The Fourier transform (FT) operating mode of a quadrupole ion trap leads to an axial secular frequency spectrum of the simultaneously confined ions. During confinement, an ion trajectory as pure as possible is sought. The addition of a pure frequency in a quadrupolar configuration to the confinement voltage is examined in detail. Simulation and experimental results concerning an axial-trajectory spectrum are presented. With an additional quadrupolar perturbation, the ion motion is frequency modulated and, as a result, a peak splitting of the axial ion motion is observed. The frequency modulation induces sideband frequency peaks with amplitudes that are higher for low frequencies of the perturbation. Since ion detection is destructive, a repetition of elementary experiments realized for increasing confinement times is needed. Therefore, for each confinement time, the initial phase of the perturbation can be different. As a result, an additional ion-motion phase modulation, which depends on the repetition mode and the duration of the elementary experiments, is induced. With a constant duration of the elementary experiments, phase modulation is made at discrete frequencies. This induces a new high frequency peak splitting. When the duration is equal to the period of the perturbation, solely the frequency modulation effect is visible. When the elementary experiments follow one another (with no lag time), the ion motion is phase modulated at a quasi-infinite range of frequencies. The result is a decreasing of the modulation index due to the frequency modulation and a background noise in the whole spectrum. For βz ≈ 0.798, a duration of the elementary experiment of 80 ms and a perturbation with an amplitude and a frequency of 10 mV and 50 Hz, respectively, the limit of the mass resolution is about 3800 for m/Z = 127 u. When the elementary experiments follow one another, the mass resolution limit is higher than 5600 but the signal-to-noise ratio is halved.
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