Additional Source Research Articles

Simultaneous anodic de-lithiation/cathodic lithium-embedded regeneration method for recycling of spent LiFePO4 battery

The widespread use of lithium-ion batteries for energy storage will result in millions of tons of scrapped LiFePO4 (LFP) batteries. Current recycling technologies for LFP cathode materials require harsh acid treatments and are expensive. Hence, in this work, an ingenious electrochemical method is developed to recycle scrapped LFP. Specifically, through the charging/discharging process of an electrolytic system in which both the cathode and anode are scrapped LFP, the anode is de-lithiated to obtain FePO4 (FP), meanwhile, the Li+ from the anode is embedded into the cathode scrapped LFP to achieve regeneration. The experimental results show that the anode de-lithiation rate is 92 % and the cathode regeneration performance is closely related to the driving voltage. A voltage of 1 V converts the FP phase to LFP and effectively eliminates the LFP defect lattice. However, an excessive voltage (1.2 V) leads to an extremely fragile LFP crystal structure, resulting in the ineffective embedment of Li+ into the defective lattice and ineffective capacity restoration. The regenerated LFP exhibits a high restored capacity (136.5 mAh g−1 at 1 C) and excellent stability (95.32 % capacity retention after 300 cycles at 5 C). This novel method does not require an additional Li source, consumes low electrical energy (31.9 kWh t−1) and has a high current efficiency (>98 %), and it yields economic and environmental benefits that will contribute to the sustainable development of the LFP industry.

The effect of additional nitrogen source on iron phthalocyanine-based nanocarbon catalysts for oxygen reduction reaction in acidic media

The focus in the development of catalysts doped with transition metals aims to replace platinum group metal catalysts in fuel cells. However, these non-precious metal catalysts exhibit limited performance in acidic environment for the oxygen reduction reaction (ORR) due to issues such as metal agglomeration and the subsequent loss of active sites. Herein, we synthesised catalysts doped with iron and nitrogen on a composite material consisting of carbide-derived carbon (CDC) and graphene (G), employing an additional nitrogen source dicyandiamide (DCDA), denoted as FeN-CDC/G/DCDA. Our physico-chemical analysis unveiled that the inclusion of DCDA was effective in mitigating metal agglomeration during the synthesis process and increasing the presence of Fe-Nx sites in the catalysts. Notably, the FeN-CDC/G/DCDA catalyst exhibited enhanced ORR activity in acid media with half-wave potential (E1/2) of 0.76 V, surpassing the performance of the FeN-CDC/G catalyst, which had an E1/2 value of 0.70 V. Furthermore, the rotating ring-disk electrode results indicated a reduced formation of hydrogen peroxide when employing the FeN-CDC/G/DCDA catalyst. The findings from this study represent a significant step towards the development of efficient catalysts for fuel cells, underscoring the pivotal role of additional nitrogen doping and its positive impact on the ORR performance.

Contrasting management paradigms for pronghorn in the arid Southwest and their northern range: a review

AbstractPronghorn (Antilocapra americana), a symbol of western North America, experienced diverging population trajectories since the mid‐twentieth century, with northern populations showing signs of recovery while those in the arid Southwest have struggled to persist. We conducted a systematic literature review of papers published through August 2023 to understand 3 questions. What are the habitat conditions needed for pronghorn to persist? What management actions can be taken to foster higher quality habitat? Do these actions differ for populations in the arid Southwest compared to their northern counterparts? Although the fundamental habitat requirements for pronghorn persistence have remained constant since the early 2000s, it has become clear that precipitation is a key factor influencing pronghorn populations in the arid Southwest. The precise mechanisms by which precipitation influences pronghorn population dynamics are not yet clear, whether through the availability of free water, by affecting forage quality, or indirectly via predator‐prey dynamics. Although range‐wide forage enhancement may be impractical, providing additional free water sources could facilitate greater movement, enabling pronghorn to access more and higher quality forage and areas with lower predation risk. To clarify how pronghorn persisted for thousands of years in this harsh environment, we must gain a better understanding of their historical metapopulation and migratory behaviors in the arid Southwest.

Utility of Follicular Unit Excision Using Nonscalp Donor Hair.

Nonscalp donor hair harvesting or body hair transplantation offers patients an additional source of donor hair in cases when the scalp does not have an adequate supply for the intended recipient area. The most common applications for nonscalp donor hair are for patients with advanced hair loss or to camouflage scarring from prior hair restoration procedures. For patients with available body hair, the beard is probably the best source followed by the chest and abdomen. Combined, these sources may be able to provide thousands of additional grafts for transplantation. Nonscalp hair donor harvesting is technically challenging and should be performed by those with extensive experience in follicular unit excision surgical techniques.

Improving building resilience in the face of future climate uncertainty: A comprehensive framework for enhancing building life cycle performance

This research introduces an innovative resilient design framework, addressing gaps in building performance optimization by considering a holistic life cycle perspective and factoring in climate projection uncertainties from the 2020s to 2090s. The study concludes that in the case study, future climate scenarios in different Shared Socio-Economic Paths significantly impact building life cycle performance, with wall U-value, windows U-value, and wall density identified as major factors affecting building performance under future climate uncertainty. The ensemble learning model achieves high fidelity in predicting life cycle carbon emissions (LCCE), life cycle cost (LCC), and indoor discomfort hours (IDH) through input feature screening and hyperparameter optimization. Comparing optimization algorithms, Two-Archive Evolutionary Algorithm for Constrained multi-objective optimization (C-TAEA) demonstrates better convergence degree and optimization effect. Among the tested multi-criteria decision making methods, the VIKOR method selects the best building resilient design scheme from the Pareto data set, effectively reducing LCCE, LCC, and IDH, and leading to an overall improvement in building life cycle performance. Applying this framework, the finalized scheme for an office building in cold region optimizes 44.0% of LCCE, 8.2% of LCC, and 4.3% of IDH. This framework develops a new approach to improve building life cycle performance under future climate uncertainty and supports informed decision-making for resilient building design. To promote carbon neutrality in construction, it is urged that future studies incorporate additional sources of uncertainty, such as occupant behavior, into the proposed framework.

Augmentation of solar still distillation performance using waste heat energy and guiding vanes: A field study

This research proposes a new approach for increasing the productivity of solar still distillation units (SSDUs) while reducing environmental pollution and global warming by exploiting the wasted thermal energies from industrial and domestic applications as an additional heating source for the SSDU. This field study is accomplished by testing two SSDUs simultaneously; the first is a conventional SSDU, and the second is attached with an air duct beneath its base inside which a set of guide vanes is fitted on the lower horizontal side of the duct at several angles (0°–135°). Hot air flows through the duct simulating the waste heat source at several mass fluxes (1.45–6 kg/m2.s). The findings show that the heating airflow raised the temperatures and enhanced freshwater production and system thermal efficiency. The improvements are boosted by increasing the airflow rate and expanding the vane angle up to 120°. After a full day of testing, the modified SSDU achieved maximum productivity of 17.13 L/m2 and thermal efficiency of 34.2 %. Compared to the conventional SSDU, the modified SSDU showed maximum enhancements of 442 % in freshwater productivity and 66.8 % in thermal efficiency, leading to a reduction of the total cost of producing 1 L of freshwater by 70.5 %.

Effect of CNF in-situ growth on microstructure and mechanical properties evolution of RMI-deriver C/C–SiC composites

The present paper investigates the effect of carbon nanofibers (CNFs) on the microstructure and mechanical properties of Carbon fiber reinforced carbon and silicon carbide binary matrix (C/C–SiC) composite prepared by using the reactive melt infiltration technique. The CNFs used in this paper were generated through in-situ reaction in the pores of C/C preforms using the chemical vapor deposition. Results indicate introducing additional carbon sources in the form of CNFs in the C/C preform can remarkably improve the permeability of molten Si, resulting in higher density and more uniform microstructure of the RMI-deriver C/C–SiC composites. Consequently, the in-situ formation of CNFs reduces the residual Si content by 64.71% and increases the mechanical strength and modulus at room temperature by [22.31% and 17.89%] and after heat treatment at 1500 °C by [35.6% and 47.48%] with respect to no-CNF containing composites due to a lower amount of residual Si content and additional reinforcement effect of the unreacted CNFs.

Quantification and Chemical Characterization of Plastic Additives and Small Microplastics (

Road dust is one of the environment's most important microplastic and plastic additive sources. Traffic vehicles and the wear of tires can release these emerging contaminants, which can be resuspended in the air and washed off by stormwater runoff. In this study, a concurrent quantification and chemical characterization of additives, plasticizers, natural and non-plastic synthetic fibers (APFs), and small microplastics (SMPs, <100 µm) in samples of highway road dust (HWRD) was performed. The sampling procedure was optimized, as well as pretreatment (extraction, purification, and filtration) and analysis via micro-FTIR. The average length of the SMPs was 88 µm, while the average width was 50 µm. The highest abundance of SMPs was detected in HWRD 7 (802 ± 39 SMPs/g). Among the polymers characterized and quantified, vinyl ester and polytetrafluoroethylene were predominant. APFs' average particle length was 80 µm and their width was 45 µm, confirming that both of these emerging pollutants are less than 100 µm in size. Their maximum concentration was in RD7, with 1044 ± 45 APFs/g. Lubricants and plasticizers are the two most abundant categories, followed by vulcanizing agents, accelerators, and pre-vulcanizing retarders derived mainly from tires. A potential relationship between APFs and SMPs in the different seasons was observed, as their concentration was lower in summer for both and higher in winter 2022. These results will be significant in investigating the load of these pollutants from highways, which is urgently necessary for more accurate inclusion in emission inventories, receptor modeling, and health protection programs by policymakers, especially in air and water pollution policies, to prevent risks to human health.

An estimation of reservoir pressure dynamics and recoverable gas reserves based on the data of production well surveys

In the development of gas fields, reservoir pressure can be used to estimate gas reserves by means of the material balance methodology and to calculate drained reserves. This provides an indication of the effectiveness of the development system. The authors of the article suggest a methodology for determining drained reserves in wells without reservoir pressure measurements. This approach is useful if the well stock is put into operation concurrently or within a brief period of time. Numerical modelling and analysis of field development data have led the authors to conclude that the current flow rate of wells, the hydrodynamic parameters of the productive formation and the interference of nearby wells are the most significant factors controlling the amount of drained reserves. The use of this technique will improve the understanding of the current processes occurring in the reservoir, clarify the assessment of the energy of the deposit and the value of the initial gas reserves, and also create an additional source of information for timely and more accurate decision-making in field development. Adopting this methodology can improve the understanding of ongoing processes in the reservoir, enhance evaluations of reservoir energy and initial gas reserve sizes, and provide additional information resources for making decisions on field development in a more timely and precise manner.

Is there an association between periodontal disease and root caries? A systematic review and meta-analysis.

Some periodontal diseases can be associated with cariogenic bacterial growth due to various oral health imbalances. This fact may be linked to a greater development of root caries. Thus, this systematic review analyzed the evidence on the association between periodontal disease and root caries. An electronic search was performed in five databases (Cochrane Library, LILACS, MedLine via PubMed, Scopus, and Web of Science) and two additional sources (Google Scholar and Open Grey) to partially capture the grey literature. The PECO strategy was used to identify prospective or retrospective observational studies assessing root caries in patients with periodontal disease without language or year publication restrictions. Two reviewers extracted data and evaluated the individual risk of bias in the eligible studies. Random effects meta-analyses were performed to calculate the Odds Ratio (OR). The risk of bias was assessed by the NIH tool, and the certainty of evidence was classified according to the GRADE tool. There were 1,725 studies retrieved, of which four met the eligibility criteria. All of them were evaluated for the control statements for possible confounders, bias consideration, and confounding factors because they had multivariate analysis. Adults with periodontal disease had a greater chance of presenting root caries than adults without, with OR 1.38 [CI 1.25, 1.53]. The certainty of evidence was classified as very low. Within the limits presented in this review, there was an association between periodontal disease and root caries, highlighted in the qualitative synthesis and the meta-analysis results.

Simultaneous nitrification/denitrification in a single-chamber stainless steel bioelectrochemical reactor

The removal of nitrogen from wastewater with a low C/N ratio often requires additional carbon sources to address the shortage of electron donors, which increases the cost. We explored a simple and energy effecient means for treating wastewater with a high concentration of ammonia nitrogen under anoxic conditions without the addition of carbon sources. We constructed a stainless steel tube as an anaerobic single-chamber microbial electrolysis cell (MEC) for investigating autotrophic simultaneous nitrification/denitrification (SND). Two different structures (carbon brush vs. stainless-steel) were used to construct biocathodes and compared their performances under different voltages (1.8 V, 1.5 V, 1.2 V) applied by DC power. When voltage was applied at 1.5 V, the removal rates of TN and NH4+-N reached 19.68 ± 0.02 mg L−1 d−1 and 21.04 ± 0.17 mg L−1 d−1, respectively. Simultaneously, it achieved maximum TN and NH4+-N removal over 14 days (44.97 ± 0.28 %, 48.16 ± 0.32 %). These rates were 1.8 and 5 times of that obtained with the conventional carbon brush electrode and open-circuit control. Furthermore, microbial community and SEM analysis indicate that species of Thermomonas, Thibacillus and Thauera were the predominant autotrophic electroactive denitrifying bacteria in the reactors. Overall, we achieved a high rate of nitrogen removal, electron utilization and energy recovery in a single-chamber stainless steel MEC.

Photoactive Au@MoS2 Micromotors for Dynamic Surface-Enhanced Raman Spectroscopy Sensing.

Photophoretic Au@MoS2 micromotors are used as smart mobile substrates for dynamic surface-enhanced Raman spectroscopy (SERS) sensing. The photophoretic capabilities and swarming-like propulsion of the micromotors allow for their schooling and accumulation in the measuring spot, increasing the density of SERS-active gold nanoparticles for Raman mapping and, simultaneously, the preconcentration of the target analyte. The generation of "hot-microflake spots" directly in the Raman irradiation point results in a 15-18-fold enhancement in the detection of crystal violet without the requirement for additional external sources for propulsion. Moreover, the reproducible collective micromotor motion does not depend on the exact position of the laser spot concerning individual micromotors, which greatly simplifies the experimental setup, avoiding the requirements of sophisticated equipment. The strategy was further applied for the detection of malachite green and paraquat with a good signal enhancement. The new on-the-move-based SERS strategy holds great promise for on-site detection with portable instrumentation in a myriad of environmental monitoring and clinical applications.

Thermodynamics of deformed AdS-Schwarzschild black hole

By implementing the gravitational decoupling method, we find the deformed AdS-Schwarzschild black hole solution when there is also an additional gravitational source, which obeys the weak energy condition. We also deliberately choose its energy density to be a certain monotonic function consistent with the constraints. In the method, there is a positive parameter that can adjust the strength of the effects of the geometric deformations on the background geometry, which we refer to as a deformation parameter. The condition of having an event horizon limits the value of the deformation parameter to an upper bound. After deriving various thermodynamic quantities as a function of the event horizon radius, we mostly focus on the effects of the deformation parameter on the horizon structure, the thermodynamics of the solution and the temperature of the Hawking–Page phase transition. The results show that with the increase of the deformation parameter: the minimum horizon radius required for a black hole to have local thermodynamic equilibrium and the minimum temperature below which there is no black hole decrease, and the horizon radius of the phase transition and the temperature of the first-order Hawking–Page phase transition increase. Furthermore, when the deformation parameter vanishes, the obtained thermodynamic behavior of the black hole is consistent with that stated in the literature.

Increasing Access to Contraception: Examining Barriers and Facilitators of Long-Acting Reversible Contraception.

Objective(s): To identify barriers and facilitators related to reimbursement processes, device acquisition costs, stocking, and supply of long-acting reversible contraception (LARC) from 27 jurisdictions (26 states/1 territory) participating in the Increasing Access to Contraception Learning Community from 2016 to 2018. Materials and Methods: A descriptive study using qualitative data collected through 27 semistructured key informant interviews was conducted during the final year of the learning community among all jurisdictional teams. Excerpts were extracted and coded by theme, then summarized as barriers or facilitators using implementation science methods. Results: Most jurisdictions (89%) identified barriers to reimbursement processes, device acquisition, stocking, and supply of LARC devices, and 85% of jurisdictions identified facilitators for these domains. Payment methodology challenges and lack of billing and coding processes were identified as the most common barriers to reimbursement processes. Device acquisition cost challenges and lack of delivery facility protocols for billing were the most common barriers to device acquisition, stocking, and supply of LARC. The most common facilitator of reimbursement processes was expanded payment methodology options, whereas supplemental funding for acquisition costs and protocol development were identified as the most common facilitators of device acquisition, stocking, and supply. Conclusion: Revised payment methodologies and broader health systems changes including additional funding sources and protocols for billing, stocking, and supply were used by learning community jurisdictions to address identified barriers. The learning community framework offers a forum for information exchange, peer-to-peer learning, and sharing of best practices to support jurisdictions in addressing identified barriers and facilitators affecting contraception access.

Calcium isotopes track volatile components in the mantle sources of alkaline rocks and associated carbonatites

The volatile components CO2 and H2O induce mantle melting and thus exert major controls on mantle heterogeneity. Primitive intraplate alkaline magmatic rocks are the closest analogues for incipient mantle melts and provide the most direct method to assess such mantle heterogeneity. Given the considerable Ca isotope differences among carbonate, clinopyroxene, garnet, and orthopyroxene in the mantle (up to 1 ‰ for δ44/40Ca), δ44/40Ca of alkaline rocks is a promising tracer of lithological heterogeneity. We present stable Ca isotope data for ca. 1.4 Ga lamproites, 590–555 Ma ultramafic lamprophyres and carbonatites, and 142 Ma nephelinites from Aillik Bay in Labrador, eastern Canada. These primitive alkaline rock suites are the products of three stages of magmatism that accompanied lithospheric thinning and rifting of the North Atlantic craton. The three discrete magmatic events formed by melting of different lithologies in a metasomatized lithospheric mantle column at various depths: (1) MARID-like components (mica-amphibole-rutile-ilmenite-diopside) in the source of the lamproites; (2) phlogopite-carbonate veins were an additional source component for ultramafic lamprophyres during the second event; and (3) wehrlites at shallower depths were an important source component for nephelinites during the final event.The Mesoproterozoic lamproites show lower δ44/40Ca values (0.58 to 0.66 ‰) than MORBs (0.84 ± 0.03 ‰, 2se). This cannot be explained by fractional crystallization or melting of the clinopyroxene-dominated source but can be attributed to a source enriched in the alkali amphibole K-richterite, which has characteristically low δ44/40Ca. The δ44/40Ca values of the ultramafic lamprophyre suite during the second rifting stage are remarkably uniform, with overlapping ranges for primary carbonated silicate melts (aillikite: 0.67 to 0.75 ‰), conjugate carbonatitic liquids (0.71 to 0.82 ‰) and silicate-dominated damtjernite liquid (primary damtjernite: 0.68 to 0.72 ‰). This suggests negligible Ca isotope fractionation during liquid immiscibility of carbonate-bearing magmas. Combined with previously reported δ44/40Ca values for carbonatites and kimberlites, our data suggest that carbonated silicate melts in Earth's mantle have δ44/40Ca compositions resolvably lower than those for MORBs (0.74 ± 0.02 ‰ versus 0.84 ± 0.03 ‰, 2se). The δ44/40Ca values of the Cretaceous nephelinites (0.72 to 0.78 ‰) are homogenous and similar to those of the 590–555 Ma ultramafic lamprophyres, suggesting that the wehrlitic source component for the nephelinites formed by mantle metasomatism during interaction with rising aillikite magmas during the second rifting stage. Our results highlight that both K-richterite and carbonate components in mantle sources can result in the systematically low δ44/40Ca values of alkaline magmas, which may explain previously reported low δ44/40Ca values of alkaline rocks and some carbonatites. Our study indicates that Ca isotopes are a robust tracer of lithological variation caused by volatiles in the Earth's upper mantle.

Retaliation

An overview of the key topics faced by disability services providers with citations to noteworthy cases, statutes, regulations, and additional sources.

Among the trees: shade promotes the growth and higher survival of juvenile toads

getation, including trees, significantly shapes microhabitats for amphibians due to the leaf litter input, providing stable shelter, creating a microclimate or indirectly through trophic interactions. It is known that some species can survive in a highly modified urban environment. Species associated with open space can find stable habitats in urban and human-transformed areas, but is the impact of shading (presence of canopy cover) significant in their case? We focus on the effect of solar exposure on the growth rate of juvenile green toads Bufotes viridis in fruit and canopy manipulation treatments. The main aim of the study was to examine the selected habitat traits promoting post-metamorphic growth of the green toad in semi-open enclosures. We investigated differences between exposure/land cover variants, i.e., sunny site (open area with direct solar exposure) and shadow site (shady site with a tree canopy cover). Using imitation fruits and real cherry plum Prunus cerasifera fruits (non-native tree species), we checked wheth­er amphibian growth is related to the additional structure that fruit lying on the ground created (a more heterogeneous surface structure) or to a trophic character (additional food source due to attracting inver­tebrates). We conducted a 40-day rearing experiment in three variants with two replications in semi-open enclosures with 20 juvenile toads each. We found differences in snout-vent length and body mass index in­vestigated due to site exposure during post-metamorphic growth. The survival rate of juvenile toads in the shaded site was higher than in sunny sites. We demonstrated a positive effect of the tree’s shade, regardless of the fleshy fruit’s presence on the ground. Toads benefit from developing at sites with reduced solar ex­posure (i.e., with a tree canopy), resulting in intensive growth and higher survival rate. Thus, there is an opportunity for planners and urban authorities to manage habitats for amphibian conservation purposes by creating a shaded zone, even for open habitat species, especially in transformed areas such as cities. Our results indicate that the beneficial effect of the lying fruit on the growth of juveniles is limited to specific conditions, and understanding this requires further research.

To be a freshman during the COVID-19 pandemic: A cross-lagged model of depression, mentalizing, and epistemic trust.

Research has shown that severity of depression increased in freshmen during their first months at university due to increased social and academic pressures. Since the start of the COVID-19 pandemic, several cross-sectional studies have suggested that levels of depression in university students are higher than before the pandemic, but longitudinal data are largely lacking. This study investigated severity of depression and negative affect linked to the pandemic among freshmen during their first semester at a large university in Flanders, Belgium. We also investigated whether epistemic trust predicted severity of depression and pandemic-related negative affect and whether problems with reflective functioning (or mentalizing) mediated these relations. Participants in this two-wave prospective study were 289 first-year students of the Faculty of Psychology and Educational Sciences of a large Belgian university. We conducted paired samples t-tests and cross-panel analysis to answer the research question. The number of students at risk of clinical depression increased by 41% between T1 (early October 2020) and T2 (late December 2020). Epistemic mistrust at T1 was prospectively associated with an increase in the prevalence and severity of depression at T2. Problems with mentalizing and negative COVID-19-related affect were positively associated with severity of depression at T2 and mediated the association between epistemic mistrust and severity of depression at T2. The findings highlight the key role of epistemic trust in the development of depression among freshmen, with the COVID-19 pandemic presenting an additional source of uncertainty.

Effects of wetland connectivity on overwintering and movement behaviours of Australian freshwater turtles

AbstractFreshwater turtles are important consumers in Australian freshwater ecosystems. They serve as scavengers, nutrient regulators, and as food sources and Totems for Traditional Owners throughout Australia. Despite their importance, most Australian freshwater turtle species are declining. The impact of winter wetland drying on turtle populations remains unknown, and winter exposure of hibernating turtles may be an important additional source of mortality. We aimed to examine turtle responses to seasonal and episodic wetland drying in wetlands using acoustic telemetry and active trapping. Wetlands were chosen that spanned a range of hydrological connectivity to the adjacent Edward/Kolety‐Wakool River. We found that tagged Emydura macquarii typically exit wetlands disconnected from the adjacent permanent river prior to winter, and overwinter in the river. Female E. macquarii rapidly re‐entered ‘home’ wetlands (wetlands in which they were initially tagged) the following spring, whereas males tended to leave the study area, returning occasionally. Although we were not able to evaluate a winter drying event, one of the wetlands experienced partial summer drying. All three local turtle species (E. macquarii, Chelodina expansa, C. longicollis) exited the wetland long before winter drying would have become a potential threat. Our results suggest that turtles in this system may be protected from winter wetland drying because they move to the adjacent permanent river prior to winter. Spending the winter in the river channel reduces the risks of being trapped in a drying wetland as temperatures drop in winter.

Review recent rulings involving failure to accommodate

An overview of the key topics faced by higher education administrators with citations to noteworthy cases, statutes, regulations, and additional sources.