The phase diagram AgI-PbI 2 was investigated by X-ray and difference thermoanalytical methods. Two high-temperature compounds, one based on Ag 3PbI 5 the other on AgPb 4I 9, were observed. The temperature of transformation of PbI 2 into the high-temperature 12R-PbI 2 modification is decreased by the addition of AgI.
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