Adhesion Performance Research Articles

Effects of surface micro-texturing laser-etching on adhesive property and failure behaviors of basalt fiber composite single-lap-joint

Laser-etching technology can perform micro-nano processing on the sub-surface of composite, thereby enhancing its mechanical interlocking to improve the adhesive performance. However, it can easily cause surface fiber damage and destroy the integrity of composite. Hence, the influences of surface micro-texturing and laser-etching effect on the adhesive property and failure behaviors of basalt fiber reinforced polymer (BFRP) composite single-lap-joint are investigated. Here, different surface micro-texturing of BFRP with different laser-etching power and line space are processed by laser-etching. The surface morphology and wetting property of experimental samples are characterized, and single lap tests are conducted to evaluate the adhesive properties. Results show that the adhesive property firstly increases and then decreases with the laser power increase, where the samples etched with 10 W and line space of 0.1 mm perform the best. It is found that the epoxy on the surface is removed by laser-etching to improve the contact area, but the fiber damage is formed to affect the adhesive property. When the laser-etching reaches a certain depth in spite of fiber damage, it can achieve the best bonding performance with the balance of performance and structural integrity. Finally, the multi-scale simulations are conducted to effectively demonstrate the laser-etched interface bonding behavior and damage evolution process of BFRP single lap joints.

Laboratorial investigation on optical, thermal and pavement performance of biomimetic dark reflective coatings with composite structure for pavement cooling

The surface temperature of asphalt pavement in summer can reach up to 70 °C, which leads to poor outdoor thermal comfort and exacerbates the urban heat island effect. Reflective coatings can effectively reduce pavement temperature, but their intrinsic light color with high reflectance causes safety issues such as glaring. In this study, based on the biomimetic idea of chameleon skin structure, composite pavement coatings for cooling and anti-glare were developed. Their optical properties, thermal behavior, adhesion and skid-resistance performances were investigated. The results showed that near-infrared reflectance of black and grey double-layer reflective coatings could reach 0.66 and 0.70, respectively (58 % higher than single-layer coatings). The optimal mass fraction of perylene black in the upper black/grey coating was 2.94 % and 0.74 %, respectively. The double-layer dark coatings could decrease the temperature by 14 °C at the depth of 3 cm below road surface, which achieved cooling effect close to that of white single-layer reflective coatings. The adhesion between coating and stone was generally higher than the cohesion of asphalt, therefore, opening traffic for a period of time or carrying out micro-milling before coating could improve the abrasion resistance. Due to increase in the thickness of the double-layer coating, the microscopic texture of road surface was reduced, thereby reducing skid-resistance. However, it still met the standard requirements. This study intends to provide a reference for developing pavement coatings that balance cooling and visual safety to mitigate the heat island effect, and improve the sustainability of transportation infrastructure.

UV-driven self-replenishing liquid-infused surface with promising anti-algal adhesion performance.

Slippery liquid-infused porous surfaces (SLIPSs) inspired by Nepenthes have attracted much attention owing to their potential application in various cutting-edge fields. However, the performance of SLIPSs is impeded by surface damage and lubricant depletion, thereby limiting their further application. Herein, a UV-responsive slippery surface (SMEMG) was fabricated by introducing the UV-responsive functional group coumarin into the polymer side chain through random copolymerization, followed by crosslinking, curing and impregnation with vegetable oil. The self-healing ability and lubricant self-replenishing performance of the SMEMG were investigated. The results show that upon exposure to UV light, the damaged surface substrate can be repaired through a reversible photodimerization reaction between coumarin groups. Meanwhile, the lubricant oil within the bulk of the SMEMG substrate can be extruded to the surface during the photodimerization reaction, facilitating the recovery of surface wettability. The SMEMG exhibited excellent self-cleaning and anti-algal properties as well as durability in a harsh environment, demonstrating its promising application in marine anti-fouling.

Sustainable chitin-derived elastomers via grafting strategy with tunable mechanical and adhesion properties

With increasing environmental awareness and the pursuit of sustainable development goals, environmentally friendly sustainable thermoplastic elastomers (TPEs) derived from natural resources are highly desired to replace traditional TPEs. However, preparing sustainable TPEs with high mechanical properties and multifunctionality from biobased feedstocks remains a significant challenge. In this work, a series of chitin-graft-poly(acrylamide-co-2-ethylhexyl acrylate) (Chitin-g-P(AM-co-EHA)) copolymers were synthesized through reversible addition-fragmentation chain transfer (RAFT) polymerization. The tensile strength of Chitin-g-P(AM-co-EHA) copolymers can be tuned over a wide range from 1.0 to 7.3 MPa by adjusting the chitin and PAM contents. Benefiting from the brush-like architecture, Chitin-g-P(AM-co-EHA) copolymer exhibits improved mechanical properties over its linear counterparts. Moreover, these Chitin-g-P(AM-co-EHA) copolymers show good adhesion performance on different substrates. The shear strength can achieve 7.5 MPa for Chitin0.8-PAM50, which is high enough for commercial applications. The combination of chitin and grafting strategy can promote the development of strong chitin-based sustainable elastomers. This approach can be further utilized to design novel high-performance biobased elastomers and adhesives derived from natural resources.

Impact of ultraviolet radiation energy curing UV primer on adhesion of bamboo lumber surfaces and colorimetry of UV inkjet coatings

ABSTRACT The application of UV digital inkjet printing technology in the home furnishing industry has greatly enriched the diversity of decorative panels. Controlling the UV radiation energy curing UV primers process has a significant impact on the performance of UV printing coatings on bamboo surfaces. The results showed that the UV radiation energy is in the range of 60∼300 mJ cm−2, the adhesion of the UV primer on the surface of bamboo is the best when it is controlled at 180 mJ cm−2, which reaches the standard of 0 level; when the radiation energy reaches 240 mJ cm−2, the content of oxygen-containing functional groups on the surface of the primer is higher, the surface wettability is the best, and the roughness is also relatively high. When the radiation energy reaches 360 mJ cm−2, radiation energy that is too high would reduce the adhesion performance of the UV primer on the surface of bamboo lumber. In addition, the gloss difference of the UV ink coatings between adjacent parameter samples is small, while the color difference is more obvious. The energy of UV radiation should be controlled in the range of 180∼240 mJ cm−2 in the actual production application.

Fish Gelatin-Based Flexible and Self-Healing Hydrogel Modified by Fe2(SO4)3.

The application of fish gelatin (FG) is limited due to its poor mechanical properties and thermal stability, both of which could be significantly improved by gellan gum (GG) found in previous research. However, the FG/GG composite hydrogel was brittle and easily damaged by external forces. It was found that the composite hydrogel with Fe2(SO4)3 showed good flexibility and self-healing properties in the pre-experiment. Thus, the synergistic effect of FG, GG and Fe2(SO4)3 on the mechanical properties of the composite hydrogel was investigated in this study. According to one-way experiments, response surface tests and Texture Profile Analysis, it was found that under the optimum condition of FG concentration 186.443 g/L, GG concentration 8.666 g/L and Fe2(SO4)3 concentration 56.503 g/L, the springiness of the composite cylindrical hydrogel with the height of 25 mm formed in 25 mL beakers (bottom diameter 30 mm) was 7.602 mm. Determination of the rheological properties, compression performance, adhesive performance and self-healing properties showed that the composite hydrogel had good thermal stability, flexibility and self-healing properties with good adhesion, skin compliance and compressive strength, and it was easy to remove. The composite hydrogel showed strong antimicrobial activity against A. salmonicida and V. parahaemolyticus. All hydrogels showed a uniform and porous structure. The 3D structure of the composite hydrogel was much looser and more porous than the pure FG hydrogel. The flexible and self-healing composite hydrogel with some antimicrobial activity is suitable for the development of medical dressings, which broadens the applications of the composite hydrogel.

Enhanced corrosion protection of steel strip through advanced Zn–Mg alloy coatings manufactured by Continuous Physical Vapor Deposition: A review

The growing global consensus on the “carbon peak and neutrality” has focused on high-strength steel, highlighting its critical role in enhancing energy efficiency, reducing emissions in the steel industry, and reducing the weight of automobiles. Traditional Electro-Galvanizing (EG) and Hot-Dip Galvanizing (HDG) technologies face challenges in meeting the surface protection demands of these applications. This limitation is evident with the development of Zn–Mg coated strip steel, which offers high corrosion resistance. Continuous Physical Vapor Deposition (CPVD) effectively addresses these issues in a sealed vacuum environment, drawing significant attention in the strip coating industry owing to its superior surface quality, diverse material options, and environmental advantages. This article reviews the latest advancements and current status of Zn–Mg alloy coatings prepared using the CPVD technology. It discusses the typical thermal evaporation process used in CPVD, traces the development history of CPVD coatings on strip steel, and examines the microstructure, corrosion resistance, and adhesion performance evolution mechanisms of Zn–Mg alloy coatings. By designing multilayer structures, adjusting the Mg composition, and implementing controllable heat treatments, the overall performance of the coatings is enhanced. This study also comprehensively analyzes the feasibility of applying multilayer, highly corrosion-resistant Zn–Mg coatings. Additionally, it identifies the main challenges in applying CPVD technology to Zn–Mg coatings on strip steel, such as the large-scale, stable, and low-cost mass production of typical processes and controlling the void content at multilayer interfaces. Finally, future research directions are anticipated, underscoring the potentially significant impact of further alloying and computer simulations in advancing steel surface treatments.

Enhancing adhesive interlayer performance with waste tire rubber and amorphous poly alpha olefin compound modified asphalt

Insufficient bonding performance in interlayers is a key factor in the deterioration of bridge deck pavements. This study evaluates the bonding and durability of Waste Tire Rubber (WTR)/Amorphous Poly Alpha Olefin (APAO) modified asphalt compared to the commonly used Styrene-Butadiene-Styrene (SBS) modified asphalt. We conducted shear and pull tests to analyze how different bonding processes and the texture depth of the concrete surface affect bonding performance. The research also assessed the durability of the adhesive layer under conditions such as temperature fluctuations, water immersion, and aging. Results show that the choice of bonding method significantly impacts adhesive performance, with the coating bond method being superior to the crushed stone bond method. A concrete surface texture depth of 0.88 mm was identified as optimal for improving adhesive performance. Moreover, the WTR/APAO adhesive interlayer provided better adhesive and durability performance than the SBS adhesive interlayer under conditions of temperature fluctuations and water immersion. Based on these findings, the study recommends using the coating bond process and 15%WTR + 4%APAO modified asphalt for the adhesive interlayer.

Data-Driven Interpretable Machine Learning Prediction Method for the Bond Strength of Near-Surface-Mounted FRP-Concrete

The Near-Surface-Mounted (NSM) technique for Fiber-Reinforced Polymer (FRP) strengthening is widely applied in the seismic retrofitting of concrete structures. The key aspect of the NSM technique lies in the adhesive performance between the FRP, adhesive layer, and concrete. In order to accurately predict the bond strength of embedded reinforced NSM FRP–concrete, this study constructs the relationship between the influencing factors of bonding performance and bond strength based on four machine learning (ML) algorithms: Decision Tree (DT), Support Vector Machine (SVM), Random Forest (RF), and eXtreme Gradient Boosting (XGB). A unified and interpretable prediction method for FRP–concrete interface bond strength based on SHAP values and ML algorithms is proposed. The results indicate that the ML models exhibit good predictive performance, with the R2 of the test set ranging from 0.8190 to 0.9621, showing higher accuracy than empirical calculation formulas. Among them, the RF algorithm demonstrates the highest overall accuracy and optimal performance. Additionally, the SHAP (Shapley additional explanations) method quantitatively confirms that the width of the FRP strip has the most significant impact on bond strength. The newly developed hybrid ML model has the potential to become a new choice for accurately assessing the bond strength of NSM FRP strengthening technology.

Bond performance of fly ash-based geopolymer mortar in simulated concrete sewer substrate

Geopolymers have been extensively explored as a promising repair material for deteriorated Ordinary Portland Cement (OPC) concrete elements. However, knowledge of the adhesion performance of geopolymer to concrete substrates is limited. This study investigates the bond performance of low calcium fly ash geopolymer (FAGP) mortar and concrete for holistic acidic environmental conditions, such as in sewer rehabilitation. The bond evaluation was conducted by slant-shear test, performed at different substrate conditions, namely Rough-Dry, Rough-Saturated, Smooth-Dry and Smooth-Saturated, to simulate the in-service condition of a typical sewer pipe wall. The standard OPC repair mortar and a commercially available proprietary geopolymer repair product (P-GP) were evaluated and compared as controls to ascertain the viability of geopolymer for repair application. The shear bond strength of FAGP mortar was found to be in the order of 14 MPa, outperforming OPC and P-GP in all substrate conditions. Even though FAGP bond strength was insensitive to roughened substrate moisture levels, the synergistic effect of smoothness and moisture condition appeared detrimental. The testing of the prototype geopolymer-coated concrete pipe under line loading showed no sign of delamination at the bond plane. OPC and P-GP exhibited a distinct bond separation, which commenced at only 20 % of the ultimate load. The acid resistance and low permeability of FAGP mortar appeared to aid in preserving the repair bond.

Integrating Bioinspired Natural Adhesion Mechanisms into Modified Polyacrylate Latex Pressure-Sensitive Adhesives.

For polyacrylate latex pressure-sensitive adhesives (PSAs), high peel strength is of crucial significance. It is not only a key factor for ensuring the long-lasting and effective adhesive force of polyacrylate latex PSAs but also can significantly expand their application scope in many vital fields, such as packaging, electronics, and medical high-performance composite materials. High peel strength can guarantee that the products maintain stable and reliable adhesive performance under complex and variable environmental conditions. However, at present, the peel strength capacity of polyacrylate latex PSAs is conspicuously insufficient, making it difficult to fully meet the urgent market demand for high peel strength, and severely restricting their application in many cutting-edge fields. Therefore, based on previous experimental studies, and deeply inspired by the adhesion mechanism of natural marine mussels, in this study, a traditional polyacrylate latex PSA was ingeniously graft-modified with 3,4-dihydroxybenzaldehyde (DHBA) through the method of monomer-starved seeded semi-continuous emulsion polymerization, successfully synthesizing novel high-peel-strength polyacrylate latex pressure-sensitive adhesives (HPSAs) with outstanding strong adhesion properties, and the influence of DHBA content on the properties of the HPSAs was comprehensively studied. The research results indicated that the properties of the modified HPSAs were comprehensively enhanced. Regarding the water resistance of the adhesive film, the minimum water absorption rate was 4.33%. In terms of the heat resistance of the adhesive tape, it could withstand heat at 90 °C for 1 h without leaving residue upon tape peeling. Notably, the adhesive properties were significantly improved, and when the DHBA content reached 4.0%, the loop tack and 180° peel strength of HPSA4 significantly increased to 5.75 N and 825.4 gf/25 mm, respectively, which were 2.5 times and 2 times those of the unmodified PSA, respectively. Such superior adhesive performance of HPSAs, on the one hand, should be attributed to the introduction of the bonding functional monomer DHBA with a rich polyphenol structure; on the other hand, the acetal structure formed by the grafting reaction of DHBA with the PSA effectively enhanced the spatial network and crosslink density of the HPSAs. In summary, in this study, the natural biological adhesion phenomenon was ingeniously utilized to increase the peel strength of pressure-sensitive adhesives, providing a highly forward-looking and feasible direct strategy for the development of environmentally friendly polyacrylate latex pressure-sensitive adhesives.

Mussel-inspired tough ionogel with robust adhesion and mechanical adaptivity for impact resistance

Intrinsic adhesiveness and mechanical adaptivity allowing spontaneous anchoring and impact-stiffening, which facilitate safer impact protection, remain challenges for the design and synthesis of advanced tough impact-resistant materials. Herein, a novel biomimetic mechanically robust impact-resistant ionogel with the mussel-inspired diphasic structure was elaborately developed. The salt-bridge hydrogen bonds between carboxyl and imidazole groups inside rigid clusters serve as reversible crosslinking sites and prime energy-dissipation motifs, leading to strong noncovalent cohesion. Furthermore, the hydrophobic ionic liquid enriches surface interactions, providing extensive adhesive performance for in-situ attachment under external impact. Benefitting from the dynamic nature of the salt-bridge hydrogen bonds, the ionogel possesses impressive energy dissipation, self-healing, and recyclable properties. Notably, the prepared ionogel exhibits rate-dependent mechanical adaptivity and outstanding impact-stiffening performance with extraordinary initial modulus (∼6.3 GPa), impact strength (∼178.5 MPa), and impact toughness (∼89.6 MJ m−3) under high-speed impact (∼5200 s−1). This work offers promising biomimetic design inspirations for the future development of advanced, flexible, sustainable, and protective materials.

Barnacle-inspired amphipathic high strength adhesives under-water/oil

Adhesives designed for bonding in liquid environments have a broad application prospect. In general, amphiphilic polymer structures are important research objects for underwater bonding. And in the study of underwater adhesives, it was found that they can quickly dispel or absorb interfacial water and form reliable bulk strength and adhesion strength. However, achieving strong adhesion in both water-based and oily environments poses a significant challenge. In this work, an adhesive inspired by barnacles that can meet the bonding requirements in both water-based and oily environments has been prepared. Hydrophilic (polyethylene glycol (PEG)) main chains and hydrophobic (1-Octadecyl thiol (ODT)) side chains are simultaneously integrated into the polyurethane structure. Different from the past, hydrophobic and hydrophilic segments are included in the hard segment and soft segment microregion, respectively; At the same time, both hydrophilic and hydrophobic chain segments have strong crystallization, which greatly strengthens the driving force of molecular segments migration and phase separation compared with ordinary hydrophilic/hydrophobic structures. Water-based and oil-based solvents drive hydrophilic and hydrophobic molecular chains to diffuse to the surface, respectively, which enhances the adhesive strength to hydrophilic and hydrophilic surfaces, respectively. In comparison to the adhesion strength observed in air, the adhesion strength of the adhesive to polymethyl methacrylate (PMMA) increases by 1.72 times in oil environments (from 1.02 to 1.75 MPa). Similarly, the adhesion strength to aluminum (Al) increases by 2.23 times under water (from 1.82 to 4.04 MPa). These findings suggest that the regulation strategy for polymer chains employed in this study holds great potential for advancing adhesive performance in diverse environments.

Aging time improves adhesive performance of handmade starch paste for restoration of ancient Chinese books and its mechanism of action

In the restoration of ancient Chinese books, handmade starch paste serves as a paper adhesive, distinguished from traditional starch paste preparation methods. It involves special processes such as starch washing and aging, relying entirely on the artisanal expertise throughout the entire process. The study recreates the process of making handmade starch paste for the restoration of traditional ancient books and investigates the effects of aging time on the apparent viscosity, rheological properties, and adhesive performance of the paste. The results indicate that during aging, the pH of the starch paste decreases significantly, but it has a minimal impact on its apparent viscosity, rheological properties, and paper softness. However, it notably enhances the adhesive performance, with the optimal results observed after 3 days of aging. This is attributed to the decrease in residual protein content in the starch, as well as the significant improvement in swelling power and solubility of the starch. The results of infrared spectroscopy and XRD testing reveal that there are no significant changes in the molecular and crystalline structures of starch during the aging process. The acidic environment produced by starch fermentation promotes protein hydrolysis, emerging as the primary reason for the improved adhesive performance of the paste.

The Adhesion Performance in Green-Glued Finger Joints Using Different Wood Ring Orientations

Structural lumber is designed to meet the technical standards that ensure safety, cost-effectiveness, and sustainability. However, some tree species face limitations in their growth, which restricts their widespread use. An example of this is Nothofagus alpina, which has excellent mechanical properties but is not utilized much due to the challenges in extracting its timber and poor utilization, mainly because of the length of the wood. There is little information concerned with the uses and better management of small pieces using Nothofagus species, but it is still insufficient. This study investigates the adhesion performance of green-glued finger joints with varying wood ring orientations and moisture contents ranging from 21% to 25% using Nothofagus alpina. The primary aim is to assess how ring orientation and wet timber affect the green gluing process for creating larger wood pieces than sawn wood. The resulting products could meet the standards for wood serviceability number three for native Chilean wood. The findings indicate that finger joint performance improves with higher timber moisture levels. However, the orientation of the wood fibers did not significantly affect the performance under the tested conditions. It is important to note that this effect may become more significant near the fiber saturation point. These findings emphasize the need for a detailed protocol on the green gluing technique for Nothofagus alpina and the associated drying and surface processes in finger joint construction.

Do in vitro and in situ erosive challenges alter the bonding performance of universal adhesives?

ObjectiveTo evaluate microtensile bond strengths (μTBS), nanoleakage (NL), and degree of conversion (DC) of two universal adhesives, using etch-and-rinse (ER) or self-etch (SE) strategies on eroded dentin submitted to in vitro and in situ erosive challenges. MethodsDentin blocks were prepared from 120 human molars and categorized based on dentin condition (sound, in vitro eroded, and in situ eroded), adhesive system (Scotchbond Universal [SBU] and Zip bond Universal [ZIP]), and adhesive strategy (ER and SE). In the in situ erosive challenge, 20 volunteers wore acrylic resin palatal devices with dentin blocks, immersing them in cola soft drink for 90 s, six times daily for 15 days. The same erosive protocol was used in vitro, followed by rinsing and remineralization. Sound dentin blocks served as controls. Afterward, all dentin blocks were restored with composite resin and sectioned into resin-dentin bonded sticks for μTBS, NL, and DC assessments. Data were analyzed using three-way ANOVA and Tukey's test (α = 0.05). ResultsSound dentin exhibited the highest μTBS and DC values and the lowest NL values, while in situ eroded dentin showed the lowest μTBS and DC values and the highest NL values (p = 0.000001). While some differences in the μTBS values were observed between universal adhesives when evaluated on sound dentin (p = 0.0001), no significant differences between adhesives were observed when tested on in vitro and in situ eroded dentin. Regarding NL and DC, no significant differences were found between SBU and ZIP, as well as among adhesive strategies (p > 0.05). ConclusionErosion in dentin, especially under in situ conditions, presents significant challenges to the adhesion of restorative materials. The choice of an effective adhesive system is crucial, as dentin eroded in situ showed lower adhesion strength and greater nanoleakage. These results highlight the need for specific clinical strategies to improve the durability and effectiveness of restorations.

Room-Temperature Self-Healing and Recyclable Self-Crosslinked Isosorbide-Based Adhesive Bioelastomer.

Recently, renewable bio-based materials have received more and more attention due to environmental issues such as global warming and ecosystem destruction. In the present work, a series of isosorbide-based bioelastomers poly(isosorbide carbonate-co-butanediol aliphatic esters)s (PICBAs) are synthesized by a facile and economical two-step melt polycondensation. Due to the slightly self-crosslinking reaction of isosorbide, PICBAs exhibit excellent tensile strength and self-healing ability, the mechanical properties of PICBAs can recover over 95% after 48h under room temperature. In addition, PICBAs can stick different substances, such as glass, rubber, plastic, and stones, and show better adhesive performance than 3M commercially available double-sided tape. Consequently, isosorbide-based bioelastomers PICBAs are of great potential to be used as environmentally friendly pressure-sensitive adhesives (PSA) in the future.

Adhesion and Cohesion Performance of Polyurethane Made of Bio‐Polyol Derived from Modified Waste Cooking Oil for Exterior Grade Plywood

Adhesion and Cohesion Performance of Polyurethane Made of Bio‐Polyol Derived from Modified Waste Cooking Oil for Exterior Grade Plywood

Bioinspired Nanocomposite Dry Adhesives Applicable Over a Wide Temperature Range

AbstractBioinspired structural adhesives have shown great potential in the field of industrial manipulation and locomotion. However, such adhesives usually perform great adhesion performance at room temperature, reliable adhesion under high‐temperature conditions remains a major challenge and is rarely investigated, which severely limits the applications of current bioinspired adhesives. Here, a bioinspired adhesive structure based on fluororubber (FKM) and nanofillers is proposed. The adhesive structure has a “suction cup‐shaped” tip that mimics the special structural configuration of the adhesive setae of Dytiscus lapponicus, and the ability to regulate the structural modulus by adjusting the content of nanofillers, as well as exhibiting strong and contamination‐free adhesion (>350 kPa) with high adhesive efficiency (up to 77.7) in a wide temperature range (from room temperature to high temperatures (>200 °C)). Moreover, the adhesion performance can be enhanced by precisely regulating the structural modulus, and the enhancement mechanism is demonstrated based on the cohesive zone theory. The proposed adhesion strategy expands the application areas of dry adhesives from room‐ to high‐temperature conditions, especially for the pick‐up and transfer of thin and fragile materials that require high‐temperature operation, opening an avenue for the development of devices and systems based on dry adhesives.

A soft bioinspired suction cup with tunable adhesion force using shape memory alloy

Abstract Suction cups has been widely utilized to grasp objects, but they typically encounter challenges with sealing failure and non-adjustable adhesion force. In this study, a bioinspired suction cup integrated with an shape memory alloy actuated module was proposed to solve these problems. The actuating performance under different input current was firstly investigated to ensure the effectiveness of the module. Then, inspired by the surface structures of the tree frog’s toe pad, the synthetic bioinspired suction cups with hexagonal microstructures at the rims were designed. The regular cup with soft and smooth rim was also fabricated for comparison study. Furthermore, the adhesion performance and surface adaptability of different two cups were studied in both dry and water conditions on substrates with various roughness levels. The results indicated that the proposed active bioinspired suction cup exhibited higher pull-off strength and better sealing on less rough substrates. The proposed bioinspired suction cup possessed the advantages of compactness and lightweight, thus demonstrating potential for integration into arrayed suction grippers.