Accurate temperature monitoring of heat transfer tube is crucial for safe and efficient operation of nuclear power plants, and radiation thermometer is a common method used for this purpose. This paper thoroughly introduces the measurement principle of the radiation thermometer with an operation wavelength range of 8-14 μm. The spectral emissivity of Ni-based alloy DD6 under argon condition is measured using an emissivity measurement setup equipped with a Fourier-transform infrared (FTIR) spectrometer. By integrating the spectral emissivity in the working wavelength range, the spectral band emissivity can be calculated to enhance the accuracy of calculation results obtained by radiation thermometer. And curve of the spectral band emissivity with temperature can be accurately described by the nonlinear model. The radiation and corrected temperatures are compared with the temperatures obtained by a K-type thermocouple to verify the availability of the spectral band emissivity obtained by fitting the nonlinear model. The temperature comparison results demonstrate that the corrected temperatures are closer to the true temperature than the radiation temperature, with a maximum temperature deviation of only 4.38°C. The combined relative uncertainty of true temperature measurement by the radiation thermometer at temperatures of 200, 300, 400, and 500°C is less than 3.60%.