AbstractRunge–Kutta algorithms with adaptive step size control provide reliable tools for the solution of initial value problems with diagonally implicit Runge‐Kutta (DIRK) methods as the most common approach. In this contribution, the new low‐order explicit last‐stage diagonally implicit Runge–Kutta (ELDIRK) methods are investigated, combining implicit schemes with an additional explicit evaluation as an explicit last stage. This results in Butcher tableaus with two solutions of different convergence orders suitable for embedded methods, where the higher‐order solution is achieved by additional explicit evaluations. Thus, the iterative solution of non‐linear systems is omitted for the additional stage, presenting a major reduction in computational cost for the determination of a local error estimate. The key contribution is the application of the novel Butcher tableaux to phase‐field problems, solved with the finite‐element method, leading to substantial numerical investigations with an efficient approach for DIRK schemes. The most important aspects are the investigations of stability properties which lead to the novel class of A‐stable ELDIRK methods. In accordance, the study of the convergence orders is presented. A local error estimator is presented, such that adaptive step size control for the new low‐order embedded schemes based on an empirical approach for error estimation is achieved. A suitable parallel algorithm is presented with conclusive two‐dimensional phase‐field simulations based on a Kobayashi‐Warren‐Carter model. The higher‐order convergence suggested by the novel schemes is confirmed, and their effective results are demonstrated, resulting in a valuable semi‐explicit addition to the family of Runge–Kutta time integration schemes.