (genus Sebastes, Scorpaenidae) coincided with the advection of a low salinity water mass into the channel from the Southern California Bight. Before arrival of this water mass, water at the platforms resembled upwelled, high salinity water around the Point Conception region at the western channel entrance. Settlement pulses of rockfishes and blacksmith were observed during advective events when salinity decreased in the upper 40 m and currents turned northwestward or intensified in that direction. Two abundant rockfish species [bocaccio, Sebastes paucispinis Ayres, 1854, and treefish, Sebastes serriceps (Jordan and Gilbert, 1880)] showed synchronous patterns of juvenile settlement between platforms separated by 7 km. Our findings indicate that currents from the bight, rather than from central California, supplied recruits to settlement habitat in the eastern channel and that the spatial scale of connectivity for some fish populations in this region is greater than the channel itself.

Modeling slippery layers in the northern Bay of Bengal

In this study, we model a “slippery” layer observed during September 2011 at a National Institute of Ocean Technology (NIOT) mooring deployed at 18 oN, 89 oE in the northern Bay of Bengal (BoB). The mooring was located close to the mouths of the huge rivers draining the Indian subcontinent. The lateral advection of riverine water masses past the mooring resulted in a shallow brackish layer 10–15 m deep bounded by a strong halocline below, giving rise to the possibility of a slippery layer gliding past the layers below. The strong currents in this slippery layer were simulated by a simple slab-type dynamical model. In addition, a second moment turbulence closure-based model, driven by surface data from the buoy was also used to simulate the water mass structure and upper layer currents during the event. Both the slab and turbulence-closure models reproduce currents in the slippery layer reasonably well overall, although the currents are somewhat overestimated. This “haline” slippery layer observed in the BoB complements well the “thermal” slippery layers that have been observed under certain conditions during strong diurnal heating of the upper layers of the ocean.

Seasonal changes of water mass, circulation and dynamic response in the Kuril Basin of the Sea of Okhotsk

The seasonal variability of the hydrography and anticyclonic circulation in the Kuril Basin of the Sea of Okhotsk, from which the North Pacific ventilation originates, is studied from bi-monthly climatologies of temperature, salinity, dynamic height and current velocity. The subsurface hydrography of the Kuril Basin is characterized by the dominant role of fresh and cold waters transported by the East Sakhalin Current during winter and spring, and relatively warm and saline waters flowing with the Soya Warm Current. At the intermediate layer, the influence of dense shelf water is maximum from May to August, and this water mixes with surrounding waters in around half a year to form a well homogenized Okhotsk Sea Intermediate Water, the source of North Pacific ventilation. The anticyclonic circulation typical of the Kuril Basin exhibits a strong seasonality, being absent in winter and showing a maximum amplitude in summer. Its formation is mainly related to the dynamic response of isopycnals to wind forcing. A dynamic height maximum appears along the coastal regions from Sakhalin Island to the southern Kuril Straits in winter, likely migrates towards the Kuril Basin in March–April and forms the anticyclonic system between May and October. The dynamic height – and thus the flow field – is mainly determined by isopycnal displacement in and around the Kuril Basin, whereas advection of water masses has a negligible effect. Surface intensification and decay of the anticyclonic circulation seems to be related to other processes such as heat exchange with the atmosphere.

The resilience and sensitivity of Northeast Atlantic deep water εNd to overprinting by detrital fluxes over the past 30,000 years

The neodymium isotope proxy has become a valuable tool for the reconstruction of past ocean water mass provenance and mixing. For its accurate application, knowledge about the origin and preservation of Nd in sedimentary archives is crucial. Recently, concerns have emerged regarding the applicability of neodymium isotopes as a conservative palaeo water mass tracer, given potential Nd fluxes from sediments into bottom waters (Abbott et al., 2015a) and inferred relabelling of ocean waters by settling detrital material (Roberts and Piotrowski, 2015). Consequently, a decoupling of water mass provenance and proxy variations may arise. We investigate the mobility of Nd around extreme detrital sedimentation events such as glacial ice rafting pulses and turbidite deposition in the Northeast Atlantic. The constructed records from sediment leachates span extreme Nd isotope variations including volcanic (εNd ∼ 0) and Laurentian (εNd ∼ −27) sources. We find that Nd was released into pore waters from reactive detritus inside some detrital layers during early diagenesis, thereby overprinting any archived bottom water Nd signature and precluding the reconstruction of past water mass provenance during the affected time intervals. However, we do not observe any definite indication of diffusive vertical migration of Nd into adjacent layers. Furthermore, bottom water Nd isotope signatures were not modified to a measurable degree by any potential benthic flux of Nd during the deposition of these detrital sediment layers. Consequently, the Nd isotope composition of the pelagic glacial Northeast Atlantic water masses were resilient to such episodic large detrital fluxes.Apart from extreme local sedimentation events, we confirm the presence of detritally overprinted deep waters north of 47°N during the peak glacial from comparison of Northeast Atlantic depth transects. We furthermore suggest that the sensitivity of deep waters to this overprinting effect increased during periods of reduced Atlantic Meridional Overturning Circulation and elevated ice rafting.Overall, our study demonstrates that a thorough evaluation of the proportion of Nd originating from physical water mass advection versus in situ chemical inputs is crucial for the reliable application of Nd isotopes as a water mass tracer.

Water mass transformation in the Barents Sea inferred from radiogenic neodymium isotopes, rare earth elements and stable oxygen isotopes

Nearly half the inflow of warm and saline Atlantic Water (AW) to the Arctic Ocean is substantially cooled and freshened in the Barents Sea, which is therefore considered a key region for water mass transformation in the Arctic Mediterranean (AM). Numerous studies have focused on this transformation and the increasing influence of AW on Arctic climate and biodiversity, yet geochemical investigations of these processes have been scarce. Using the first comprehensive data set of the distributions of dissolved radiogenic neodymium (Nd) isotopes (expressed as ɛNd), rare earth elements (REE) and stable oxygen isotope (δ18O) compositions from this region we are able to constrain the transport and transformation of AW in the Barents Sea and to investigate which processes change the chemical composition of the water masses beyond what is expected from circulation and mixing.Inflowing AW and Norwegian Coastal Water (NCW) both exhibit distinctly unradiogenic ɛNd signatures of −12.4 and −14.5, respectively, whereas cold and dense Polar Water (PW) has considerably more radiogenic ɛNd signatures reaching up to −8.1. Locally formed Barents Sea Atlantic Water (BSAW) and Barents Sea Arctic Atlantic Water (BSAAW) are encountered in the northeastern Barents Sea and have intermediate ɛNd values resulting from admixture of PW containing small amounts of riverine freshwater from the Ob (<~1.1%) to AW and NCW. Similar to the Laptev Sea, the dissolved Nd isotope composition in the Barents Sea seems to be mainly controlled by water mass advection and mixing despite its shallow water depth. Strikingly, the BSAW and BSAAW are marked by the lowest dissolved REE concentrations reported to date for the AM reaching 11 pmol/kg for Nd ([Nd]), which in contrast to the Nd isotopes, cannot be attributed to the admixture of REE-rich Ob freshwater to AW or NCW ([Nd] = 16.7, and 22 pmol/kg, respectively) and instead reflects REE removal from the dissolved phase with preferential removal of the light over the heavy REEs. The REE removal is, however, not explainable by estuarine REE behavior alone, suggesting that scavenging by (re)suspended (biogenic) particles occurs locally in the Barents Sea. Regardless of the exact cause of REE depletion, we show that AW transformation is accompanied by geochemical changes beyond those expected from water mass mixing.This article is part of a special issue entitled: “Cycles of trace elements and isotopes in the ocean – GEOTRACES and beyond” - edited by Tim M. Conway, Tristan Horner, Yves Plancherel, and Aridane G. González.

Asymmetric oceanographic processes mediate connectivity and population genetic structure, as revealed by RADseq, in a highly dispersive marine invertebrate (Parastichopus californicus).

Marine populations are typically characterized by weak genetic differentiation due to the potential for long-distance dispersal favouring high levels of gene flow. However, strong directional advection of water masses or retentive hydrodynamic forces can influence the degree of genetic exchange among marine populations. To determine the oceanographic drivers of genetic structure in a highly dispersive marine invertebrate, the giant California sea cucumber (Parastichopus californicus), we first tested for the presence of genetic discontinuities along the coast of North America in the northeastern Pacific Ocean. Then, we tested two hypotheses regarding spatial processes influencing population structure: (i) isolation by distance (IBD: genetic structure is explained by geographic distance) and (ii) isolation by resistance (IBR: genetic structure is driven by ocean circulation). Using RADseq, we genotyped 717 individuals from 24 sampling locations across 2,719 neutral SNPs to assess the degree of population differentiation and integrated estimates of genetic variation with inferred connectivity probabilities from a biophysical model of larval dispersal mediated by ocean currents. We identified two clusters separating north and south regions, as well as significant, albeit weak, substructure within regions (FST =0.002, p=.001). After modelling the asymmetric nature of ocean currents, we demonstrated that local oceanography (IBR) was a better predictor of genetic variation (R2 =.49) than geographic distance (IBD) (R2 =.18), and directional processes played an important role in shaping fine-scale structure. Our study contributes to the growing body of literature identifying significant population structure in marine systems and has important implications for the spatial management of P.californicus and other exploited marine species.

Study of Marine Waters Hydrological Characteristics in Odessa Bay in 2016-2017

Purpose. The results of pilot monitoring project carried out in Odessa Bay coastal waters in 2016-2017 by a research group of the Regional Center for Integrated Monitoring and Environmental Studies (Odessa National I.I. Mechnikov University) have been summarized. Methods. Primary data on transparency, temperature and salinity of marine water have been collected using standard methods. Data processing, calculation of statistics, producing of graphs and maps have been carried out using ArcGIS and Excel software. Results. Temporal and spatial distributions of transparency, temperature and salinity of marine coastal waters of Odessa Bay in the area of Marine Hydrobiological Station of the University for the period from April 2016 to August 2017 have been presented and analyzed. Using the results of analysis of the accumulated experimental data on transparency, temperature and salinity of seawater the peculiarities of those characteristics’ seasonal changes have been revealed. It was demonstrated that marine water transparency was minimal in May and June 2016 (2.2-2.8 m); maximal transparency values for the entire period of observation (7.0 m) was registered in May 2017. A strongly pronounced seasonal variation was revealed in the distribution of marine water temperature in Odessa Bay in 2016-2017, which was determined by spring-summer warming up / autumn-winter cooling down, as well as coastal upwelling, advection of water masses from other marine areas. It was shown that with observations performed every 10 days the desalinated water masses were registered in 13.5% of measurements but never found during monthly surveys at 13 of the micro-polygon. It means that during the detailed monthly surveys in Odessa Bay coastal waters all the cases of advection of desalinated water stayed unregistered. Conclusions. Impact of transformed water masses from the Dnieper-Bug mouth on seasonal cycles of hydrological characteristics in Odessa Bay in 2016-2017 has been established. Violations of the seasonality of thermohaline structure formation in Odessa Bay waters in 2016–2017 due to the longshore cyclonic and compensatory currents impact in the coastal zone have been recorded. Forming of stable two-layer vertical density stratification in Odessa Bay coastal waters at the spring and summer periods of 2016-2017 has been traced.

The role of local and regional environmental factors for Calanus finmarchicus and C. hyperboreus abundances in the Nordic Seas

In the advective realm of the seas, it is challenging to disentangle the role of regional and local processes on zooplankton populations. However, comparative studies of spatially separated zooplankton populations can provide valuable insights into this issue. We studied interannual abundance variation of the key zooplankton species Calanus finmarchicus and C. hyperboreus in three near-shore locations of the Nordic Seas: off northern Norway, Svalbard, and northern Iceland. Average abundances of both species were similar among locations, while in each location the abundance of C. finmarchicus was about an order of magnitude higher than the abundance of C. hyperboreus. The abundance of both species decreased in northern Norway, while C. finmarchicus abundance increased in northern Iceland. C. finmarchicus abundance in northern Norway covaried with regional climate, while the Svalbard Calanus populations were related to local environment (hydrography, phytoplankton). In northern Iceland, C. finmarchicus abundance covaried with local environmental factors, while C. hyperboreus abundance covaried with climate variability. Top-down forcing could not be investigated. The results indicate that the mechanisms relating regional climate variability (North Atlantic and Arctic oscillations) to Calanus abundance are mediated through advection of water masses, while more local environmental variability involved bottom-up processes or advection.

Diurnal changes in ocean color sensed in satellite imagery

Measurements of diurnal changes in ocean color in turbid coastal regions in the Gulf of Mexico were characterized using above water spectral radiometry from a National Aeronautics and Space Administration (aerosol robotic network-WaveCIS CSI-06) site that can provide 8 to 10 observations per day. Satellite capability to detect diurnal changes in ocean color was characterized using hourly overlapping afternoon orbits of the visual infrared imaging radiometer suite (VIIRS) Suomi National Polar-orbiting Partnership ocean color sensor and validated with in situ observations. The monthly cycle of diurnal changes was investigated for different water masses using VIIRS overlaps. Results showed the capability of satellite observations to monitor hourly color changes in coastal regions that can be impacted by vertical movement of optical layers, in response to tides, resuspension, and river plume dispersion. The spatial variability of VIIRS diurnal changes showed the occurrence and displacement of phytoplankton blooming and decaying processes. The diurnal change in ocean color was above 20%, which represents a 30% change in chlorophyll-a. Seasonal changes in diurnal ocean color for different water masses suggest differences in summer and winter responses to surface processes. The diurnal changes observed using satellite ocean color can be used to define the following: surface processes associated with biological activity, vertical changes in optical depth, and advection of water masses.

The malacostracan fauna of two Arctic fjords (west Spitsbergen): the diversity and distribution patterns of its pelagic and benthic components

Summary This study examines the performance of pelagic and benthic Malacostraca in two glacial fjords of west Spitsbergen: Kongsfjorden, strongly influenced by warm Atlantic waters, and Hornsund which, because of the strong impact of the cold Sorkapp Current, has more of an Arctic character. The material was collected during 12 summer expeditions organized from 1997 to 2013. In all, 24 pelagic and 116 benthic taxa were recorded, most of them widely distributed Arctic-boreal species. The advection of different water masses from the shelf had a direct impact on the structure of the pelagic Malacostraca communities, resulting in the clear dominance of the sub-arctic hyperiid amphipod Themisto abyssorum in Kongsfjorden and the great abundance of Decapoda larvae in Hornsund. The taxonomic, functional and size compositions of the benthic malacostracan assemblages varied between the two fjords, and also between the glacier-proximate inner bays and the main fjord basins, as a result of the varying dominance patterns of the same assemblage of species. There was a significant drop in species richness in the strongly disturbed glacial bays of both fjords, but only in Hornsund was this accompanied by a significant decrease in density and diversity, probably due to greater isolation and poorer quality of sediment organic matter in its innermost basin. Our results suggest that the diversity and distribution of benthic malacostracans in these two fjords are only distantly related to the different hydrological regimes; rather, they are governed by locally acting factors, such as depth, sediment type, the variety of microhabitats and the availability and quality of food.

Upper water mass variability in the Anegada–Jungfern Passage, NE Caribbean, during the last 11,100 cal. yr

Using qualitative and quantitative analyses of planktonic foraminifera assemblages, δ18O measurements, Mg/Ca–temperature relationship ( Globigerinoides ruber pink sensu stricto) data and sea-surface temperatures (SSTs) derived from artificial neural network (ANN) transfer functions, a reconstruction was made of upper water mass variability in the Anegada–Jungfern Passage (AJP), northeastern Caribbean Sea, over the last c. 11,100 years. Our record is based on the study of two marine sediment cores and reveals three main circulation stages during the Holocene. In the early-Holocene (11,100–6300 cal. yr BP), ANN-based SST estimations indicate moderately cooler than present winter condition in the NE Caribbean with SSTs of ~25.5°C. These conditions presumably reflect advection of well-mixed upper water masses from the Guyana upwelling area associated with a strong Atlantic Meridional Overturning Circulation (AMOC) and enhanced trade wind activity, linked to a more northerly location of the inter-tropical convergence zone (ITCZ). Between 6300 and 3700 cal. yr BP, a relative warming of winter SSTs (~26.5°C) was probably related to a weaker circulation and upper water mass mixing because of less intense trade wind activity, as the ITCZ moved southwards. From 3700 cal. yr BP to the present, the region was characterised by small seasonal SST variations and generally stable winter and summer SSTs. The data suggest a minor shift in the (sub)surface inflow pattern during the last 2000 years, possibly related to changes in Northern Hemisphere large-scale atmospheric circulation also observed at higher latitude. The ANN-based temperature pattern is supported by fluctuations in the Mg/Ca-derived temperature record, although temperature maxima derived from the Mg/Ca ratio appear anomalously high. On a Holocene timescale, we conclude that the northeastern Caribbean SST and circulation regime have been mainly dependent on the position of the ITCZ, which, in turn, is controlled by changes in hemispheric solar insolation.

Ocean circulation and freshwater pathways in the Arctic Mediterranean based on a combined Nd isotope, REE and oxygen isotope section across Fram Strait

The water masses passing the Fram Strait are mainly responsible for the exchange of heat and freshwater between the Nordic Seas and the Arctic Ocean (the Arctic Mediterranean, AM). Disentangling their exact sources, distribution and mixing, however, is complex. This work provides new insights based on a detailed geochemical tracer inventory including dissolved Nd isotope (εNd), rare earth element (REE) and stable oxygen isotope (δ18O) data along a full water depth section across Fram Strait.We find that Nd isotope and REE distributions in the open AM primarily reflect lateral advection of water masses and their mixing. Seawater-particle interactions exert important control only above the shelf regions, as observed above the NE Greenland Shelf. Advection of northward flowing warm Atlantic Water (AW) is clearly reflected by an εNd signature of −11.7 and a Nd concentration ([Nd]) of 16pmol/kg in the upper ∼500m of the eastern and central Fram Strait. Freshening and cooling of the AW on its way trough the AM are accompanied by a continuous change towards more radiogenic εNd signatures (e.g. −10.4 of dense Arctic Atlantic Water). This mainly reflects mixing with intermediate waters but also admixture of dense Kara Sea waters and Pacific-derived waters. The more radiogenic εNd signatures of the intermediate and deep waters (reaching −9.5) are mainly acquired in the SW Nordic Seas through exchange with basaltic formations of Iceland and CE Greenland. Inputs of Nd from Svalbard are not observed and surface waters and Nd on the Svalbard shelf originate from the Barents Sea. Shallow southward flowing Arctic-derived waters (<200m) form the core of the East Greenland Current above the Greenland slope and can be traced by their relatively radiogenic εNd (reaching −8.8) and elevated [Nd] (21–29pmol/kg). These properties are used together with δ18O and standard hydrographic tracers to define the proportions of Pacific-derived (<∼30% based on Nd isotopes) and Atlantic-derived waters, as well as of river waters (<∼8%). Shallow waters (<150m) on the NE Greenland Shelf share some characteristics of Arctic-derived waters, but exhibit less radiogenic εNd values (reaching −12.4) and higher [Nd] (up to 38pmol/kg) in the upper ∼100m. This suggests local addition of Greenland freshwater of up to ∼6%. In addition to these observations, this study shows that the pronounced gradients in εNd signatures and REE characteristics in the upper water column provide a reliable basis for assessments of shallow hydrological changes within the AM.

Variability of neodymium isotopes associated with planktonic foraminifera in the Pacific Ocean during the Holocene and Last Glacial Maximum

The deep Pacific Ocean holds the largest oceanic reservoir of carbon which may interchange with the atmosphere on climatologically important timescales. The circulation of the deep Pacific during the Last Glacial Maximum (LGM), however, is not well understood. Neodymium (Nd) isotopes of ferromanganese oxide coatings precipitated on planktonic foraminifera are a valuable proxy for deep ocean water mass reconstruction in paleoceanography. In this study, we present Nd isotope compositions (εNd) of planktonic foraminifera for the Holocene and the LGM obtained from 55 new sites widely distributed in the Pacific Ocean. The Holocene planktonic foraminiferal εNd results agree with the proximal seawater data, indicating that they provide a reliable record of modern bottom water Nd isotopes in the deep Pacific. There is a good correlation between foraminiferal εNd and seawater phosphate concentrations (R2=0.80), but poorer correlation with silicate (R2=0.37). Our interpretation is that the radiogenic Nd isotope is added to the deep open Pacific through particle release from the upper ocean during deep water mass advection and aging. The data thus also imply the Nd isotopes in the Pacific are not likely to be controlled by silicate cycling. In the North Pacific, the glacial Nd isotopic compositions are similar to the Holocene values, indicating that the Nd isotope composition of North Pacific Deep Water (NPDW) remained constant (−3.5 to −4). During the LGM, the southwest Pacific cores throughout the water column show higher εNd corroborating previous studies which suggested a reduced inflow of North Atlantic Deep Water to the Pacific. However, the western equatorial Pacific deep water does not record a corresponding radiogenic excursion, implying reduced radiogenic boundary inputs during the LGM probably due to a shorter duration of seawater–particle interaction in a stronger glacial deep boundary current. A significant negative glacial εNd excursion is evident in mid-depth (1–2 km) cores of the eastern equatorial Pacific (EEP) which may suggest a stronger influence of NPDW return flow to the core sites and decreased local input in the EEP. Taken together, our Nd records do not support a dynamically slower glacial Pacific overturning circulation, and imply that the increased carbon inventory of Pacific deep water might be due to poor high latitude air–sea exchange and increased biological pump efficiency in glacial times.

Dissolved aluminium in the ocean conveyor of the West Atlantic Ocean: Effects of the biological cycle, scavenging, sediment resuspension and hydrography

The concentrations of dissolved aluminium (dissolved Al) were studied along the West Atlantic GEOTRACES GA02 transect from 64°N to 50°S. Concentrations ranged from ~0.5nmolkg−1 in the high latitude surface waters to ~48nmolkg−1 in surface waters around 25°N. Elevated surface water concentrations due to atmospheric dust loading have little influence on the deep water distribution. However, just below the thermocline, both Northern and Southern Hemisphere Subtropical Mode Waters are elevated in Al, most likely related to atmospheric dust deposition in the respective source regions.In the deep ocean, high concentrations of up to 35nmolkg−1 were observed in North Atlantic Deep Water as a result of Al input via sediment resuspension. Comparatively low deep water concentrations were associated with water masses of Antarctic origin. During water mass advection, Al loss by scavenging overrules input via remineralisation and sediment resuspension at the basin wide scale. Nevertheless, sediment resuspension is more important than previously realised for the deep ocean Al distribution and even more intensive sampling is needed in bottom waters to constrain the spatial heterogeneity in the global deep ocean.This thus far longest (17,500km) full depth ocean section shows that the distribution of Al can be explained by its input sources and the combination of association with particles and release from those particles at depth, the latter most likely when the particles remineralise. The association of Al with particles can be due to incorporation of Al into biogenic silica or scavenging of Al onto biogenic particles. The interaction between Al and biogenic particles can lead to the coupled cycling of Al and silicate that is observed in some ocean regions. However, in other regions this coupling is not observed due to (i) advective processes bringing in older water masses that are depleted in Al, (ii) unfavourable scavenging conditions in the water column, (iii) low surface concentrations of Al or (iv) additional Al sources, notably sediment resuspension.