Quantification of thermal environments in cities is of significance for revealing heat-related impacts and the performance of urban cooling measures, in which field measurement has been a prevailing method. However, the accuracy of field measurement is a critical issue, especially considering the spatial heterogeneity of urban spaces and its interactions with urban heat sources. Accordingly, the selection of fixed measurement points is of importance to accurately capture urban thermal environments, which has not been well considered in previous studies. Therefore, this study examines the heterogeneity of street thermal environments and explores an approach to improving field measurement accuracy. The study was empirically conducted in two typical streets in Chongqing, a hot-humid city in China. The results indicate that both microclimatic and thermal comfort indices could exhibit strong spatiotemporal heterogeneity, whilst they were measured in a same street. At a specific time, within a street, the largest air temperature (Ta), mean radiant temperature (MRT), physiological equivalent temperature (PET) and universal thermal climate index (UTCI) difference within a same street could reach 9.4 °C, 45.9 °C, 29.6 °C and 16.3 °C. Moreover, the measured Ta, MRT, PET and UTCI deviated from the average values which are used to represent street thermal environments and thermal comfort. Ta and UTCI converged towards the averaged values stronger than MRT and PET, while only 53.4% and 67.1% of the measured Ta and only 34.3% and 40.7% of measured UTCI fell into 95% accuracy zones. A framework of optimised multi-objective mobile measurement path was proposed, based on which the optimised measurement paths were obtained, and the measurement accuracy could be improved to above 98.0%. Overall, this study provides a reference for understanding spatiotemporal heterogeneity of street thermal environments and offers an approach to overcoming this issue for high accuracy.
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