Addition Of Iron Oxide Research Articles

Designed magnetic nanoparticles for ferroptosis: Release of iron ions from metal-organic frameworks modified with iron oxides

The unique chemical properties of the catalytic and biocompatible metal organic framework MIL88b allow for considering it as prooxidant agent. The authors hypothesize whether additional modification of the MIL88b with an additional iron source as Fe3O4 nanoparticles can increase both pro-oxidant activity and provide magnetic properties contributing to target delivery. The prooxidant activity of the Fe3O4-MOF was studied using electron paramagnetic resonance spectroscopy and methylene blue degradation reactions in the presence of hydrogen peroxide. To understand the reaction mechanism, the authors studied the released iron ions, as well as the surface composition using the X-ray photoelectron spectroscopy method. The addition of iron oxide leads to a more prolonged release of iron ions and the production of hydroxyl radicals within 24 h. The native MIL88b demonstrates the highest Fenton reaction rate due to "sacrificial" behavior (despite lower concentration of iron ions in the composition and on the surface compared to the modified sample) and the blocking of the active centers of MIL88b by Fe3O4 on the surface.

Enhanced anaerobic digestion of food waste by the addition of cobalt iron oxide

In this study, the impact of cobalt iron oxide(CoFe2O4) on the anaerobic digestion (AD) of food waste (FW) was investigated including the variations in pH, VFAs, ORP, Fe2+/Fe3+ concentrations, SCOD, dehydrogenase activity, methane production and microbial community structure. The results showed that CoFe2O4 had a positive effect on the anaerobic digestion of food waste. CoFe2O4 could promote the release of SCOD, increase the dehydrogenase concentration and reduce ORP resulting in an increase of methane production. At a CoFe2O4 concentration of 200 mg/L, the cumulative methane production reached to 414.75 mL/(gVS) which was increased by 79.1% compared to the control group(231.59 mL/(gVS)). Meanwhile, the variation of microbial community showed that CoFe2O4 could increase the relative abundance of Methanobacterium and the methane production pathway in the AD was shifted from acetoclastic to hydrogenotrophic.

Optimization of Iron Oxide (Fe2O3) Addition Parameters on the Physical Properties of Al-Si Alloys as an Advanced Material Innovation

Aluminum-silicon alloys are widely used in the industrial world, one of which is because they have high wear resistance. The aim of this research is to determine the physical and mechanical properties of the Al-Si alloy after strengthening by mixing reinforcing materials. The research method uses Taguchi optimization and analysis of the physical properties of the Al-Si alloy test results. The results showed that the highest hardness value was obtained in the 7th experiment, namely with a rotation variation of 2000 rpm, temperature of 6000C, and holding time of 60 seconds. This result is in line with the results of the tensile strength test, where the highest tensile strength was also obtained in the 7th experiment. This result is supported by the results of other researchers, which show that the higher the rotation in the casting results in higher hardness. The results of the microphotographs show that all alloy materials have an even distribution of grains, the grain size appears small, and the dendrites in the raw Al-Si alloy appear small compared to other materials. The macro photo results show that all alloy materials have fractures that appear brittle, as evidenced by the fact that these fractures provide light reflection.

Effects of soot and plastic fibers on the performance of SCC

Self-compacting concrete is regarded as one of the newest types of concrete due to its durability, efficiency, viscosity, stability, flowability, and resistance. Today, one of the most pressing environmental challenges is the disposal of solid waste, and one of the plastic materials discarded as waste after use is plastic packaging belts. These are made on the basis of polypropylene, as well as the factory Iron smelting mines are the main source of iron oxide waste production. Studies using recycled plastic fibers (30 mm × 0.3 mm) and waste iron oxide as cost-effective additives in self-compacting concrete (SCC) are presented. The effects on fresh and hardened properties were evaluated at various additive contents. Fresh and hardened properties of self-compacting concrete (SCC) were evaluated with and without fiber and iron oxide additives. Tests included workability (slump flow, funnel), strength (compressive, tensile), and durability (ultrasonic pulse speed, permeability). Experiments revealed that increasing the amount of recycled plastic fibers and waste iron oxide in self-compacting concrete (SCC) led to higher compressive and tensile strengths at both 7 and 28 days. These strength increases ranged from 2 to 9.68 MPa for compressive strength and 1.61–7.44 MPa for tensile strength, compared to the control specimen without additives.

Impact of additives on syntrophic propionate and acetate enrichments under high-ammonia conditions

High ammonia concentrations in anaerobic degradation systems cause volatile fatty acid accumulation and reduced methane yield, which often derive from restricted activity of syntrophic acid-oxidising bacteria and hydrogenotrophic methanogens. Inclusion of additives that facilitate the electron transfer or increase cell proximity of syntrophic species by flocculation can be a suitable strategy to counteract these problems, but its actual impact on syntrophic interactions has yet to be determined. In this study, microbial cultivation and molecular and microscopic analysis were performed to evaluate the impact of conductive (graphene, iron oxide) and non-conductive (zeolite) additives on the degradation rate of acetate and propionate to methane by highly enriched ammonia-tolerant syntrophic cultures derived from a biogas process. All additives had a low impact on the lag phase but resulted in a higher rate of acetate (except graphene) and propionate degradation. The syntrophic bacteria ‘Candidatus Syntrophopropionicum ammoniitolerans’, Syntrophaceticus schinkii and a novel hydrogenotrophic methanogen were found in higher relative abundance and higher gene copy numbers in flocculating communities than in planktonic communities in the cultures, indicating benefits to syntrophs of living in close proximity to their cooperating partner. Microscopy and element analysis showed precipitation of phosphates and biofilm formation in all batches except on the graphene batches, possibly enhancing the rate of acetate and propionate degradation. Overall, the concordance of responses observed in both acetate- and propionate-fed cultures highlight the suitability of the addition of iron oxide or zeolites to enhance acid conversion to methane in high-ammonia biogas processes.Key points• All additives promoted acetate (except graphene) and propionate degradation.• A preference for floc formation by ammonia-tolerant syntrophs was revealed.• Microbes colonised the surfaces of iron oxide and zeolite, but not graphene.Graphical

Impact of Iron Oxide on Anaerobic Digestion of Frass in Biogas and Methanogenic Archaeal Communities' Analysis.

With the increasing prominence of the global energy problem, socioeconomic activities have been seriously affected. Biofuels, as a renewable source of energy, are of great significance in promoting sustainable development. In this study, batch anaerobic digestion (AD) of frass (swine manure after bioconversion by black soldier fly larvae) and co-digestion with corn straw after the addition of iron oxide (Fe3O4) nanoparticles is investigated, as well as the start-up period without inoculation. The biochemical methane potential of pure frass was obtained using blank 1 group and after the addition of various sizes of Fe3O4 nanoparticles for 30 days period, and similarly, the digestion of frass with straw (blank 2) and after the addition of various sizes of Fe3O4 nanoparticles for 61 days period. The results showed that the average gas production was 209.43 mL/gVS, 197.68 mL/gVS, 151.85 mL/gVS, and 238.15 mL/gVS for the blank, ~176 nm, ~164 nm, and ~184 nm, respectively. The average gas production of frass with straw (blank 2) was 261.64 mL/gVS, 259.62 mL/gVS, 241.51 mL/gVS, and 285.98 mL/gVS for blank 2, ~176 nm, ~164 nm, and ~184 nm, respectively. Meanwhile, the accumulated methane production of the ~184 nm group was 2312.98 mL and 10,952.96 mL, respectively, which significantly increased the biogas production compared to the other groups. The methanogenic results of the frass (30 days) indicated that Methanocorpusculum, Methanosarcina, and Methanomassiliicoccus are the important methanogenic species in the AD reactor, while the microbial diversity of the ~184 nm group was optimal, which may be the reason for the high gas production of ~184 nm.

Iron borophosphate glasses: Merging optical transparency, structural integrity, and radiation shielding efficacy for sustainable uses

The research work explored the influence of iron doping on the optical behavior, structural characteristics, and radiation shielding capabilities of soda lime borophosphate glass system of composition xFe2O3-(42.5-x)B2O3-26CaO-28.7Na2O-2.8P2O5 (x up to 8 mol%). The glass samples doped with varying iron concentrations were synthesized via the conventional melt-quenching method. A comprehensive characterization approach was employed, integrating X-ray diffraction (XRD) analysis to probe the structural aspects, Fourier transform infrared (FTIR) spectroscopy to examine the molecular vibrations and bonding, and UV–visible spectroscopic techniques to investigate the optical properties. Furthermore, the study evaluated the potential of these iron-doped glasses as effective radiation shielding materials by assessing their attenuation performance against various radiation types. The influence of iron oxide (Fe2O3) addition on the borophosphate network, coordination environment, and optical absorption was examined. The radiation shielding characteristics, such as mass attenuation coefficient, half-value layer, mean free path, and other parameters, were assessed using Phy-x freeware program calculations. The results revealed the formation of an amorphous glass structure and the incorporation of iron ions into the borophosphate network. The addition of Fe2O3 influenced the borate superstructural units, the conversion of BO3 to BO4 units, and the optical absorption bands. The glasses exhibited promising radiation shielding properties combined with increasing Fe2O3 content.

Iron Oxide-Activated Carbon Composites for Enhanced Microwave-Assisted Pyrolysis of Hardwood

A commercial activated carbon (AC) was modified through iron oxide incorporation to obtain microwave absorbers (MWAs) for microwave-assisted pyrolysis. The influence of iron oxide content (5 and 20 wt% Fe3O4) and the modification methods were tested as follows: (1) in situ co-precipitation + washing step with Milli-Q; (2) in situ co-precipitation + washing step with Milli-Q/ethanol; and (3) physical iron oxide blending. The resulting MWAs were evaluated on the microwave-assisted pyrolysis of hardwood in a Milestone Flexiwave microwave reactor. The biochar yield varied from 24 wt% to 89 wt% and was influenced by the modification method rather than the iron oxide addition. The MWAs with physically blended iron oxide resulted in biochar yields comparable to conventional biochar (450 °C). Furthermore, the addition of iron oxide-activated carbon composites during the microwave-assisted pyrolysis caused a significant decrease in the biochar’s 16 EPA polycyclic aromatic hydrocarbons, mainly by reducing the amount of pyrene in the biochar.

Small concentrations, big results: μM addition of photoactive iron oxides with PMS, PDS, or H2O2, leads to enhanced removal of viruses at near-neutral pH

The photo-Fenton process is effective for pathogen removal, and its low-cost versions can be applied in resource-poor contexts. Herein, a photo-Fenton-like system was proposed using low concentrations of iron oxides (hematite and magnetite) and persulfates (peroxymonosulfate – PMS, and peroxydisulfate - PDS), which exhibited excellent inactivation performance towards MS2 bacteriophages. In the presence of bacteria, MS2 inactivation was inhibited in H2O2 and PDS systems but promoted in PMS-involved systems. The inactivation efficacy of all the proposed systems for mixed bacteria and viruses was greater than that of the sole bacteria, showing potential practical applications. The inactivation performance of humic acid-incorporated iron oxides mediating photo-Fenton-like processes was also studied; except for the PMS-involved system, the inactivation efficacy of the H2O2- and PDS-involved systems was inhibited, but the PDS-involved system was still acceptable (< 2 h). Reactive species exploration experiments indicated that ·OH was the main radical in the H2O2 and PDS systems, whereas 1O2 played a key role in the PMS-involved system. In summary, hematite- and magnetite-mediated persulfate-assisted photo-Fenton-like systems at low concentrations can be used as alternatives to the photo-Fenton process for virus inactivation in sunny areas, providing more possibilities for point-of-use drinking water treatment in developing countries.

Investigation of nanoparticle (Fe3O4) addition to 3rd generation biodiesel (spirulina microalgae)/diesel mixture as an innovative fuel according to different engine variables: An RSM optimization

In order to reduce dangerous air pollution and lessen the hazards associated with climate change, biofuels made from vegetable biomass can be utilized as fuel in diesel engines. However, feedstocks and the crop space needed for their cultivation are unavoidable barriers that hinder its adoption and result in a shortage of farmland for increasing food profits. Nevertheless, microalgae are the most reliable and competent biodiesel supply because they are not edible and do not require cropland. Additionally, the addition of nanoparticles has become popular to improve the negative aspects of biodiesel. Based on these, in this study, multi-purpose optimization research was conducted on the addition of iron oxide (Fe3O4) nanoparticles in three different amounts (25, 50, and 75 ppm) to 20 % synthesized spirulina microalgae biodiesel (SSMB)/80 % diesel mixtures. Tests were conducted at three different compression ratios (14.5:1, 15.5:1, and 16.5:1) (CoR) and four different engine loads (25 %, 50 %, 75 %, and 100 %). The response surface methodology (RSM) optimization process was performed with the test results. According to RSM, a desirability coefficient of 0.8299, 15.80:1 CoR, 68 ppm AoN, and 45 % LoE were the ideal conditions. The optimum responses under these circumstances were 421.9653 g/kWh, 19.4014 %, 0.0939 %, 4.0785 %, 73.1716 ppm and 253.0620 ppm for brake-specific fuel consumption (BSFC), brake-thermal efficiency (BTHE), carbon monoxide (CO), carbon dioxide (CO2), hydrocarbon (HC), and nitrogen oxide (NOx), respectively. RSM could be used successfully because the error rates (maximum 6.5 %) when comparing the test results with the RSM optimization outcomes were within reasonable bounds.

Magnetic membranes based on PVA-SPION for hyperthermia and dielectric applications

Magnetodielectric membranes were spun by electrospinning ferrofluids containing Superparamagnetic Iron Oxide (SPION) in a carrier liquid of Polyvinyl alcohol(PVA) for various loadings of iron oxide. These membranes were characterised using X-ray diffractometer (XRD), Field Emission Scanning Electron Microscopy (FESEM),Vibrational Sample Magnetometry (VSM),Fourier Transform Infrared Spectroscopy (FTIR) and UV–visible spectroscopy (UV–vis) and found to be of good quality having adequate magnetic and dielectric properties. The iron oxide particles were found to be ∼9 nm in size and superparamagnetic in nature. The addition of iron oxide led to a systematic increase in both magnetic and dielectric properties. A maximum saturation magnetization of ∼6.3 emu g−1 and a dielectric constant of ∼50 was obtained for a loading of 40 percentage of Iron oxide. A dielectric transducer was fabricated using the membranes. These membranes also exhibited magnetic hyperthermia as evidenced by magnetic hyperthermia measurements. They are found to be potential candidates for hyperthermia applications as wearables. The method of employing a ferrofluid can be adopted for spinning membranes based on other than PVA/SPION. If the loading is optimised these membranes can be employed as Magnetodielectric transducers.

Investigation of Mechanical, Thermal Properties of Camel wool Fiber and Chopped E-Glass Fiber Reinforced Epoxy Resin with and without Addition of Iron Oxide

Composites are an excellent alternative to metal alloys due to their high strength-to-weight ratio. It's awesome that researchers are working on biodegradable and recyclable fiber-reinforced composites. Each natural and synthetic fiber has advantages and disadvantages, but combining different fibers alters the properties of composite materials. In this project, we used camel wool fiber and chopped E-glass to make a hybrid composite with epoxy as the matrix. Combining different fibers in composite materials, it is possible to alter their properties and create materials with specific characteristics. Additionally, adding fillers to composites can further enhance their characteristics, such as improving strength, stiffness, and other mechanical and thermal properties. We also experimented with different amounts of iron oxide which resulted in these semi-biodegradable materials. The mechanical and thermal characteristics of these composites improved as the iron oxide powder content rose. The best part is that using iron oxide as a filler material can help reduce material costs. Key Words: Chopped E glass (CEG), Camel wool Fiber (CWF), Filler, Differential thermal analysis (DTA), Thermogravimetric analysis (TGA), Derivative thermogravimetry (DTG).

Shielding parameters and optical stability of sodium alumino-borate glasses against gamma rays by iron oxide additives

The development of various industries and technologies necessitates a greater utilization of ionizing radiation, such as gamma rays. Herein, we investigate the shielding parameters and the stability of the optical parameters of sodium alumino-borate glasses against gamma rays by different iron oxide (Fe2O3) additives. We found that the Fe2O3 additives improved the shielding parameters. Moreover, the influence of various doses of γ rays (50, 100, and 150 kGy) on the optical characteristics of the performed glasses was studied. For example, the influence of gamma doses on the optical absorbance (A), optical band gap (Eg), Urbach energy (EU), refractive index (no), electronegativity (X), electron polarizability (αo), and nonlinear refractive index (n2). The optical absorbance of all glass samples increased, particularly in the visible range, with further irradiation.Furthermore, the reduced optical band gap and Urbach energy values grow as the gamma irradiation increases, which are attributed to the increased number of donor centres. Conversely, an investigation was conducted on the ability of the material to protect against radiation. We found that the Fe2O3 additives improved the shielding parameters. Furthermore, the half-value layer results of the glassy samples in question were compared to those of conventional radiation shielding materials and glasses. Therefore, the glass samples work better at blocking radiation than conventional window glass when employed for radiation shielding purposes.

Wetland soil organic carbon balance is reversed by old carbon and iron oxide additions.

Iron (Fe) oxides can stabilize organic carbon (OC) through adsorption and co-precipitation, while microbial Fe reduction can disrupt Fe-bound OC (Fe-OC) and further increase OC mineralization. The net effects of OC preservation and mineralization mediated by Fe oxides are still unclear, especially for old carbon (formed from plant litters over millions of years) and crystalline Fe oxides. Accelerating the recovery of wetland carbon sinks is critical for mitigating climate change and achieving carbon neutrality. Quantifying the net effect of Fe-mediated OC mineralization and preservation is vital for understanding the role of crystalline Fe oxides in carbon cycling and promoting the recovery of soil carbon sinks. Here, we explored the OC balances mediated by hematite (Hem) and lignite addition (Lig) to freshwater wetland (FW, rich in C and Fe) and saline-alkaline wetland (SW, poor in C and Fe) soil slurries, incubated under anaerobic conditions. Results showed that Lig caused net OC accumulation (FW: 5.9 ± 3.6 mg g-1; SW: 8.3 ± 3.2 mg g-1), while Hem caused dramatic OC loss, particularly in the FW soils. Hem inhibited microbial Fe(III) reduction by decreasing the relative abundance of Fe respiration reducers, while substantially enhancing OC mineralization through the shift in the microbial community structure of FW soils. Lig resulted in carbon emission, but its contribution to preservation by the formation of Fe-OC was far higher than that which caused OC loss. We concluded that crystalline Fe oxide addition solely favored the increase of OC mineralization by adjusting the microbial community structure, while old carbon enriched with an aromatic and alkyl promoted Fe-OC formation and further increased OC persistence. Our findings could be employed for wetland restoration, particularly for the recovery of soil carbon sinks.

Linear/nonlinear opto-gamma radiation attenuation hallmarks of high-density lead barium-borate glass blocks containing iron oxide additives

Linear/nonlinear opto-gamma radiation attenuation hallmarks of high-density lead barium-borate glass blocks containing iron oxide additives

MAGNESIUM AND IRON OXIDES INFLUENCE ON SINTERING PROCESSES AND PHASE FORMATION OF ANORTHITE CERAMICS BASED ON NATURAL RAW MATERIALS

Ceramic proppants based on silicates and aluminosilicates with various structures are used in the hydrocarbons mining with hydraulic fracturing method. The disadvantage of these known proppants is their high apparent density. Anorthite CaO∙Al2O3∙2SiO2 is a prospective material for proppants production. However, its wide application in this field is restricted due to insufficient knowledge of the MgO-CaO-Fe2O3(FeO)-Al2O3-SiO2 system. Consequently, the physical and chemical processes in the mixes of kaolin and chalk with magnesium oxide and iron(III) oxide additives during firing for anorthite ceramics were studied. It was found that adding of 5 – 10% magnesium oxide in batch for anorthite synthesis leads to obtain ceramics with near-zero water absorption at 1250 °C. Increasing the firing temperature to 1300 °C leads to overfiring of the ceramic and a decrease in its strength. Magnesium oxide reacts with the kaolin to form spinel and forsterite. The highest compressive strength (350 – 390 MPa) is achieved for ceramics with 5% MgO in the batch. The ceramics has fine-grained structure with the grain sizes less than 5 μm. Iron(III) oxide is a weak mineralizer for anorthite synthesis, and its mineralizing effect occurs during the formation of gehlenite-based solid solutions. The sintering process of anorthite ceramics is intensified at 1350 °C due to the melting of the anorthite – iron(III) oxide eutectic. This leads to decrease the water absorption of ceramics with 5 – 10% Fe2O3 in batch to about 2 – 3%. The compressive strength of this ceramics is about 230 – 250 MPa.

Effect of iron oxide on combustion and thermal decomposition of AN/MgAl-based pyrotechnic mixtures

Ammonium nitrate (AN) is widely used as an oxidizer in energetic-burning mixtures. However, poor ignition and low burning rate require special additives to speed up this process. MgAl alloy is used as a fuel to improve the burning characteristics of AN. Mg-50%Al Alloy was synthesized by a high-temperature diff usion bonding method. In addition, the eff ect of iron oxide on the burning characteristics of pyrotechnic mixtures was studied. The burning characteristics of pyrotechnic mixtures were determined by ignition in a high-pressure chamber. With the addition of iron oxide, the burning rate of pyrotechnic compounds increased up to two times. Also, the pressure defl agration limit of the pyrotechnic mixture was reduced from 2 MPa to 1 MPa. In addition, the thermal characteristics of pyrotechnic mixtures were studied, and activation energies were calculated.

Enhanced food waste anaerobic digestion by simultaneously controlling sludge loads and iron oxide addition

The influence of the combination of sludge load control and iron oxide (IO) addition strategies on food waste anaerobic digestion (AD) was explored. The results showed that low sludge loads or IO addition could significantly enhance AD performance. Low sludge loads promoted substrate hydrolysis and volatile fatty acids degradation, which enhanced the biochemical methane potential (BMP) and production rate, respectively. IO addition promoted the CH4 yield and maximum CH4 production rate (Rm) by 65.50% and 206.79%, respectively, by promoting hydrolysis and interspecies electron transfer among syntrophic microbes. Moreover, although the presence of IO could prevent the failure of AD in extremely high sludge load conditions, it could not ensure complete BMP recovery. In an IO-assisted reactor, low sludge loads decreased the methanogenic lag phase by 53.15% and increased the BMP and Rm by 49.93% and 120.11%, respectively. Although adequate IO dosage could effectively improve the digester performance, excessive dosage may limit the economic benefits. Overall, the AD performance could be optimized by simultaneously controlling the sludge load and IO addition.

Influence of solar radiation and an electric force on nanofluid convection inside a porous sector cavity

Using novel numerical techniques, this paper estimates the effect of EHD force on ferrofluid treatment. Iron oxide additives of various nanoscale forms and dimensions are added to the operating fluid. Because the percentage of nanoparticles exceeds 0.06 and the slip velocity is disregarded, the features of the carrier fluid were modified using an empirical model. The left and bottom surfaces of the moving walls had the highest temperatures and voltages. A non-Darcy presumption was that the region was permeable. A combined FVM and FEM method was utilized to solve this issue. Due to the application of an electric force, the nanofluid is able to move more quickly, and two primary vortices combine to form a single, stronger vortex. As voltage increases, Nu increases by approximately 125.52%. Utilizing greater permeable medium results in a stronger wall collision and a 113.29% increase in Nu. Nu increases by approximately 3.69% when a nanoparticle with a greater shape factor than the sphere is utilized.

Comparison of magnetite, hematite and goethite amendment and capping in control of phosphorus release from sediment.

The characteristics and mechanism of phosphate adsorption onto magnetite, hematite and goethite were comparatively studied, and the effects of magnetite, hematite and goethite amendment and capping on endogenous phosphorus (P) liberation from sediment into overlying water (OW) were comparatively investigated. The adsorption of phosphate onto magnetite, hematite and goethite mainly obeyed the inner-sphere complexation mechanism, and the phosphate adsorption capacity decreased in the order of magnetite > goethite > hematite. The magnetite, hematite and goethite amendment all can decrease the risk of endogenous Prelease into OW under anoxic conditions, and the inactivation of diffusion gradients in thin films-labile P in sediment made a great contribution to the restraint of endogenous P release into OW by the magnetite, hematite and goethite amendment. The efficiency of endogenous P release restraint by the iron oxide addition decreased in the order of magnetite > goethite > hematite. The magnetite, hematite and goethite capping all can be effective for the suppression of endogenous P release from sediment into OW under anoxic conditions, and most of P immobilized by the magnetite, hematite and goethite capping layers is relatively or very stable. The results obtained from this work suggest that magnetite is more suitably used a capping/amendment material to prevent P release from sediment than hematite and goethite, and magnetite capping is a promising approach for hindering sedimentary P release into OW.