The use of mercury in gold mining, as well as the presence of uncontrolled and illegal releases to the environment, continues to create severe pollution and public health risks for over 14 million people worldwide, particularly in developing countries. This study presents a modeling framework to estimate the fate and transport of mercury on a national-scale river network, where a physical-based conceptual model is implemented. Using the model, mercury concentrations are estimated for every river segment in the network, serving as a tool for effective management and control nationwide, enabling establishing intervention priorities. To test the framework’s suitability, it was applied to Colombia’s river network, a country with documented mercury pollution issues from gold mining. Results revealed persistent concentrations above 0.001 µg/L in all major basins, and concentrations close to 7 µg/L in active mining areas. The release of nearly 300 mines led to the contamination of river distance between 50 and 285 km downstream, exceeding local drinking water standards. The model results were validated with mercury concentration data of available studies in the country, showing small deviations between modeled and measured concentrations (<0.95 µg/L), confirming the robustness and suitability of the proposed framework as a screening assessment for national-scale mercury transport and fate.
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