In the field of heat transfer in permanent magnet synchronous motors (PMSM) for electric vehicles, the boundary element method (BEM) has been applied for the first time to calculate the steady-state temperature of the PMSM with a spiral water-cooled system. In this investigation, the boundary-integration equation for the steady-state heat transfer problem of a water-cooled PMSM is first derived on the basis of thermodynamic theory, and the system of constant coefficient differential equations is obtained by discretizing its boundaries, while the temperature results obtained from the BEM are compared with the finite element method (FEM) results. Furthermore, the temperature distribution and heat transfer characteristics obtained from the FEM and BEM were verified twice using the PMSM prototype and test platform. The results show that the maximum relative error between the temperature calculation results of FEM and BEM is 1.97%, and the maximum relative error between the results of BEM and the test does not exceed 3%, which finally verifies the validity and accuracy of BEM in solving the heat transfer problems of water-cooled PMSM.