The tungsten inert gas (TIG) welding process is widely used in various industries for its ability to produce high-quality welds at a low cost. However, TIG welding struggles with welding thick stainless steel in a single pass, reducing production efficiency. To address this, new TIG variants such as activated TIG (A-TIG), flux bound TIG (FB-TIG), and flux zone TIG (FZ-TIG) have been developed to enhance penetration in austenitic stainless steel. This study investigates the effects of TiO2 and Fe2O3 flux on 304 stainless steels welded using A-TIG, FB-TIG, and FZ-TIG processes. Results show a slight increase in the depth-to-width (d/w) ratio for A-TIG and FB-TIG, while FZ-TIG achieved a 59% higher d/w ratio compared to autogenous TIG welding. The increased penetration is attributed to the reversal Marangoni convection and arc constriction. Microstructural analysis reveals a higher delta ferrite content in A-TIG and FZ-TIG welds due to increased heat input. Additionally, FZ-TIG welds exhibited an 11.5% higher microhardness compared to autogenous TIG welds. FZ-TIG welding enhances penetration and mechanical properties effectively.