With the development of the Internet age, the gradual deepening of reforms, and the continuous improvement of marketization, the financial ecological environment is directly related to the risk of financial institutions’ loans and the enthusiasm to support local economic development. Capital is accompanied by the physical development and evolution of the production and circulation of goods. After thousands of years of historical development and evolution, it has formulated its own development law and internal logic. In view of the unclear environmental and social evaluation indicators in supply chain research and the model’s failure to accurately describe the real supply chain network, an adaptive dynamic relaxation approximation algorithm model is proposed. This model introduces upstream and downstream transit stations as distributors and as a hub between customers, the transportation mode is improved to horizontal and vertical coordinated transportation, and multiple transportation methods are used for transportation. In this paper, the experimental group adopts a new model based on the approximate algorithm of dynamic relaxation factors, and the control group adopts the original old model. The two groups conduct comprehensive data analysis on social indicators, self-indicators, initial indicators, economic indicators, and environmental indicators in each year. Starting from the dimension, comprehensively consider the selection of indicators to measure the level of enterprise performance. The experiment proves that the transportation loss in the green supply chain is between the new model and the old model. When the number of partners is small, the degree of the optimal solution between the new and old models is not obvious, and the degree of optimization of the new model relative to the old model is increasing. It has a significant statistical difference ( P < 0.05 ). This shows that efforts to build a good financial ecological environment and an honest and reliable and healthy economic ecological environment are of great importance for promoting the continuous and rapid growth of the social economy.