Activity For Combustion Research Articles

Compilation of a city-scale black carbon emission inventory: Challenges in developing countries based on a case study in Brazil

Black carbon (BC) inventories for cities are scarce, especially in developing countries, despite their importance to tackle climate change and local air pollution. Here, we draw on results from a case study in a Brazilian city to discuss the challenges of compiling a BC inventory for different activity sectors. We included traditionally inventoried sectors, such as industries and on-road transportation, other less reported sectors (food establishments and aviation), and open burning of household solid waste (HSW), typically found in developing countries. We present a machine-learning technique (Random Forest) as a novel approach to obtain HSW burning activity using a set of spatial predictors. The BC inventory was based on PM2.5 emissions weighted by the fraction of PM2.5 emitted as BC and developed for the year 2018. We also reported the disaggregated spatial PM2.5 emissions for the same combustion sources, and documented the databases used for activity data and emission factors (EF). The total estimated BC and PM2.5 emissions amounted to 57.88 and 234.75 tons, respectively, with on-road vehicle exhaust emissions and industrial combustion as the main BC sources (63 and 22%, respectively). For PM2.5 emissions, on-road transportation (exhaust and non-exhaust) contributed 48%, followed by industrial combustion (21%) and food establishments (20%). Population density, number of vacant lots, and property tax values were identified as the most important features to predict the HSW fire activity. A comparison with other inventories revealed that the BC emission profile of Londrina is similar to the profile reported for Greater Mexico City, another Latin American city. Thus, the methodology used in this study could be extended to other cities with similar local BC sources. Finally, we highlight that the lack of local activity data, representative EF, and even methodology may undermine the development of reliable BC inventories, and intensive research should be conducted to characterize the emission sources.

Innovation of Poly(Lactic Acid)/Carbon Black Composite as an Environment-Friendly Antistatic Packaging

Antistatic packaging mainly functions to protect an electronic device from damage caused by the electronic discharge. However, antistatic packaging is typically made with a polymer that's hard to decompose naturally, this can badly affect Indonesian environments considering Indonesian produce a lot of plastic waste. Therefore, environmentally friendly antistatic packaging could potentially alleviate several plastic wastes generated. Antistatic packaging made of Conductive Polymer Composite (CPC) with Poly Lactic Acid as its matrics have a biodegradable characteristic, biocompatibility, resistance to thermal and chemical influence. And the use of Carbon Black as its filler can increase the electrical conductivity of CPC. CB is synthesis by burning coconut shells and activation with H 2 SO 4 . The synthesis of CPC samples was carried out by 2 methods; melt blending using an extruder and solvent blending using chloroform solvent and stirring with a magnetic stirrer at 650 rpm at 60°C. The filler composition was varied, namely 0, 0.5, 0.1, 1.5% by weight of PLA for blending melt and 0, 1.5% by weight of PLA for blending solvent. The thermal properties of the sample were tested by DSC, it was found that the Melting Temperature of the sample was not much different from that of pure PLA with a difference of 0.4-2.2°C. With the FTIR test, it is known that the solvent has completely disappeared from the sample, and the conductivity test shows a increase in conductivity along with the addition of filler from 9,505x10 -12 S/cm to 5,752x10 -7 S/cm and 9,872x10 -12 S/cm to 1,034x10 -6 S/cm for melt and solvent method.

Contamination, sources and health risks of toxic elements in soils of karstic urban parks based on Monte Carlo simulation combined with a receptor model

Understanding the health risks of toxic elements (TEs) in urban park soils and determining their priority control factors are crucial for public health and pollution management. Soil samples were collected from 33 urban parks in Guiyang, a typical karstic city. For each park, 15–45 topsoil samples were collected according to the area and then thoroughly mixed to obtain a representative sample. The results showed that the mean concentrations of TEs in park soils (22.5, 0.37, 88.6, 43.7, 0.26, 39.9, 44.7, and 101.0 mg/kg for As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn, respectively) were higher than their background values. Approximately 54.5% and 33.3% of enrichment factor (EF) values reached moderately enriched to significantly enriched levels for Cd and Hg, respectively. Moreover, 54.5% and 42.4% of monomial potential ecological index (EI) values were at considerable to high risk levels for Cd and Hg, respectively. These results illustrate that Cd and Hg pose high ecological risks. According to the potential ecological risk index (RI) values, 21.2% of the parks were exposed to considerable ecological risk and 48.5% were at moderate risk. Based on the positive matrix factorization (PMF) model, four sources governing TE contamination (including coal combustion, natural sources, traffic emissions, and industrial activities) were identified, with contribution rates of 32.3%, 31.0%, 19.6%, and 17.1%, respectively. A probabilistic health risk assessment showed acceptable non-carcinogenic risks and high levels of carcinogenic risk in all populations. Based on the source-specific health risk assessment, arsenic from coal combustion was determined to be a major contributor to human health risks. Although several efforts have been made by the local government to eliminate coal-borne arsenicosis, our results revealed that the accumulation of arsenic in the soil due to coal combustion poses a potential threat to human health.

Enhanced Performance of Supported Ternary Metal Catalysts for the Oxidation of Toluene in the Presence of Trichloroethylene

Chlorinated volatile organic compounds (CVOCs), even in small quantities, can cause Pt-based catalyst poisoning. Improving the low-temperature chlorine resistance of catalysts is of vital importance for industrial application, although it remains challenging. Considering actual industrial production, a TiO2-supported ternary metal catalyst was prepared in this work to study the catalytic oxidation of multicomponent VOCs (toluene and trichloroethylene (TCE)). Among all of the samples, PtWRu/TiO2 and PtWCr/TiO2 exhibited the best catalytic performance for toluene oxidation. In the mixed VOC oxidation, the PtWCr/TiO2 sample showed the best catalytic activity for toluene combustion (a toluene conversion of 90% was achieved at 258 °C and a space velocity of 40,000 mL g−1 h−1, and the specific reaction rate and turnover frequency at 215 °C were 44.9 × 10−6 mol gPt−1 s−1 and 26.2 × 10−5 s−1). The PtWRu/TiO2 sample showed the best catalytic activity for TCE combustion (a TCE conversion of 90% was achieved at 305 °C and a space velocity of 40,000 mL g−1 h−1, and the specific reaction rate and turnover frequency at 270 °C were 9.0 × 10−6 mol gPt−1 s−1 and 7.3 × 10–5 s−1). We concluded that the ternary metal catalysts could greatly improve chlorine desorption by increasing the active lattice oxygen mobility and surface acidity, thus reducing chlorinated byproducts and other serious environmental pollutants. This work may serve as a reasonable design reference for solving more practical industrial production emissions of multicomponent VOCs.

Spontaneous Bulk-Surface Charge Separation of TiO2-{001} Nanocrystals Leads to High Activity in Photocatalytic Methane Combustion

Spontaneous Bulk-Surface Charge Separation of TiO₂-{001} Nanocrystals Leads to High Activity in Photocatalytic Methane Combustion

Design of structured reactor for biogas exhaust abatement

The post-combustion of methane from stationary sources such as powerplants at biogas installations is an important issue for scientists to address due to the quantities of methane released into the atmosphere. Methane is one of the greenhouse gases, thus its emission should be reduced. Here is shown a converter module designed for methane combustion for use independently or in a two-module reactor together with a deNOx module. The reactor unit is based on short-channel structures in the form of metallic wires immobilised with a mixed CoPd catalyst supported on gamma alumina. The structured reactor packing was characterised by spectroscopic and spectrometric methods in terms of qualitative and quantitative composition (UV–Vis, EDX, AAS), and the morphology by SEM microscopic techniques was determined. The reactor has been successfully investigated in the catalytic reaction of methane combustion from exhaust gas in the one-step methane removal and in the presence of NH3 used in the deNOx process. The results revealed high catalytic activity of methane combustion in both cases, with the catalyst’s mechanical resistance maintained. Therefore, the presented catalytic reactor is a good candidate for methane combustion in cogeneration with nitrogen oxide reduction in installations of stationary sources such as small powerplants.

Spatial–temporal variability and health impact of particulate matter during a 2019–2020 biomass burning event in Southeast Asia

To understand the characteristics of particulate matter (PM) in the Southeast Asia region, the spatial–temporal concentrations of PM10, PM2.5 and PM1 in Malaysia (Putrajaya, Bukit Fraser and Kota Samarahan) and Thailand (Chiang Mai) were determined using the AS-LUNG V.2 Outdoor sensor. The period of measurement was over a year from 2019 to 2020. The highest concentrations of all sizes of PM in Putrajaya, Bukit Fraser and Kota Samarahan were observed in September 2019 while the highest PM10, PM2.5 and PM1 concentrations in Chiang Mai were observed between March and early April 2020 with 24 h average concentrations during haze days in ranges 83.7–216 µg m−3, 78.3–209 µg m−3 and 57.2–140 µg m−3, respectively. The average PM2.5/PM10 ratio during haze days was 0.93 ± 0.05, which was higher than the average for normal days (0.89 ± 0.13) for all sites, indicating higher PM2.5 concentrations during haze days compared to normal days. An analysis of particle deposition in the human respiratory tract showed a higher total deposition fraction value during haze days than on non-haze days. The result from this study indicated that Malaysia and Thailand are highly affected by biomass burning activity during the dry seasons and the Southwest monsoon.

Respiratory Deposition Dose of PM2.5 and PM10 Before, During and After COVID-19 Lockdown Phases in Megacity-Delhi, India

Considerable changes in particulate matter (PM) during COVID-19 lockdown in major cities around the World demand changes in exposure assessment studies of PM. The present study shows variations in respiratory deposition dose (RDD) of both fine (PM2.5) and coarse (PM10) particles before, during and after Covid-19 lockdown phases at three sites (with different pollution signatures) in Delhi—Alipur, Okhla and Pusa Road. Exposure assessment study showed mean PM2.5 RDD (± S.D.) (µg/min) for walk and sit mode during before lockdown (BL) as 2.41(± 1.20) and 0.84(± 0.42) for Alipur, 2.71(± 1.60) and 0.94(± 0.56) for Okhla, and 2.54(± 1.28) and 0.88(± 0.44) for Pusa road, which decreased drastically during Lockdown 1(L1) as 0.85(± 0.35) and 0.30(± 0.12) for Alipur, 0.83(± 0.33) and 0.29(± 0.11) for Okhla, and 0.68(± 0.28) and 0.23(± 0.10) for Pusa road, respectively. Mean PM10 RDD (± S.D.) (µg/min) for walk and sit mode during before lockdown (BL) as 3.90 (± 1.73) and 1.36 (± 0.60) for Alipur, 4.74 (± 2.04) and 1.65 (± 0.71) for Okhla, and 4.25 (± 1.69) and 1.48 (± 0.59) for Pusa Road, respectively which decreased drastically during Lockdown 1(L1) as 2.19 (± 0.95) and 0.76 (± 0.33) for Alipur, 1.73 (± 0.67) and 0.60 (± 0.23) for Okhla and, 1.45 (± 0.50) and 0.50 (± 0.17) for Pusa Road, respectively. Significant decrease in RDD concentrations (Both PM2.5 and PM10) than that of BL phase have been found during Lockdown 1(L1) phase and other successive lockdown and unlock phases—Lockdown 2(L2), Lockdown 3(L3), Lockdown 4(L4) and Unlock1 (UL1) phases. Changes in RDD values during lockdown phases were affected by lesser traffic emission, minimized industrial activities, biomass burning activities, precipitation activities, etc. Seasonal variations of RDD showed Delhites are found exposed to more fine and coarse particles’ RDD (walk and sit modes) before and after lockdown, i.e. during normal days than during lockdown phases showing potential health effects. People in sit condition found less exposed to fine and coarse RDD comparison to those in walk condition both during normal and lockdown days.

Physical and Chemical Properties of Coal Gasification Fine Slag and Its Carbon Products by Hydrophobic-Hydrophilic Separation.

Coal gasification fine slag is a kind of solid waste with low resource utilization rate. The complex embedding of residual carbon and inorganic minerals (ash materials) is the main reason restricting the efficient resource separation and utilization of residual carbon or ash materials. Hydrophobic–hydrophilic separation (HHS) is a separation technology in which mineral particles with different surface hydrophobicity values are enriched in the water phase and oil phase under the action of mechanical stirring. The water on the surface of hydrophobic particles is replaced by the oil phase to form flocs, which are enriched in the hydrophobic liquid phase, while hydrophilic particles are dispersed into the aqueous phase. In this study, the HHS process was used to separate the carbon/ash from the fine gasification slag produced by a Shenning gasifier, Texaco gasifier, and GSP gasifier of Ningxia Coal Industry Co., Ltd. The physicochemical properties of the original sample and the residual carbon products obtained by hydrophobic–hydrophilic separation were analyzed. The results show that HHS can separate the carbon/ash in the three kinds of fine slag to varying degrees. The carbon element is enriched into the hydrophobic phase to form the concentrates, while the silicon element, oxygen element, and metal element enter the tailings. The spherical ash with different particle sizes distributed on the surface of residual carbon and the gap of the matrix is basically removed, while the ash in the carbon–ash melt is difficult to remove. The ash contents of the concentrate and tailings of fine slag of the Shenning gasifier are 22.58 and 96.28%, respectively, which reach the best ash index compared with that of the other two gasifiers. From the change of mineral surface properties after HHS, the distribution of oxygen-containing groups, benzene rings, Si–O, and clay minerals or carbonate minerals in the three kinds of fine slag residual carbon products is basically similar. Compared with the other two gasifier products, the GSP gasifier concentrate has a larger specific surface area and less ash material, more amorphous carbon structures (less graphitic), and more active sites, resulting in a stronger combustion activity.

Silica-Supported Copper (II) Oxide Cluster via Ball Milling Method for Catalytic Combustion of Ethyl Acetate

Highly dispersed CuO/SiO2 catalysts were successfully synthesized by a green process of ball milling (BM) under solvent-free and room temperature conditions. The structural evolution of CuO/SiO2 catalysts prepared by BM was elucidated by TG-DSC, XRD, FT-IR, and XPS characterizations. We found that the copper acetate precursor was dispersed over the layer of copper phyllosilicate which was formed by reacting between the copper acetate precursor and the silica support during the BM process. The copper phyllosilicate layer over the support might play an important role in the stabilization of the CuO cluster (<2 nm) during thermal pretreatment. The 15% CuO/SiO2 catalyst exhibited the best catalytic activity for the catalytic combustion of ethyl acetate as it owned a highest active surface area of CuO among the CuO/SiO2 catalysts with different copper loadings.

Confining shell-sandwiched Ag clusters in MnO2-CeO2 hollow spheres to boost activity and stability of toluene combustion

Confining shell-sandwiched Ag clusters in MnO2-CeO2 hollow spheres to boost activity and stability of toluene combustion

Assessment greenhouse gas emissions on households in Can Tho city

This study investigated household greenhouse gas (GHG) emissions in Ninh Kieu, Cai Rang and Binh Thuy districts in Can Tho city. The calculated emissions were based on the Intergovernmental Panel on Atmospheric Brown Cloud Emission Inventory Manual - ABC EIM (2013) for the 3 gases of carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O). Data collection is through the interviewing of 565 households including direct emission sources (gas, coal, firewood burning activities) and indirect emission sources (electricity consumption and domestic solid waste burning). The results found that in the year 2019, the total GHG emissions in the three districts was 1,008,197.82 tons CO2eq/year, in which CO2accounted for the highest proportion with 988,716.68 tons/year (98.07%), with both CH4 and N2O accounting for a very low proportion with about 1.88 and 0.05% respectively. Among the districts, Ninh Kieu contributed the highest proportion to emission at 59.43%, next to Cai Rang at 21.69% and the final in Binh Thuy at 18.88%. In addition, it was revealed that indirect emission sources of 1.4 times higher than direct emission sources in which Ninh Kieu district has the highest emission and higher than Cai Rang and Binh Thuy districts at 6.4 to 7.6 times, respectively. The research outcomes will be supported to the policy makers in greenhouse gas emission mitigation scenario development and serve as a basis for formulating emission reduction strategies of the city.

The Contents of Potentially Toxic Elements and Emission Characteristics of PM2.5 in Soil Fugitive Dust around Six Cities of the Yunnan-Guizhou Plateau in China

The contents of potentially toxic elements (V, Cr, Mn, Co, Ni, Cu, Zn, As, Cd, and Pb) and emission characteristics of PM2.5 in soil fugitive dust (SFD) in six Yunnan cities (Baoshan, Kunming, Wenshan, Honghe, Yuxi, and Zhaotong) were investigated in this research. The results showed that the contents of Zn and Pb in PM2.5 of SFD were the highest around Honghe and Yuxi, respectively, while the contents of Mn were the highest in PM2.5 of SFD around the other four cities. The enrichment factor and correlation indicated that the potentially toxic elements’ pollution degrees of PM2.5 of SFD around Kunming, Yuxi, and Honghe were higher than those around the other three cities and that potentially toxic elements were generally affected by metal smelting activities, and in Zhaotong, were affected by coal burning activities, while in Wenshan and Baoshan were less affected by human activities. The total emission of PM2.5 of SFD in the six cities was 7705.49 t in 2018. The total emission factor of PM2.5 of SFD reached the highest level from January to May and the lowest level from July to October. The health risk assessment showed that the potentially toxic elements in PM2.5 of SFD for children in the six cities and for adults in Baoshan, Kunming, Honghe, and Zhaotong had non-carcinogenic risk (non-carcinogenic risk thresholds were greater than 1), and As contributes most to non-carcinogenic risk. The carcinogenic risk value of Cr in PM2.5 of SFD in Kunming and Zhaotong was between 1 × 10−6 and 1 × 10−4, which had a certain carcinogenic risk. More attention should be paid to alleviate health risks posed by particle-bound potentially toxic elements through SFD.

Co-Combustion Characteristics And Ash Melting Behavior Of Sludge/High-Alkali Coal Blends

ABSTRACT Liquid slagging is an important solution for the problem of high-alkali coal slagging. The blending of low-melting-point fuel for combustion can effectively reduce the ash melting point of mixed fuel, improving the efficiency of liquid slagging. In this study, highly active sludge is mixed with Zhundong (ZD) coal. Then, co-combustion characteristics and ash melting behavior are studied by combining thermogravimetric analysis, thermodynamic analysis, ash melting analysis and ash composition analysis. The following results are observed. Ignition temperature is significantly reduced with an increase in sludge blending ratio, and combustion performance deteriorates rapidly when sludge proportion exceeds 20 wt.%. The burn out temperature initially decreases and then increases, reaching its minimum value when the sludge blending ratio is 10 wt.%. The blending of sludge causes the apparent activation of the sample to decrease, enhancing the combustion activity of the mixed fuel. The mixed fuel has lower ash melting point. A eutectic system with low melting point is produced due to the reaction of a large amount of sludge Fe2O3 with SiO2 in coal. The ash melting point is only 1080°C when 10 wt.% sludge is mixed. On the basis of the two considerations for improving combustion performance and reducing the melting point of ash, the recommended optimal blending ratio of sludge is 10 wt.%.

Assessing spatiotemporal sources of biogenic and anthropogenic sedimentary organic matter from the mainstream Haihe River, China: Using n-alkanes as indicators

Sedimentary organic matter (SOM) plays an important role in the transportation and transformation of various pollutants and the carbon cycle in aquatic and terrestrial ecosystems, especially for seagoing rivers. However, few studies have focused on the sources and factors of SOM in rivers under the significant pressure of high urbanization and industrialization. In this study, we adopted the molecular markers of n-alkanes and their proxies in the mainstream Haihe River to reveal the spatiotemporal distributions and biogenic and anthropogenic sources of SOM. The concentrations of Σ29n-alkanes, Σbiogenicn-alkanes, and Σanthropogenicn-alkanes were 4985.6 (127.5–26,296.6), 1872.1 (38.1–9216.9), and 3113.5 (89.4–18,259.7) ng·g−1 dw (dry weight), respectively. Hybrid sources of n-alkanes were found in this study. The composition distribution and proxies of n-alkanes showed that woody and herbaceous plants are the main sources of biogenic SOM, while incomplete fossil fuel burning and heavy oil emissions served as the main contributors to anthropogenic SOM in the mainstream Haihe River, especially through industrial activities. The average chain length of biogenic n-alkanes (ACLbio) was verified to quantify the relative contributions of biogenic sources of SOM and proxies; the average chain length of anthropogenic n-alkanes (ACLanthro), and the ratio of unit short‑carbon to unit long‑carbon anthropogenic n-alkanes (L/H) were verified to quantify the relative contributions of anthropogenic sources of SOM in the river system. Impacts from sedimentary geochemistry (such as total organic carbon (TOC) and grain size of sediments) on n-alkanes were explored, and the correlations of Σ29n-alkanes with TOC and grain size of the river sediment indicated that terrestrial organic matter was the main source of SOM, while emissions from incomplete combustion and intensive manufacturer activities should also not be neglected.

Tailoring Co3O4 active species to promote propane combustion over Co3O4/ZSM-5 catalyst

Co3O4 species in Co3O4/ZSM-5 catalyst can be tailored to smaller particle size and higher content of surface lattice O2− and Co3+ species by pre-reduction and pre-oxidation (labeled as Co3O4/ZSM-5-A catalyst), resulting in the enhanced catalytic activity for propane combustion. The 25Co3O4/ZSM-5-A catalyst gives a high reaction rate of 0.379 μmol gcat−1 s−1, which is over two folds higher than that of the 25Co3O4/ZSM-5 catalyst (reaction rate of only 0.177 μmol gcat−1 s−1). The higher content and reducibility of surface lattice O2− in the Co3O4/ZSM-5-A catalyst facilitated its activity for propane combustion through the Mars-Van Krevelen mechanism as evidenced by in-situ diffuse reflectance infrared spectra. The 25Co3O4/ZSM-5-A catalyst (Ea = 37.1 ± 2.9 kJ mol−1) gives much lower apparent activation energy than 25Co3O4/ZSM-5 catalyst (Ea = 85.5 ± 6.7 kJ mol−1), suggesting the easier occurrence of propane combustion over the 25Co3O4/ZSM-5-A catalyst. The atmospheres (2% O2 + 0.2% C3H8 + N2; 9% O2 + 0.2% C3H8 + N2; Air) for pre-oxidation process also significantly affect the catalytic activity of the finally obtained catalysts (labeled as 25Co3O4/ZSM-5-A, 25Co3O4/ZSM-5-B, 25Co3O4/ZSM-5-C), which is attributed to their differences in Co3O4 species (nanoparticle size, and the content of surface lattice O2− and Co3+). Besides, the acid sites of ZSM-5 also play important role on the catalytic combustion propane.

Contamination of 16 priority polycyclic aromatic hydrocarbons (PAHs) in urban source water at the tidal reach of the Yangtze River.

To explore the occurrence, source, and risk of 16 priority polycyclic aromatic hydrocarbons (PAHs) in urban source water at the tidal reach of the Yangtze River, eighty-nine surface water samples were collected in 8 field campaigns from July 2018 to November 2019. Fifteen of 16 PAHs except for dibenz(a,h)anthracene (DBA) were found in the water. Detection frequencies were observed between 53 and 72% for PAHs with 4 rings, while most of other PAHs were less detected, e.g., benzo(a)pyrene (BaP) in 31% of samples. The total concentrations of 16 priority PAHs reached up to 2.8µg·L-1 and increased during the tidal transitions from flood to ebb. The average concentrations of PAHs in ebb tides were higher than those in flood tides. PAH concentrations and compositions showed great variation with different sampling campaigns, and higher levels and more components were observed in the rainy months and cold months. Those priority PAHs in the tidal water source are mainly from combustion activities (especially fossil fuel combustion), but the contribution from oil spills/leakage is also important in rainy months. High-molecular-weight PAHs in this tidal water source may pose risks to aquatic life, while they pose no carcinogenic risk to human health via ingestion of drinking water.

Dioxins and dioxin-like compounds in meat and meat products

Dioxin and dioxin-like compounds are persistent organic pollutants that received considerable attention in recent years due to their high potential toxicity, wide distribution and extreme stability. Polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) mainly occur in the environment as a result of several human activities including combustion, incineration and many other industrial activities, whereas polychlorinated biphenyls (PCBs) congeners were intentionally manufactured and widely used in various fields. Since dioxin and dioxin-like compounds are found in various environmental compartments (air, water, soil, sludge, sediment, food, feed, blood, animal and human tissues), humans could be exposed to them via inhalation, dermal contact or food ingestion. However, 90% of human exposure to dioxin is through food ingestion particularly foods from animals and foods that are rich in fat. In contrast, only low levels have been found in food items of plant origin. Exposure to dioxin compounds is associated with various adverse health problems. However, their toxicity varies dramatically according to the type of dioxin, species of exposed organism, as well as exposure frequency and duration. Dioxins are mainly determined by instrumental chromatographic methods such as GC-HRMS and GC–MS/MS. Many efforts have been made to remove, reduce and prevent these hazardous substances from the environment. However, the best method for reducing human exposure to dioxins and dioxin-like compounds is controlling and minimizing their production. In this article, structures, sources, exposure, toxicity and analysis methods of dioxin and dioxin-like compounds in meat and other foods were reviewed.

Assessment of PM2.5 using satellite lidar observations: Effect of bio-mass burning emissions over India

The present study estimates the particulate matter with aerodynamic diameters less than 2.5 μm (PM2.5) over the Indian sub-continent using near-surface retrieval of aerosol extinction coefficient (2007–2021) of Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) onboard Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) satellite. Climatology of wintertime PM2.5 during the last 15 years shows the highest concentration over the middle Indo-Gangetic Plain (IGP) and northwest India with a 3 to 4 fold increase in magnitude compared to the peninsular India. Surface-level PM2.5 mass concentration during winter (December to February) shows statistically significant positive trends over the Indian subcontinent. It increases at a rate of ~3% over the IGP and arid regions of northwest India, and ~4% over peninsular India during the last fifteen years (2006–2020). Interannual variability of average near-surface PM2.5 concentration over the Indian sub-continent during the fog occurring season (December to February) shows a statistically significant correlation with the post-harvest agro-residue burning over the western IGP (Punjab and Haryana) during November. The wintertime near-surface PM2.5 concentration shows a higher correlation with anthropogenic agro-residue burning activity compared to meteorological parameters. The influence of agro-residue burning during November over northern India extends up to peninsular India and might contribute to continental pollution outflow and associated aerosol plumes persisting over the Northern Indian Ocean during the winter season. Sustainable energy recovery solutions to the agro-residue burning need to be implemented to effectively reduce the far-reaching implications of the post-monsoon burning activity over the western IGP.

Pollution Characteristics and Health Risk Assessment of VOCs in Jinghong

In order to investigate the seasonal variation in chemical characteristics of VOCs in the urban and suburban areas of southwest China, we used SUMMA canister sampling in Jinghong city from October 2016 to June 2017. Forty-eight VOC species concentrations were analyzed using atmospheric preconcentration gas chromatography–mass spectrometry (GC–MS), Then, regional VOC pollution characteristics, ozone formation potentials (OFP), source identity, and health risk assessments were studied. The results showed that the average concentration of total mass was 144.34 μg·m−3 in the urban area and 47.81 μg·m−3 in the suburban area. Alkanes accounted for the highest proportion of VOC groups at 38.11%, followed by olefins (36.60%) and aromatic hydrocarbons (25.28%). Propane and isoprene were the species with the highest mass concentrations in urban and suburban sampling sites. The calculation of OFP showed that the contributions of olefins and aromatic hydrocarbons were higher than those of alkanes. Through the ratio of specific species, the VOCs were mainly affected by motor vehicle exhaust emissions, fuel volatilization, vegetation emissions, and biomass combustion. Combined with the analysis of the backward trajectory model, biomass burning activities in Myanmar influenced the concentration of VOCs in Jinghong. Health risk assessments have shown that the noncarcinogenic risk and hazard index of atmospheric VOCs in Jinghong were low (less than 1). However, the value of the benzene cancer risk to the human body was higher than the safety threshold of 1 × 10−6, showing that benzene has carcinogenic risk. This study provides effective support for local governments formulating air pollution control policies.