Adjustable Pore Structure Research Articles

Supermolecule-opitimized defect engineering of rich nitrogen-doped porous carbons for advanced zinc-ion hybrid capacitors.

Pitch-based porous carbons with adjustable surface chemical property and controllable pore structure are regarded as promising cathode materials for aqueous zinc-ion hybrid capacitors (ZIHCs), while its disordered carbon matrix and microstructure as well as insufficient surface defects often result in low Zn2+-storage capacity and poor rate capability of ZIHCs. Herein, a synergetic strategy of self-assembled supermolecule and enriched defective carbon engineering was developed to achieve ultrahigh edge-nitrogen doping for ZIHCs. The crystallite defects and surface structure of porous carbon could be effectively achieved through grafting electronegative oxygen-containing small molecules and high-level nitrogen-containing functional groups between modified polycyclic aromatic hydrocarbon and supermolecule framework. The optimized three-dimensional carbon structure delivered high capacity of 218 mAh g-1 at 0.2 A g-1, fast charge/discharge capability, enhanced energy density (165.4 Wh kg-1) and superior cycling stability (95% retention after 10000 cycles as cathode of ZIHCs). This provided new insight into the controllable synthesis of carbon cathodes for ZIHCs and expects to prepare functional porous carbon by supermolecules and special precursors.

Modulating porosity and hydrophilicity of granular adsorbent by water-soluble polymers to enhance lithium extraction from ultrahigh Mg/Li ratio brine

The development of granular adsorbents with high adsorption capability and high cycle stability is of great significance for the application in efficiently extracting lithium from salt lake brine. Herein, the structure of granular aluminum-based adsorbents was regulated by adding water-soluble polymer PEG. The results showed that the molecular weight of PEG was closely related to the pore structure and surface hydrophilicity of the granular adsorbents. With the decrease of the molecular weight of PEG, the specific surface area, the average surface pore size, and the hydrophilicity of granular adsorbents increase. The optimized adsorbent PSF-PEG600@AD formed a complex pore structure with surface macropores and internal mesopores as well as excellent hydrophilicity. The mechanical strength and wear resistance are enhanced. This unique porous structure and surface hydrophilicity enable PSF-PEG600@AD rapid adsorption equilibrium in the old brine of Qarhan salt lake with a Mg/Li ratio of 323 within 4 h. The adsorption capacity remains as high as 99.02 % after 10 static adsorption-desorption cycles, showing excellent cyclic stability. This study guides a direction in preparing high-performance granular adsorbents with adjustable pore structure and surface properties.

Research Progress on Controllable Absorption Properties of Rare Earth Element Doped Electromagnetic Wave Absorbing Materials†

Comprehensive SummaryThe utilization of rare earth (RE) elements is pivotal in wave absorption. In particular cases, RE group elements manifesting unique 4f electron layer structures are doped as impurities into certain materials, which is a practical and reliable method for regulating these materials' magnetic and electrical properties. Moreover, ferrites and metal‐organic frameworks (MOFs), standing out among conventional and emerging wave‐absorbing materials, can achieve significantly enhanced wave absorption through RE doping or substitution. Numerous scholars have dedicated massive research over a substantially long time to explore the utilization of RE elements to reinforce the absorption of these two materials. Therefore, consolidating and summarizing such efforts are crucial and necessary. This review aims to clarify the underlined mechanism of electromagnetic wave (EMW) absorption and elaborate on the impact of RE doping by providing a comprehensive overview of recent progress in ferrites and MOFs dopped with RE elements. Finally, the limitations associated with RE doping in such materials are delineated, and the upcoming prospects for its application are highlighted. Key ScientistsIn 1947, J. A. Marinky et al. obtained promethium from uranium fission products. From the isolates of yttrium soil in 1794 to the discovery of promethium in 1947, it took more than 150 years. In 1975, Guangxian Xu found that the rare earth solvent extraction system has the basic "constant mixed extraction ratio" rule. In 1984, the theory of "one‐cavity multi‐mode" was proposed by Weigan Lin to improve the electromagnetic wave theory further and develop the theory of absorbing materials. In 1995, Omar M. Yaghi synthesized the first MOFs in history, and since then, they have been widely used in gas adsorption and separation and other fields because of their large specific surface area and adjustable pore structure. In recent years, various functional materials based on MOFS‐derived carbon have been studied endlessly. Masato Sagawa, known for inventing NdFeB magnets, won the "28th Japan Prize" in 2012. In recent years, Renchao Che has promoted the development of interface theory and magnetic theory in the field of wave absorption. In addition, Jiurong Liu is committed to developing various wave‐absorbing materials and the respective theoretical research and continues to promote the development of wave‐absorbing materials to "thin, light, wide and strong".

Constructing the Interconnected and Hierarchical Nanoarchitectonics in Coal-Derived Carbon for High-Performance Supercapacitor.

Because of the deep and zigzag microporous structure, porous carbon materials exhibit inferior capacitive performance and sluggish electrochemical kinetics for supercapacitor electrode materials. Herein, a single-step carbonation and activation approach was utilized to synthesize coal-based porous carbon with an adjustable pore structure, using CaO as a hard template, KOH as an activator, and oxidized coal as precursors to carbon. The obtained sample possesses an interconnected and hierarchical porous structure, higher SSA (1060 m2 g-1), suitable mesopore volume (0.25 cm3 g-1), and abundant surface heteroatomic functional groups. Consequently, the synthesized carbon exhibits an exceptionally high specific capacitance of 323 F g-1 at 1 A g-1, along with 80.3% capacitance retention at 50 A g-1. The assembled two-electrode configuration demonstrates a remarkable capacitance retention of up to 95% and achieves Coulombic efficiency of nearly 100% with 10,000 cycles in a 6 M KOH electrolyte. Furthermore, the Zn-ion hybrid capacitor also exhibits a specific capacity of up to 139.1 mA h g-1 under conditions of 0.2 A g-1. This work offers a simple method in preparation of coal-based porous carbon with controllable pore structure.

Superhydrophobic Highly Flexible Triple-Network Polyorganosiloxane-Based Aerogels for Thermal Insulation, Oil-Water Separation, and Strain/Pressure Sensing.

Polyvinylpolymethylsiloxane (PVPMS)/polydimethylsiloxane (PDMS) copolymer aerogels were synthesized via consecutive radical polymerization and cohydrolytic polycondensation of vinylmethyldimethoxysilane and dimethyldimethoxysilane, followed by supercritical drying or ambient pressure drying. The resultant PVPMS/PDMS copolymer aerogels exhibit a highly porous, tunable triple-network structure consisting of interlinked hydrocarbon polymers, PVPMS and PDMS. These aerogels display superhydrophobicity (151°), low density (109 mg cm-3), low thermal conductivity (29.8 mW m-1 K-1), and adjustable pore structure. The combination of good machinability, low thermal conductivity, excellent compressive elasticity and bending flexibility, and efficient organic solvent adsorption gives these aerogels broad application prospects in thermal insulation and oil-water separation. In addition, PVPMS/PDMS/carbon nanotube (CNT) composite aerogels were obtained by incorporating the conductive CNTs, followed by vacuum drying. The resultant PVPMS/PDMS/CNT composite aerogel exhibits high sensitivity with a broad pressure sensing range in strain and pressure sensing applications.

A switchable zinc-based metal organic framework for the light triggered absorption and release of organic dyes

Due to its adjustable pore structure, the metal–organic frameworks (MOFs) have attracted much attention in the treatment of organic dye molecules in wastewater. However, the general tuning of the pore channels of MOFs is mainly by changing the chain length of the organic ligands and metal nodes. This approach not only limits the types of MOFs, but also limits the treatment of a large number of dye methylene blue (MB) and methyl orange (MO) dye molecules in the wastewater. Hence, we synthesized photoresponsive Zn-AzDC/TPA MOF as adsorbents to adsorb and release organic dye molecules in a photo-controlled manner. The photoresponsive Zn-AzDC/TPA was prepared using a mixed ligand strategy, in which the azobenzene carboxylic acid derivative (AzDC) served as a photoresponsive ligand and terephthalic acid (TPA) served as a non-active ligand in coordination with zinc ion. The optical and structural properties of the synthesized Zn-AzDC/TPA was characterized by UV–vis, FT-IR, PXRD, SEM, TEM, TGA, and pore analysis. Interestingly, it was found that the photoresponsive AzDC unit of Zn-AzDC/TPA demonstrated reversible trans–cis isomerization under the alternating UV and visible light, resulting in reversible changes in the pore size of the Zn-AzDC/TPA. Its photoresponse properties can trapp and release dye molecules under light-driven conditions. This result provides a new direction for the application of photoresponsive MOF and also lays a foundation for the study of diversified optically responsive materials.

Alginate-based adsorbents with adjustable slit-shaped pore structure for selective removal of copper ions

Adopting effective and efficient techniques for the treatment of heavy metal pollution in water bodies plays an important role in guaranteeing the quality of water and the sustainable development of water resources. In this study, GO, MMT and SA were used as raw materials to compare the adsorption behaviors of three alginate-based adsorbents crosslinked with different valence metal ions (Ca2+, Fe3+ and Zr4+) on Cu(II). The aerogels were based on sodium alginate as the matrix material with unique slit-shaped pore structures formed by stacking effect of sheets and chemical bonding. It was found that the pore structures of the aerogels were denser and more orderly with the increase of the valence states of the crosslinked ions, and the affinity for Cu(II) in planar configuration was stronger. The Zr4+-GMSA aerogel had the maximum adsorption capacity of 126.68 mg/g and the Kd of Cu(II) was up to 50.80 L/g, which exhibited good preferential adsorption performance. The adsorption mechanism of Mn+-GMSA aerogels on Cu(II) was mainly ionic exchange, surface complexation and physical adsorption, which was explored by combining XPS and EDS characterizations of Mn+-GMSA before and after adsorption. This scheme can provide valuable and meaningful contribution to realize the selective recovery of Cu(II).

Porous polyvinyl alcohol/polyacrylamide hydrogels loaded with HTO lithium-ion sieves for highly rapid and efficient Li+ extraction

Lithium (Li) reserves in liquid resources are significantly higher than solid lithium ores and can fully meet the growing demand for Li. Lithium-ion sieves (LIS) adsorption of Li from liquid resources is one of the most promising methods. However, conventional polymeric adsorption materials encapsulate most LIS in dense structures, leading to low adsorption capacity and slow adsorption rate. Therefore, HTO-PVA/PAAm hydrogel was synthesized from titanium-type lithium-ion sieves (HTO), acrylamide, and polyvinyl alcohol by free radical polymerization. The HTO-PVA/PAAm hydrogel is characterized by a soft three-dimensional (3D) network, continuously adjustable pore structure, high specific surface area, and excellent hydrophilicity. Accordingly, the HTO-PVA/PAAm owns an excellent Li+ adsorption capacity (22.16 and 31.31 mg·g−1 in pH 7.2 and 12 of LiCl solutions, respectively) among reported advanced adsorbents. 90 % of Li+ is desorbed within 60 min, indicating the efficient and rapid Li+ desorption response of the hydrogel. Meanwhile, this hydrogel still maintains a Li+ adsorption capacity of 90 % after eight adsorption-desorption cycles, during which Ti loss is <0.42 % in each cycle. In this work, HTO-PVA/PAAm hydrogel synthesized by an environmentally friendly and low-cost approach shows great application potential as a new strategy for Li+ adsorption from liquid resources.

Efficient Electrocatalytic Reduction of CO2 to CO by Cu‐doped Carbon Materials Derived from ZIF‐8

AbstractElectrochemical reduction of carbon dioxide presents a promising pathway to tackle global energy and environmental challenges. Porous carbon materials from metal‐organic frameworks exhibit high specific surface area, abundant active sites, and adjustable pore structure, demonstrating excellent electrocatalytic performance. With their abundant resources and tunability, copper‐based catalysts are well‐suited for efficient carbon dioxide conversion. However, the selectivity and stability of copper‐based catalysts is poor. This study presents the preparation of the first Cu‐doped ZIF‐8‐derived carbon materials and investigates their effect on electrocatalytic carbon dioxide reduction. At the optimal potential of −0.7 V vs. RHE, the CO Faradaic Efficiency (FE) of the Cu0.5‐N−C catalyst reaches 89 %. Furthermore, the electrochemical current density and CO FE of Cu0.5‐N−C catalyst remain nearly unchanged within 13 hours in 0.1 mol L−1 KHCO3 electrolyte. Compared to most of the reported copper‐based catalysts, Cu0.5‐N−C exhibits better stability. Characterization results show that Cu0.5‐N−C has a larger Cu‐N4, higher pyridinic N content, larger specific surface area, and average pore size, which help promote CO2 adsorption and enhance catalyst stability. This work provides new insights and pathways for electrocatalytic carbon dioxide reduction, with enormous potential to contribute to the global energy transition and environmental protection.

Porphyrin-Based Metal-Organic Framework Materials: Design, Construction, and Application in the Field of Photocatalysis.

Metal-organic frameworks (MOFs) are a novel category of porous crystalline materials with an exceptionally high surface area and adjustable pore structure. They possess a designable composition and can be easily functionalized with different units. Porphyrins with conjugated tetrapyrrole macrocyclic structures can absorb light from ultraviolet to visible light regions, and their structures and properties can be facilely regulated by altering their peripheral groups or central metal ions. Porphyrin-based MOFs constructed from porphyrin ligands and metal nodes combine the unique features of porphyrins and MOFs as well as overcoming their respective limitations. This paper reviewed the design and construction, light absorption and charge transfer pathways, and strategy for improving the photocatalytic performance of porphyrin-based MOFs, and highlighted the recent progress in the field of CO2 reduction, hydrogen evolution, organic synthesis, organic pollutant removal, and nitrogen fixation. The intrinsic relationships between the structure and the property of porphyrin-based MOFs received special attention, especially the relationships between the arrangements of porphyrin ligands and metal nods and the charge transfer mechanism. We attempted to provide more valuable information for the design and construction of advanced photocatalysts in the future. Finally, the challenges and future perspectives of the porphyrin-based MOFs are also discussed.

Covalent Organic Frameworks as Electrode Materials for Alkali Metal-ion Batteries.

Covalent organic frameworks (COFs) are a class of porous crystalline polymeric materials constructed by linking organic small molecules through covalent bonds. COFs have the advantages of strong covalent bond network, adjustable pore structure, large specific surface area and excellent thermal stability, and have broad application prospects in various fields. Based on these advantages, rational COFs design strategies such as the introduction of active sites, construction of conjugated structures, and carbon material composite, etc. can effectively improve the conductivity and stability of the electrode materials in the field of batteries. This paper introduces the latest research results of high-performance COFs electrode materials in alkali metal-ion batteries (LIBs, SIBs, PIBs and LSBs) and other advanced batteries. The current challenges and future design directions of COFs-based electrode are discussed. It provides useful insights for the design of novel COFs structures and the development of high-performance alkali metal-ion batteries.

Cobalt nanoparticles confined in silica networks with 3D hierarchical porous features for Fischer-Tropsch synthesis.

Silica network-encapsulated cobalt nanoparticles with an adjustable pore structure as model Fischer-Tropsch synthesis catalysts were successfully prepared. The well-developed shell pore structure of the core-shell catalyst is of great importance for reducing the selectivity of methane, increasing the selectivity of heavy hydrocarbons, and the probability of carbon chain growth. Benefiting from its uniform distribution of cobalt particles and 3D open hierarchical porous shell features, Co@H-mSiO2 catalysts exhibited excellent stability and activity, achieving up to 61.4% selectivity of C5-C20 hydrocarbon products at 6 SL h-1 g-1, 220 °C and 1.0 MPa.

Nitrogen/oxygen doped hierarchical porous carbon with adjustable pore structure for efficient adsorption, separation, and enhancement mechanism of methanol and acetone azeotropes: Experimental and theoretical study

The adsorption and separation of methanol and acetone are crucial for environmental protection and recycling. However, the separation of methanol and acetone azeotropes using carbon-based materials remains challenging, and the underlying mechanism is still unclear. Here, we propose the synthesis of porous carbon (NaOCs) using benzimidazole as a precursor and NaOH as an activator. With the increase of the proportion of NaOH and benzimidazole, the activation reaction was intensified, leading to the formation of numerous mesopores. NaOCs exhibit a maximum specific surface area (SBET) of 3084 m2/g, and has extremely high adsorption capacity of methanol (56.9 mmol/g at 13 kPa) and acetone (34.6 mmol/g at 18 kPa) at 25 °C. The results of experiments and molecular simulations indicate that the saturation adsorption capacity of methanol and acetone is determined by micropores and narrow mesopores at 25 °C, whereas the adsorption capacity at relatively low pressure is primary determined by ultramicropores and oxygen group. Furthermore, for methanol-acetone azeotropes separation, the acetone/methanol selectivity at low pressure depends on carbon surface polarity and ultramicropore, while methanol/acetone selectivity at high pressure depends on micropores of 1–2 nm. Our findings provide insights into the design and further development of adsorbents for VOCs adsorption and azeotrope separation applications.

3D-printed electrospun fibres for wound healing.

Wound management for acute and chronic wounds has become a serious clinical problem worldwide, placing considerable pressure on public health systems. Owing to the high-precision, adjustable pore structure, and repeatable manufacturing process, 3D-printed electrospun fibre (3DP-ESF) has attracted widespread attention for fabricating wound dressing. In addition, in comparison with 2D electrospun fibre membranes fabricated by traditional electrospinning, the 3D structures provide additional guidance on cell behaviour. In this perspective article, we first summarise the basic manufacturing principles and methods to fabricate 3DP-ESF. Then, we discuss the function of 3DP-ESF in manipulating the different stages of wound healing, including anti-bacteria, anti-inflammation, and promotion of cell migration and proliferation, as well as the construction of tissue-engineered scaffolds. In the end, we provide the current challenge faced by 3DP-ESF in the application of skin wound regeneration and its promising future directions.

Ru-modulated morphology and electronic structure of nickel organic framework bifunctional electrocatalyst for efficient overall water splitting

Metal-organic frameworks (MOFs) are considered as prospective electrocatalysts for water splitting due to their adjustable pore structure and abundant active sites. However, the rational design of MOFs with excellent oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) performances is still an enormous challenge. Herein, Ru-doped nickel thiophene dicarboxylic acid (Ni-TDA)/nickel foam (NF) were prepared via a one-pot solvothermal method, and their morphologies and electronic structures can be facilely modulated by Ru doping contents. The as-prepared self-supporting Ni5Ru-TDA/NF with Ni/Ru molar ratio of 5:1 show the excellent OER and HER activities with low overpotentials of 235 and 35 mV at a current density of 10 mA cm−2 in 1 M KOH, respectively. Furthermore, Ni5Ru-TDA/NF indicate the remarkable stability during the process of OER and HER with the slight decrease after the stability test of 60 h. The excellent electrocatalytic activities can be attributed to high intrinsic activity of multiple Ru species, the synergistic effect of Ru and Ni sites and abundance active sites in Ru-doped Ni-TDA. The water electrolysis system using Ni5Ru-TDA/NF as the anode and cathode, respectively, can achieve a current density of 10 mA cm−2 with a cell voltage of only 1.53 V, which is promising for practical applications.

ZnS/CoS@C Derived from ZIF-8/67 Rhombohedral Dodecahedron Dispersed on Graphene as High-Performance Anode for Sodium-Ion Batteries.

Metal sulfides are highly promising anode materials for sodium-ion batteries due to their high theoretical capacity and ease of designing morphology and structure. In this study, a metal-organic framework (ZIF-8/67 dodecahedron) was used as a precursor due to its large specific surface area, adjustable pore structure, morphology, composition, and multiple active sites in electrochemical reactions. The ZIF-8/67/GO was synthesized using a water bath method by introducing graphene; the dispersibility of ZIF-8/67 was improved, the conductivity increased, and the volume expansion phenomenon that occurs during the electrochemical deintercalation of sodium was prevented. Furthermore, vulcanization was carried out to obtain ZnS/CoS@C/rGO composite materials, which were tested for their electrochemical properties. The results showed that the ZnS/CoS@C/rGO composite was successfully synthesized, with dodecahedrons dispersed in large graphene layers. It maintained a capacity of 414.8 mAh g-1 after cycling at a current density of 200 mA g-1 for 70 times, exhibiting stable rate performance with a reversible capacity of 308.0 mAh g-1 at a high current of 2 A g-1. The excellent rate performance of the composite is attributed to its partial pseudocapacitive contribution. The calculation of the diffusion coefficient of Na+ indicates that the rapid sodium ion migration rate of this composite material is also one of the reasons for its excellent performance. This study highlights the broad application prospects of metal-organic framework-derived metal sulfides as anode materials for sodium-ion batteries.

Exceptional activity of hollow porphyrin frameworks-confined Ni nanoparticles for hydrogen production from NaBH4 methanolysis

Hollow framework materials have recently attracted broad interest owing to the multifarious superiorities, such as large surface area, adjustable pore structure, short transport distance, as well as high permeability. Herein, a nitrogen-rich hollow porphyrin framework (H-POF) was synthesized via SiO2 as hard template. Then, ultrafine Ni nanoparticles (NPs) were confined on the surface of H-POF via ultrasonic impregnation reduction method. The resultant Ni/H-POF catalyst shows an extraordinary catalytic performance toward the methanolysis of NaBH4, providing a hydrogen generation rate (HGR) value of 34720 mL·min−1·gmetal−1, which surpasses all heterogeneous catalysts ever reported with NaOH. Further experimental investigation confirms that the high catalytic activity can attributed to the large specific surface area and hollow structure of the support, small size of metal NPs, as well as the electron-donating effect of nitrogen atoms on metal NPs. Based on isotopic experiments, the breaking of OH bond in CH3OH is proved to be the rate-determining step (RDS) of NaBH4 methanolysis. This work provides valuable insights for rationally designing nitrogen-rich hollow framework materials for supporting ultrafine metal NPs, which will be used for the future energy-related applications.

Review on Nitrogen-Doped Porous Carbon Materials for CO2 Adsorption and Separation: Recent Advances and Outlook

One of the most serious environmental problems is the global warming brought by CO2 and other greenhouse gases. Thus, the development of Carbon Capture, Utilization, and Storage Technology (CCUS) is urgent. Thereinto, the merits of porous carbon adsorption materials are their substantial specific surface area, stable physical and chemical properties, adjustable pore structure, etc., and they are considered to be good adsorbents for CO2. The adsorption properties of porous carbon material are capable of being directionally controlled by regulating the collocation of carbonization and activation methods and setting the technological parameters used in the preparation process. In addition, nitrogen doping can enhance the effect between adsorbent and adsorbate, leading to higher CO2 adsorption capacity. After in-depth studies, although there is still no clear explanation on the mechanism of nitrogen-doped enhancement of the adsorption properties of the adsorbent, it can be confirmed that the main reason is not the traditional acid–base theory, but a large number of micropores, specific surface area, and induction forces are more likely to be the root cause. The porous carbon materials preparation methods, pore structure adjustment strategies, and the types of functionalization and mechanism between nitrogen-doped sites and adsorbents are highlighted in this Review. Finally, the future development direction and existing challenges of this emerging field are also discussed.

Recent advances for water-stable metal-organic frameworks (MOFs)

Metal-organic framework (MOF) compounds have been widely studied and explored for many years due to their diversity of structure and composition. It is a new kind of framework material because of its high specific surface area, high porosity, and adjustable pore structure and internal environment. It has unlimited development prospects in gas storage, separation, catalysis, chemical sensing, and other related fields. Therefore, MOFs have attracted great and extensive attention. This paper mainly summarizes MOFs materials with good water stability, and stability of MOFs compounds under various harsh environmental conditions was analyzed, and the synthetic method and properties of these MOFs materials were summarized. In conclusion, this paper for the summary of the water-resistant MOFs compounds is helpful to provide a good guide to finding or creating other novel water stability MOFs functional materials.

Catalytic pyrolysis of cellulose using ZnZrO/HZSM-5 catalysts for light aromatics

ABSTRACT The HZSM-5 catalytic pyrolysis of cellulose to aromatics is one of the effective ways to realize its high-value utilization. However, HZSM-5 has strong acidity, and its microporous structure leads to low mass transfer of reactants and products. The ZnZrO/HZSM-5 catalysts with adjustable pore structure and acidity were developed for efficient conversion of cellulose to aromatics. Their physicochemical properties were characterized by XRD, N2 adsorption, SEM and NH3-TPD and their performance was studied. As the ratio of ZnZrO increases from 0 to 1, the pore size increased from 1.98 nm to 6.77 nm. When the ZnZrO ratio was 0–0.25, the Bronsted acid sites decreased, and the difference was not significant at 0.25–0.375. When the ZnZrO ratio is 0.375–1, the Bronsted acid sites continued to decrease. The random repeated exposure of cellulose cracking gas in ZnZrO and HZSM-5 made more opportunities for aromatization and cracking. ZnZrO-0.125 showed the performance. The yield of BTEX was 83.15%, and the selectivity was 95.15%. Compared with the traditional HZSM-5, the yield increased by 5.7% and the selectivity increased by 11.38%.