Adjacent Water Research Articles

Productive Characteristics of Benthic Phytocenoses in Some Areas of the Crimean Coast (Black Sea)

The results of studying the production potential of phytocenoses of fouling of coastal hydraulic structures (groins) and solid substrates of the adjacent water area in the southwest (Lyubimovka and Foros villages), south (Cape Martyan) and southeast (eastern embankment of the city of Alushta) of Crime are reflected. Analysis of the periphyton and benthic communities showed the production superiority of Rhodophyta in periphyton and Ochrophyta in benthos. Dominants and codominants with high absolute phytomass belong to the genera Ericaria Stackhouse and Gongolaria Boehmer. The absolute phytomass of the cenosis, the relative phytomass Ochrophyta, and the Shannon index vary without exceeding the norm established for biological objects. The absolute and relative phytomass of Chlorophyta is characterized by increased variability.

Atomistic insights into the performance of thermodynamic inhibitors in the nucleation of methane hydrate

Figure TOC Comparison of methane hydrate nucleation process (a) without or (b) with EG molecules. Critical nucleus size increase under the influence of Thermodynamic hydrate inhibitors. • Hydrophobic groups from the alcohols could approach the initial hydrate cages and destroy initial clusters. • The –OH groups were observed to form hydrogen bonds with the cage clusters and even initiate a new hydrate cage. • Alcohols can increase the critical nucleus size of gas hydrate. Thermodynamic inhibitors are intensively used in oil and gas pipelines to modify the formation conditions of gas hydrate, preventing the blockage of pipelines. However, their kinetic performance in hydrate nucleation is largely unclear. Herein, the molecular interactions of the small molecules of ethylene glycol and methanol with hydrate clusters were investigated. It was found that the hydrophobic groups from the glycols could approach the initial hydrate cages, thereby constricting the regional distribution of adjacent water molecules; thus, they functioned in the same way as the guest molecules that transiently helped to stabilize the water framework. However, these glycols would eventually dissolve into the solution to stay at the water/nanobubble interface; this would consequently destroy the initial cages upon losing the constraint from the surrounding hydrophobic molecules. In addition, the –OH groups were observed to form hydrogen bonds with the cage clusters and even initiate a new hydrate cage; however, they cannot stably reside there due to different atom coordination. Notably, these glycols can increase the critical nucleus size, which is considered the intrinsic mechanism of thermodynamic inhibition. Our results provide atomistic insights into the performance of glycols in the kinetic nucleation of gas hydrates and can help understand the interactions between guest and host molecules in the presence of hydrophobic and hydrophilic functional groups.

30 years trends of microplastic pollution: Mass-quantitative analysis of archived mussel samples from the North and Baltic Seas

Microplastics (MP) are ubiquitous throughout the environment as a result of an ongoing, increasing, but also lavish use, of plastics over time and its inherent persistence. In contrast, there are almost no data that allow drawing conclusions about the evolution of plastic pollution in the environment over the past decades. This study investigates the MP load in blue mussels from the North and Baltic Sea archived by the German Environmental Specimen Bank in a time series covering almost 30 years. Samples were enzymatically and chemically oxidative digested for MP extraction and subsequent analyzed mass-quantitatively for nine common polymer clusters by pyrolysis gas chromatography-mass spectrometry. Seven polymer clusters were detected in mussel tissue. Summed MP levels were at ppm levels (<20 μg/g mussel, dry weight). North Sea samples reflected a gradual increase from the 1980s/90s to the 2000s whereas those from Baltic Sea showed consistently higher, rather constant MP levels similar to the North Sea site later than 2000. Polymer composition of both sites stood out by cluster (C) of C-PVC and C-PET at both sites. Mussels from Baltic Sea site had larger C-PE and C-PP proportions. Opposed polymer- and site-specific trends indicated both regional and trans-regional MP sources for different polymer clusters. The MP composition of mussels showed strong similarities with adjacent sediment and water samples. The study introduces a relevant dataset addressing the temporal development of MP pollution. It emphasizes a high indicative potential of environmental MP composition/loads received by mussels but raises the necessity on adequate control materials accompany such kind of studies.

Demonstrating the Interfacial Polymer Thermal Transition from Coil-to-Globule to Coil-to-Stretch under Shear Flow Using SFG and MD Simulation.

Revealing interfacial shear-induced structural responsiveness has long been an important topic in that most fluids in nature and human life are in motion and cause interesting boundary phenomena. It is amazing how the polymer chain conformation or local structural features at a boundary change under the effective shear condition. In this study, microfluidic-assisted sum frequency generation (SFG) vibrational spectroscopy and all-atom molecular dynamics (MD) simulation are combined to reveal that the shear flow can effectively block the so-called thermal coil-to-globule transition of the poly(N-isopropylacrylamide) (PNIPAM) brushes on the solid substrate, and the normal coil-to-globule transition transfers to a coil-to-stretch one under shear flow with increasing ambient temperature. Such findings are attributed to the balance between the shear flow and the molecular interaction with respect to the polymer chains and adjacent water molecules, thus demonstrating the significant effect of the shear flow on the structural and dynamic behaviors of the polymer chains at the boundaries from the molecular level.

Analysis of Water Deer Roadkills Using Point Process Modeling in Chungcheongnamdo, South Korea

The expansion of road networks and increased traffic loads have resulted in an increase in the problem of wildlife roadkill, which has a serious impact on both human safety and the wildlife population. However, roadkill data are collected primarily from the incidental sighting, thus they often lack the true-absence information. This study aims to identify the factors associated with Korean water deer (Hydropotes inermis) roadkill in Korea using the point processing modeling (PPM) approach. Water deer roadkill point data were fitted with explanatory variables derived from forest cover type, topography, and human demography maps and an animal distribution survey. Water deer roadkill showed positive associations with road density, human population density, road width, and water deer detection point density. Slope and elevation showed negative associations with roadkill. The traffic volume and adjacent water deer population may be the major driving factors in roadkill events. The results also imply that the PPM can be a flexible tool for developing roadkill mitigation strategy, providing analytical advantages of roadkill data, such as clarification of model specification and interpretation, while avoiding issues derived from a lack of true-absence information.

Public preferences for green infrastructure improvements in Northern New Jersey: a discrete choice experiment approach.

Significant water pollution caused by flooding due to heavy precipitation and extreme weather events has become a considerable problem in urbanized areas such as in Northern New Jersey. These cities experience heavy downpour-related contamination and water pollution when stormwater and untreated sewage are diverted through combined sewer overflow drainage systems to adjacent water bodies. Green infrastructure has proven a successful intervention method for mitigating these unintended environmental consequences. However, while the effects of CSOs and the ability of GI to reduce them are well documented, there has been considerably less study addressing public preferences and willingness to pay for GI-based solutions. As such, this study seeks to understand these facets of GI management in urbanized areas of New Jersey, focusing on Newark, Paterson, and Elizabeth townships. A discrete choice experiment method was used to analyze the willingness of residents to pay for additional CSO infrastructure through the installation of GI options such as bioretention gardens, rain barrels, and green roofs. Furthermore, study identified attributes such as secondary benefits, proximity, and water retention that respondents found the most utility in when choosing GI stormwater management interventions. We found that several attributes, including improved air quality ($58.60), increased water supply ($49.71), and closer proximity ($110.01–$125.97) had the highest utility and similarly were associated with a higher willingness to pay than other tested attributes. These findings are important in assessing the overall attitude toward these fixtures, and may be critical in crafting local policy and development, especially to address environmental equity.

Regulation of Algal Bloom Hotspots Under Mega Estuarine Constructions in the Changjiang River Estuary

Massive large-scale engineering projects have been built in river estuaries around the world, but their effects on environments in the surrounding coastal waters were less emphasized compared to those due to the watershed projects. In this study, we used the Changjiang River Estuary as an example to show that a significant consequence can be resulted in such a situation. Through analyzing the harmful algal bloom events data and the chlorophyll satellite data, we investigate the spatiotemporal variations of algal blooms in the estuary and its adjacent water. The results indicate that the location of algal bloom hotspot changed over the period of the estuarine constructions. Furthermore, using a well-validated numerical model, we explored the mechanisms responsible for such an ecosystem regime shift. It was found that after the estuarine constructions were built, the surface chlorophyll maximum was attenuated and part of it migrated landward north of the river mouth but was strengthened south of the river mouth and extended seaward. Alternations of the nutrient concentration distribution and turbidity distribution induced by river plume deviation are responsible for the redistribution of the high chlorophyll concentration area. By contrast, the direct impact of the Three Gorges Dam through changing the runoff and sediments flux, which has been highlighted in numerous studies, was less important than expected. Given the fact that Three Gorges Dam and mega estuarine constructions were built in a similar period, any observed regime shift of hydrodynamic and ecological status outside the estuary should be interpreted with particular caution.

Accumulation and release of organic phosphorus (P) from legacy P-affected soils to adjacent drainage water

Accumulation and release of organic phosphorus (P) from legacy P-affected soils to adjacent drainage water

Annual Lateral Organic Carbon Exchange Between Salt Marsh and Adjacent Water: A Case Study of East Headland Marshes at the Yangtze Estuary

Blue carbon (C) ecosystems (mangroves, salt marshes, and seagrass beds) sequester high amounts of C, which can be respired back into the atmosphere, buried for long periods, or exported to adjacent ecosystems by tides. The lateral exchange of C between a salt marsh and adjacent water is a key factor that determines whether a salt marsh is a C source (i.e., outwelling) or sink in an estuary. We measured salinity, particulate organic carbon (POC), and dissolved organic carbon (DOC) seasonally over eight tidal cycles in a tidal creek at the Chongming Dongtan wetland from July 2017 to April 2018 to determine whether the marsh was a source or sink for estuarine C. POC and DOC fluxes were significantly correlated in the four seasons driven by water fluxes, but the concentration of DOC and POC were positively correlated only in autumn and winter. DOC and POC concentrations were the highest in autumn (3.54 mg/L and 4.19 mg/L, respectively) and the lowest in winter and spring (1.87 mg/L and 1.51 mg/L, respectively). The tidal creek system in different seasons showed organic carbon (OC) export, and the organic carbon fluxes during tidal cycles ranged from –12.65 to 4.04 g C/m2. The intensity showed significant seasonal differences, with the highest in summer, the second in autumn, and the lowest in spring. In different seasons, organic carbon fluxes during spring tides were significantly higher than that during neap tides. Due to the tidal asymmetry of the Yangtze River estuary and the relatively young stage, the salt marshes in the study area acted as a strong lateral carbon source.

Impact of Sewage Water Plant Seepage on Water Quality of Abu Simbel khor’s in Abu Simbel City

The aim of the present study is to examine the water quality of Abu Simbel khor’s, Nasser Lake during the period of flooding and receding water to explores the potential pollution hazards coming from these Khors to the whole Lake through several physico-chemical and bacteriological analyses. Results obtained from calculated water quality index (WQI) showed that the drop in Lake Nasser water's levels led to a decline in the water quality of the Lake and Abu Simbel Khor, from the order of good (period of flooding) to medium (period of receding water). This impact may in turn influence the whole Lake due to water rebounce from the Abu Simbel Khor, to the main channel. Total dissolved solids (TDS), biological oxygen demand (BOD), turbidity and recognizable depletion in dissolved oxygen (DO) were observed in sewage station and affected on Lake Nasser water area adjacent seepage water area. Pollution from total and fecal coliforms as well as fecal streptococci didn't exceed permissible limits except for sewage station basin that discharge agricultural and sewage wastes are the key factors in this environmental problem, particularly in period of receding water. Therefore, it is further concluded that the Abu Simbel Khor, could be considered as potential pollution sources during low water levels of the lake.

ТРАНСФОРМАЦИЯ АНОМАЛИЙ СИЛЫ ТЯЖЕСТИ В ПРЕДЕЛАХ БОЛЬШИХ ТЕРРИТОРИЙ (НА ПРИМЕРЕ КУРИЛЬСКОЙ ОСТРОВНОЙ ДУГИ)

An algorithm and a program for transformation of gravity anomalies for large territories are presented. The spherical shape of Earth is taken into account and the geodetic coordinates of measuring points are used. The calculations use the «quasi-ellipsoidal» model of V.V. Kavraisky, which allows the transition from geodesic to spherical coordinate system with increased accuracy. The algorithm is based on a source-like approximation of the field values, located in the nodes of a regular network, with the depths of the equivalent sources, depending on the latitude. To determine the source masses, the system of linear algebraic equations is solved by the fastest gradient descent method with an accelerated step calculation. The results of transformation of the gravity field in the Bouguer reduction for the Kuril island arc, the adjacent water areas and parts of land, located within 40°–54° N, 142°–162° E are presented with a total area of about 2.4 million km2. A slight difference between the recalculation results of gravity anomalies into the upper half-space using the «spherical» and «quasi-ellipsoidal» models of the Earth was experimentally established.

A Multi-year Seasonal Study of Amoeboid Protists in Surface Water at the Margin of a Hudson River Estuary Salt Marsh

Marshes bordering rivers and estuaries are productive ecosystems that interact dynamically with the adjacent water mass. This is a multi-year study (2019–2022) of seasonal changes in the density of naked amoebae in monthly samples from the surface water of the Hudson estuary near Piermont, N. Y. with relationships to key environmental variables (surface water temperature, salinity, Secchi depth representing turbidity, and enterococcus bacterial counts). During the colder months (November to March), when decayed leaves and litter from the deciduous marsh grass produced organic matter in the sediment surface, the mean abundance of active amoebae ± standard error of the mean (SEM) was higher (3.07 ± 0.99 × 10⁴/ L, N = 7). In warmer months (May to September) the abundance of amoebae was lower (1.35 ± 0.29 × 10⁴ / L, N = 10). A multivariate linear regression analysis was performed relating amoeba abundance to four major water mass variables, resulting in the following statistically significant equation (p = 0.03): AD = 0.121 × T + 0.301 × L – 0.047 × S + 0.359 × C, where: AD = active amoebae density (× 10 /L), T = temperature ( C), L = tide level (m), S = Secchi disc depth (cm) and C = bacterial enterococcus concentration (number/ml). In general, given the increasing evidence of the potential importance of amoeboid protists in aquatic ecosystems, further research is warranted on their role in food webs and the carbon biogeochemical cycle within heterotrophic estuarine and coastal waters.

The Salmonid fishes of Lake Baikal and its adjacent water systems: annotated checklist with new taxa description

Abstract. The updated list of Salmonid fishes of Lake Baikal and its adjacent basins is presented with data on nomenclature, diagnostic characters and distribution, systematics notes and illustrations. At present, 20 species of salmon-like fish belonging to eight genera and three families (Coregonidae, Salmonidae and Thymallidae) have been indicated in the Baikal region. The validity of the species Coregonus skrjabini Karasjov, 1987; Coregonus sajanensis Gundriser, 1978 and Brachymystax czerskii Kirillov, 1979 has been restored. A new replacement name Coregonus karasjovi Bogdanov (nom. nov.) has been established for Baunt cisco-liked whitefish. A new species of grayling Thymallus lenensis Knizhin (sp. nov.) has been described.

Digital model of the «Carbon test site in Krasnodar region» on the base of SBIO RAS (Gelendzhik)

An aerophotography of the experimental area on the Tuaphat massif (area of 6 ha, SBIO RAS) and a bathymetric survey of the adjacent water area have been made within the framework of the “Carbon test site in Krasnodar Region” development. Digital relief models (DRM) of the test site onshore and offshore components were developed based on the survey results. The article presents the methods of work and graphical representation of the developed DRM.

Histological Alterations in Some Organs of African Catfish (Clarias gariepinus) Exposed to Sub-lethal Concentrations of Glyphosate [N-(phosphonomethyl) glycine

This study used a static bioassay to investigate the histological effects of glyphosate on the gill, liver and muscle of African catfish (Clarias gariepinus) fingerlings. This was done with a view of further characterising the effect of glyphosate on C. gariepinus fingerlings and other aquatic life forms. Six-week old C. gariepinus fingerlings with an average weight of 10.02 ± 0.2 g were stocked into three exposure sets (control, 2.75 ppm (25% of the 96 h LC50 value) and 5.50 ppm (50% of the 96 h LC50 value)) in triplicate at 30 fish per tank for 70 days. The 96 h LC50 value was 11.00 mg/L. Histological examination of the C. gariepinus exposed to various sublethal concentrations of glyphosate showed that major histological changes in their organs were concentration dependent such as gill arch vacuolation, excessive mucosal secretions, lifting of epithelial, and epithelium thickening, hyperplasia and telangiectasis in the gills, discolouration, change in form and consistent alterations involving hyperplasia, narrowing of the central nerve, necrosis, pkynosis, blood congestion and vacuolation of the liver, mild hyperplasia and inflammatory responses in the muscle of the fish. The severity of histological alteration was more pronounced in fish organs exposed to 5.50 ppm of glyphosate concentration. This study concluded that the toxicant (glyphosate) is highly toxic to C. gariepinus particularly at a concentration of 5.50 ppm, therefore its use near farm lands or adjacent water bodies should be discouraged.

Lead contamination of soils, sediments, and vegetation in a shooting range and adjacent terrestrial and aquatic ecosystems: A holistic approach for evaluating potential risks

It is well accepted that shooting ranges constitute hotspots of Pb contamination. This study evaluated the degree of Pb contamination of soils, sediments and vegetation within the boundaries of a highly visited shooting range, as well as the fluvial transport and dispersal of Pb, and therefore the contamination of adjacent river and water reservoir. Soils in the shooting range were severely contaminated with Pb, as indicated by the values of enrichment and contamination factor. The concentration of Pb in these soils ranged from 791 mg kg−1 to 7265 mg kg−1, being several dozens or even hundreds of times higher compared with control background samples. A temporary stream being in close proximity was also polluted, though to a much lesser extent. The degree of Pb contamination was negatively correlated with the distance from the shooting range. To this effect, the degree of contamination of the river and the water reservoir being in the vicinity of the shooting range was negligible, as sediments and water samples preserved similar Pb concentrations with control samples. However, cultivated (olives) and wild native plant species grown in the area of the shooting range were found to uptake and accumulate high concentrations of Pb in their tissues (even 50 times higher compared with control samples). The severe contamination of soils, sediments and vegetation in the studied shooting range can provoke very high ecological risks. Overall, results suggest that management measures should be undertaken within the boundaries of the studied shooting range.

Remote Triggering of Damage Followed by Healing Recorded in Groundwater Pressure

Water levels in three adjacent water wells in the Yarmouk Gorge area have all responded to the 2020 Elazığ Mw 6.8 teleseismic earthquake. Water levels in two aquifers exhibited reciprocal behavior: during the first eight days after the earthquake, water level decreased by 40 cm in the deeper highly confined aquifer, and increased by 90 cm in the shallower less confined aquifer. The recovery of the water levels in both aquifers continued for at least three months. We interpret these observations as reflecting the increase in damage along the fault at the Yarmouk Gorge. Ground shaking increased the damage and permeability of this fault, temporarily connecting the two aquifers, allowing flow from the deep aquifer to the shallow one. Model results showing decreased permeability suggest that the fault healed by one order of magnitude within three days. This is the first documentation of decrease in permeability in a fault zone within such short time scales.

Effectiveness assessment of using riverine water eDNA to simultaneously monitor the riverine and riparian biodiversity information

Both aquatic and terrestrial biodiversity information can be detected in riverine water environmental DNA (eDNA). However, the effectiveness of using riverine water eDNA to simultaneously monitor the riverine and terrestrial biodiversity information remains unidentified. Here, we proposed that the monitoring effectiveness could be approximated by the transportation effectiveness of land-to-river and upstream-to-downstream biodiversity information flows and described by three new indicators. Subsequently, we conducted a case study in a watershed on the Qinghai–Tibet Plateau. The results demonstrated that there was higher monitoring effectiveness on summer or autumn rainy days than in other seasons and weather conditions. The monitoring of the bacterial biodiversity information was more efficient than the monitoring of the eukaryotic biodiversity information. On summer rainy days, 43–76% of species information in riparian sites could be detected in adjacent riverine water eDNA samples, 92–99% of species information in riverine sites could be detected in a 1-km downstream eDNA sample, and half of dead bioinformation (the bioinformation labeling the biological material that lacked life activity and fertility) could be monitored 4–6 km downstream for eukaryotes and 13–19 km downstream for bacteria. The current study provided reference method and data for future monitoring projects design and for future monitoring results evaluation.

Runoff mitigation via micro-dams and conservation tillage-Numerical modeling of runoff and erosion from maize field trials.

Runoff and erosion are the most important transport pathways of water, sediment, and associated pesticides from sloped agricultural fields. This results in the loss of fertile topsoil material, nutrients, irrigation water, and plant protection products (PPP) into adjacent surface water bodies. In the European and US risk assessment for the registration of PPP, runoff and erosion are numerically calculated with the simulation Pesticide Root Zone Model (PRZM) using the US Department of Agriculture (USDA) runoff curve number (CN) concept for the water movement and the MUSS equation to quantify the sediment transfer. This work presents an evaluation of maize field trials conducted in three seasons that considered micro‐dams (i.e., small earthen dams between the rows; also known as “furrow diking,” “furrow damming,” etc.) and/or conservation tillage (via subsoiling) as mitigation measures to investigate the effects on the reduction in runoff and erosion. Measured quantitative reductions and event‐wise calculated CN are presented. Furthermore, the trials were simulated using the PRZM over the complete vegetation period and runoff CN as well as parameter values of the MUSS erosion equation (a relative adaptation of the C‐factor) were inversely estimated. Compared with the control plots (i.e., conventional tillage), micro‐dams or conservation tillage reduced runoff by 24%–71% or 69%–89%, and erosion by 54%–81% or 91%–98%. Based on these data, a robust case can be made to lower CN or parameters in the MUSS equation for surface water exposure scenarios to consider the effects on predicted environmental concentrations (PECs) and estimated environmental concentrations (EECs). Mean resulting CN reductions by micro‐dams or conservation tillage were ascertained to be 6% (±2.5%) or 12% (±3.0%), the C‐factor was reduced by a factor of 0.1 (±0.15) or 0.48 (±0.19). Example calculations show reductions in the ranges of 11%–100% for PECs and 30%–98% for EECs. Integr Environ Assess Manag 2022;18:1348–1363. © 2021 Bayer AG Crop Science. Integrated Environmental Assessment and Management published by Wiley Periodicals LLC on behalf of Society of Environmental Toxicology & Chemistry (SETAC).

Tracking historical sources of polycyclic aromatic compounds (PACs) in dated lake sediment cores near in-situ bitumen operations of Cold Lake, Alberta

Most bitumen in the Alberta oil sands (Canada) is extracted by thermal in-situ recovery. Despite the widespread use of in-situ bitumen extraction, little information is available on the release of petroleum hydrocarbons by this method to adjacent land and water. Here we analyzed the composition and abundance of parent and alkylated polycyclic aromatic compounds (PACs) in 11 radiometrically-dated lake sediment cores collected near in-situ operations at Cold Lake Alberta to assess potential petroleum contamination sources to surrounding lakes over the past century. Like open-pit mining areas, alkylated PACs in Cold Lake sediments were elevated compared to unsubstituted parent PACs and increased coeval with the onset of bitumen extraction in the area. Diagnostic ratios and pyrogenic indices showed that PAC sources to these lake sediments were dominantly pyrogenic, likely from historic forest fires, however they shifted to more petrogenic sources coeval with expanding oil sands extraction at Cold Lake. PACs in sediment from regional lakes are weakly correlated to their proximity to in-situ oil wells, once corrected for lake area. These results suggest that in-situ operations, via diesel-fueled vehicular emissions and the combustion of natural gas for steam generation, are a source of PACs to nearby lakes, but PACs did not exceed Canadian sediment quality guidelines for the protection of aquatic life.