In this paper, the fracture performance of nano-metakaolin (NMK) cement mortar during early hydration period was investigated. Different NMK contents (0 %, 3 %, 5 %, 7 %) were considered, and three-point bending tests were conducted. The digital image correlation technology and acoustic emission technology were utilized to analyze P-CMOD curves, initial fracture toughness, unstable fracture toughness, fracture energy, cumulative AE hits, and cumulative AE energy, AE source locations of cement mortar at early hydration stages. Furthermore, SEM experiments were utilized to analyze the mechanism by which NMK affects fracture performance of cement mortar. The results indicate that the incorporation of NMK enhances the fracture properties of cement mortar, with the most suitable NMK content being 5 %. The addition of NMK increases the cracking load, peak load, and the CMOD at the peak load of the cement mortar at 3 d, 7 d, and 14 d. The cracking load and fracture energy of the cement mortar with 5 % NMK increase by 22.5 % and 35.7 % respectively, compared to ordinary cement mortar at 14 d. NMK enhances the initial fracture toughness and unstable fracture toughness of the cement mortar, improving its crack propagation resistance. The unstable fracture toughness of the cement mortar is the largest when the NMK content is 5 % at 14 d, which is 31.6 % higher than that of ordinary cement mortar. Furthermore, NMK increases the cumulative AE energy and fracture energy of the cement mortar, increasing the cumulative ring counts and cumulative AE hits, causing the crack propagation path to deviate and resulting in improved crack resistance. The cumulative ring counts and AE hits for the cement mortar with 5 % NMK are 42.9 % and 66.2 % higher, respectively, than those for ordinary cement mortar at 14 d. NMK significantly modifies the cement matrix, thereby enhancing the fracture resistance of cement mortar.