In tungsten inert gas (TIG) welding, less penetration depth is achieved in a single pass which adversely affects productivity, Activated TIG (A-TIG) welding techniques achieve better performances and higher penetration depths compared to conventional TIG welding. Pure argon does not have the potential to provide adequate penetration in austenitic stainless steel. Argon–hydrogen shielding gas mixture provides high heat flux, thereby influencing the arc voltage and penetration. In the present study, hydrogen is added to base shielding gas argon to study the effect on weld geometry during TIG and A-TIG of 310S stainless steel. The result shows a higher weld depth to width ratio and a significant reduction in the angular distortion. Also, higher tensile strength is obtained in A-TIG weld metal with 1% hydrogen addition, due to more efficient cooling of the weldment. However, increasing the hydrogen concentration in shielding gas resulted in defect formations in the weldment due to the interaction between activated flux and the hydrogen.