The peculiar illumination and insolation conditions at the poles of the Moon lead to the formation of Permanently Shadowed Regions (PSR) that act as cold traps for volatiles and are important for In Situ Resource Utilization (ISRU). However, since these regions lie in shadows of surrounding topographic highs, the ability of optical remote sensing in imaging these regions for photo reconnaissance is limited and using other modes of remote sensing becomes imperative. In this work, reflectance from optical data, backscatter from active microwave data and temperature from thermal data from the surfaces of three craters – de Gerlache, Haworth and Shoemaker – on the South Pole of the Moon, in close proximity to the Artemis III candidate landing sites, has been studied. Images from Clementine UVVIS, LRO WAC and LRO NAC have been compared with fully polarimetric data from the L-bands sensor of Chandrayaan-2 DFSAR. Further, the temperatures at the surface of the craters have been studied using data from LRO DIVINER. Since large parts of the craters under study lie in permanent shadows, Clementine UVVIS and LRO WAC could image only some parts of the rims. LRO NAC, with its longer exposure times, could image some parts within the crater however the walls of the crater and the floor near the walls remained in shadow. DFSAR was found to be useful in viewing the permanently shadowed regions of the craters. Overall, the backscatter in HH and VV (co-pol) channels was higher than the backscatter in HV and VH (cross-pol) channels. The elevated rims of the craters were clearly visible in co-pol channels and the rough texture of the ejecta of the craters had a distinct high backscatter in cross-pol channels. This fully polarimetric data can be used to map the interiors of the craters where optical data has low albedo. Analysis of the thermal data revealed that within the craters, in the regions that were in perpetual shadows, the maximum summer temperatures were less than 150 K making these regions cold traps for volatiles and possible locations of surface water–ice. The parts of craters lying in the shadows of surrounding higher features had lower maximum temperatures in summer and the parts facing them had higher maximum temperatures due to reflected insolation. Seleno Referenced Image (SRI) product from Chandrayaan-2 DFSAR was found to be a viable alternative to optical data for viewing the PSRs and for their geologic mapping.