Carbon paste electrodes (CPEs) are commonly employed in electroanalysis because of their chemical stability, broad electrochemical window, low capacitive current, ease of fabrication, and surface renewability. Electrocatalysts can easily be embedded into CPEs to make them suitable for a variety of applications. Poor biowaste management presents a significant challenge in the agro-industry and agriculture due to the rapid decomposition of biowaste, driven by its high water content and limited biological stability, which leads to pest attraction and greenhouse gas emissions. Consequently, this green waste can be utilized for the development of electrocatalysts. Activated carbon (AC) has been utilized in progressive electrochemical applications as it exhibits high conductivity and porosity that help to enhance electrocatalytic activity. Herein, pineapple fruit crown (PC) peel-derived AC (PCAC) is utilized as the sensing material for the determination of fungicide, carbendazim (CBM). The synthesized material was characterized using SEM, FT-IR, XRD, EDX, AFM, CV and EIS. Besides, to enhance the surface properties, Sodium dodecyl sulfate (SDS) surfactant is used as a mediator in detecting CBM. The CV and SWV approaches were employed to assess the electrochemical response of the developed electrodes for the CBM determination. Under optimum experimental conditions, the SDS/PCAC/CPE exhibits low DLim and QLim values of 32.0 nM and 128.0 nM with considerable selectivity. Furthermore, the SDS/PCAC/CPE was employed in real-time analysis of CBM in spiked environmental samples, which showed satisfying recovery results. Moreover, the electrode showed good stability over multiple measurements, and these results demonstrate that SDS/PCAC/CPE is a promising sensor for CBM detection.