Abundant Polycyclic Aromatic Hydrocarbons Research Articles

Polycyclic Aromatic Hydrocarbons as an Extraterrestrial Atmospheric Technosignature

Abstract Polycyclic aromatic hydrocarbons (PAHs) are prevalent in the Universe and interstellar medium but are primarily attributed to anthropogenic sources on Earth, such as fossil fuel combustion and firewood burning. Drawing upon the idea of PAHs being suitable candidates for technosignatures, we investigate the detectability of those PAHs that have available absorption cross sections in the atmospheres of Earth-like exoplanets (orbiting G-type stars at a distance of 10 pc) with an 8 m mirror of the Habitable Worlds Observatory (HWO). Specifically, we focus on Naphthalene, Anthracene, Phenanthrene, and Pyrene. Our simulations indicate that under current-Earth-like conditions, detecting PAH signatures between 0.2 and 0.515 μm is infeasible. To account for the historical decline in PAH production post the industrial revolution, we explore varying PAH concentrations to assess instrumental capabilities of detecting civilizations resembling modern Earth. We also evaluate telescope architectures (6 m, 8 m, and 10 m mirror diameters) to put our results into the context of the future HWO mission. With these four molecules, PAH detection remains infeasible, even at concentrations 10 times higher than current levels. While larger mirrors provide some advantages, they fail to resolve the spectral signatures of these molecules with significant signal-to-noise ratios. The UV absorption features of PAHs—caused by π-orbital → π*-orbital electronic transitions—serve as valuable markers, due to their distinct and detectable nature, preserved by the aromatic stability of PAHs. Additional lab measurements are necessary to gather absorption cross-sectional data beyond UV for more abundant PAHs. This may help further in improving the detectability of these molecules.

Unraveling the differences between pyrolytic and petrogenic sources in oiled areas of the South Atlantic: An analytical method for biliary PAHs.

Polycyclic aromatic hydrocarbons (PAHs) represent significant organic pollutants within the scope of environmental monitoring and management investigations of oiled areas. Characterized as precursors of mutagenic and carcinogenic processes, they exert a direct influence on human and environmental health. To assess the impacts of one of the largest oil spills affecting coral reefs in Alagoas, Brazil, researchers developed, validated, and applied an innovative methodology. This approach was designed to evaluate the effects of petrogenic and pyrogenic PAHs using Stegastes fuscus, a fish species commonly found in the region. This approach utilizes high-performance liquid chromatography paired with a fluorescence detector (HPLC-FD) to accurately measure PAHs in fish bile. This method analyzed six compounds whose elution occurred in the following sequence: OHNaph>OHFln>OHPhen>OHPyr>OHChr>OHBaP. The most favorable results were observed using the matrix curve, with a linear correlation coefficient exceeding 0.9800, DL ranging from 0.03 to 79.2ng/L, QL ranging from 0.1 to 264.1ng/L, and accuracy ranging from 86% to 96% and with RSD between 0 and 8%. To implement the methodology, specimens of the S. fuscus species were utilized, within which all target compounds were detected across all bile samples. In 2020, the compound OHNaph with minimum, maximum value of ND-21.42x104ng/L, and average 430.65x103ng/L, was the most frequently detected in the Japaratinga region, while in 2021, OHPyr with ND-20.57x103ng/L, and 19.99x103ng/L was the most prevalent, also in Japaratinga. However, the results indicate a consistent decrease in OHNaph concentrations across all sites from 2020 to 2021, whereas levels of OHBaP showed an increase during the same period. The relative abundance of bile PAHs showed that the levels of OHNaph represent the influence of the 2019 oil spill, while the sum of OH PAHs (phenanthrene, pyrene, chrysene, and fluorene) indicates a mixed-source group. Additionally, BaP reflects the impact of chronic sources in the region, allowing for the differentiation between the influence of chronic activities and the acute impact promoted by the 2019 oil spill in the area.

Probing the heating of the neutral atomic interstellar medium in the Dwarf Galaxy Survey through infrared cooling lines

Star formation in galaxies is regulated by dynamical and thermal processes. In the Milky Way and star-forming galaxies with similar metallicity, the photoelectric effect on small dust grains usually dominates the heating of the neutral atomic gas, which constitutes the main star-forming gas reservoir. In more metal-poor galaxies, the lower dust-to-gas mass ratio together with the higher occurrence and luminosity of X-ray sources suggest that other heating mechanisms may be at play. We aim to determine the contribution of the photoelectric effect, photoionization by UV and X-ray photons, and ionization by cosmic rays to the total heating of the neutral gas in a sample of 37 low-metallicity galaxies. In particular, we wish to assess whether X-ray sources can be a significant source of heating. We also attempt to recover the intrinsic X-ray fluxes and compare them with observations when available. We used the statistical code MULTIGRIS together with a photoionization grid of Cloudy models propagating radiation from stellar clusters and potential X-ray sources to the ionized and neutral gas. This grid includes physical parameters such as metallicity, gas density, ionization parameter, and radiative source properties. We describe a galaxy as a combination of many 1D components linked by a few physical hyperparameters. We used infrared cooling lines as constraints to evaluate the most likely combinations and parameters. We constrained the heating fractions for the main mechanisms for the first time in a low-metallicity galaxy sample. We show that for the higher metallicity galaxies, the photoelectric effect dominates the neutral gas heating. At metallicities below $1/8$ the Milky Way value, cosmic rays and photoionization can become predominant. We computed an observational proxy for the photoelectric effect heating efficiency on polycyclic aromatic hydrocarbons (PAHs) using the total cooling traced by We show that this proxy can match theoretical expectations when accounting for the fraction of the heating due to the photoelectric effect according to our models. Finally, we show that it is possible to predict the X-ray fluxes reasonably well in the $0.3-8$\,keV band from the gas cooling lines for most of the galaxies observed in this band. With the current grid and assumptions, determining the exact heating fraction due to cosmic rays remains difficult, but we speculate that heating from X-ray sources is more important. As expected from the low abundance of dust and PAHs in metal-poor galaxies, heating mechanisms other than the photoelectric effect heating must be accounted for. Bright X-ray sources may deposit their energy on large scales in such transparent, dust-poor interstellar medium, and thus they represent promising avenues to understand the physical properties of the main star-forming gas reservoir in galaxies. The modeling strategy adopted here makes it possible to recover the global intrinsic radiation field properties when X-ray observations are unavailable, such as in early universe galaxies.

Detectability of polycyclic aromatic hydrocarbons in the atmosphere of WASP-6 b with JWST NIRSpec PRISM

ABSTRACT Polycyclic aromatic hydrocarbons (PAHs) have been detected throughout the Universe where they play essential roles in the evolution of their environments. For example, they are believed to affect atmospheric loss rates of close-in planets and might contribute to the pre-biotic chemistry and emergence of life. Despite their importance, the study of PAHs in exoplanet atmospheres has been limited. We aim to evaluate the possibility of detecting PAHs on exoplanets considering future observations using JWST’s Near-Infrared Spectrograph PRISM mode. The hot Saturn WASP-6 b shows properties that are consistent with a potential PAH presence and is thus used as a case study for this work. Here, we compare the likelihoods of various synthetic haze species and their combinations with the influence of PAHs on the transmission spectrum of WASP-6 b. This is possible by applying the atmospheric retrieval code petitradtrans to a collection of data from previous observations. Subsequently, by exploring synthetic, single transit JWST spectra of this planet that include PAHs, we assess whether these molecules can be detected in the near future. Previous observations support the presence of cloud/haze species in the spectrum of WASP-6 b. While this may include PAHs, the current data do not confirm their existence unambiguously. Our research suggests that utilizing the JWST for future observations could lead to a notable advancement in the study of PAHs. Employing this telescope, we find that a PAH abundance of approximately 0.1 per cent of the interstellar medium value could be robustly detectable.

Synergistic Toxicity of Pollutant and Ultraviolet Exposure from a Mitochondrial Perspective.

Ultraviolet (UV) exposure and atmospheric pollution are both independently implicated in skin diseases such as cancer and premature aging. UVA wavelengths, which penetrate in the deep layers of the skin dermis, exert their toxicity mainly through chromophore photosensitization reactions. Benzo[a]pyrene (BaP), the most abundant polycyclic aromatic hydrocarbon originating from the incomplete combustion of organic matter, could act as a chromophore and absorb UVA. We and other groups have previously shown that BaP and UVA synergize their toxicity in skin cells, which leads to important oxidation. Even if mitochondria alterations have been related to premature skin aging and other skin disorders, no studies have focused on the synergy between UV exposure and pollution on mitochondria. Our study aims to investigate the combined effect of UVA and BaP specifically on mitochondria in order to assess the effect on mitochondrial membranes and the consequences on mitochondrial activity. We show that BaP has a strong affinity for mitochondria and that this affinity leads to an important induction of lipid peroxidation and membrane disruption when exposed to UVA. Co-exposure to UVA and BaP synergizes their toxicity to negatively impact mitochondrial membrane potential, mitochondrial metabolism and the mitochondrial network. Altogether, our results highlight the implication of mitochondria in the synergistic toxicity of pollution and UV exposure and the potential of this toxicity on skin integrity.

Characterising polycyclic aromatic hydrocarbons in road dusts and stormwater in urban environments.

The presence of polycyclic aromatic hydrocarbons (PAHs) pollution on urban road surfaces is one of the major environmental concerns. However, knowledge on the distribution variability of PAHs in road dusts (RDS) and stormwater is limited, which would restrict the further risk evaluation and mitigation implementation of PAHs in road stormwater runoff. This study collected RDS samples and stormwater samples on fourteen urban roads in Shenzhen, China. This study investigated the variation of sixteen PAHs species in RDS and stormwater, and further evaluated the intrinsic and extrinsic factors which influence PAHs accumulation on urban road surfaces. The research outcomes showed significant differences on spatial distribution of PAHs in RDS and in stormwater. The land use types, industrial, commercial and port areas and vehicular volume have a positive relationship with PAHs abundance while dust particle size showed a negative correlation with PAHs abundance. For two phases in stormwater, fluctuation of PAHs with the rainfall duration in total dissolved solid (TDS) was more intensive than in dissolved liquid phase (DLP). This indicated when PAHs attached to RDS enter stormwater, most of PAHs still tend to be on solid particles than in liquid. The study outcomes are expected to contribute to efficient designs of PAHs polluted stormwater mitigation.

Demineralization activating highly-disordered lignite-derived hard carbon for fast sodium storage

Lignite, as one of the coal materials, has been considered a promising precursor for hard carbon anodes in sodium-ion batteries (SIBs) owing to its low cost and high carbon yield. Nevertheless, hard carbon directly derived from lignite pyrolysis typically exhibits highly ordered microstructure with narrow interlayer spacing and relatively unreactive interfacial properties, owing to the abundance of polycyclic aromatic hydrocarbons and inert aromatic rings within its molecular composition. Herein, an innovative demineralization activating strategy is established to simultaneously modulate the interfacial properties and the microstructure of lignite-derived carbon for the development of high-performance SIBs. Demineralization process not only creates numerous void spaces in the matrix of lignite precursor to assist aromatic hydrocarbon rearrangement, thereby reducing the ordering and expanding interlayer spacing, but also exposes more interfacial oxygen-containing functional groups to effectively increasing the sodium storage active sites. As a result, the optimal demineralized lignite-derived hard carbon (DLHC 1300) delivers a high reversible capacity of 335.6 mAh g-1 at 30mAg-1, superior rate performance of 246.3 mAh g-1 at 6 A g-1 and nearly 100% capacity retention after 1100 cycles at 1A g-1. Furthermore, the optimized DLHC 1300 material functions as an outstanding anode in sodium ion full cells. This work significantly advances the development of low-cost, high-performance commercial hard carbon anodes for SIBs.

Oral exposure to phenanthrene during gestation disorders endocrine and spermatogenesis in F1 adult male mice

Phenanthrene (Phe), a typical low-molecular-weight polycyclic aromatic hydrocarbon (PAH) of three benzene rings, is one of the most abundant PAHs detected in daily diets. Pregnant women and infants are at great risk of Phe exposure. In the present study, Phe was administered to pregnant mice at a dose of 0, 60, or 600 μg/kg body weight six times, and the F1 male mice showed significant reproductive disorders: the testicular weight and testis somatic index were significantly reduced; the levels of serum testosterone, GnRH and SHBG were increased, while the FSH levels were reduced; histological analysis showed that the amount of Sertoli cells and primary spermatocytes in seminiferous tubules was increased, while the amount of secondary spermatocytes and spermatids were decreased in Phe groups. The protein levels of PCNA and androgen receptor were reduced. Differently expressed genes in the testis screened by RNA sequence were enriched in antioxidant capacity, reproduction et al.. Further biochemical tests confirmed that the antioxidant capacity in the F1 testis was significantly inhibited by treatment with Phe during pregnancy. Those results suggested that gestational Phe exposure disordered hypothalamic-pituitary-gonadal (HPG) hormones on the one hand, and on the other hand reduced testicular antioxidant capacity and further arrested cell cycle in F1 adult male mice, which co-caused the inhibition of spermatogenesis.

Synchronous Fluorescence Spectrometry (SFS) with Multivariate Calibration for the Determination of Polycyclic Aromatic Hydrocarbons (PAHs) and Their Oxygen Analogs in Printer Toner

Synchronous molecular fluorescence with multivariate calibration was investigated to assay seven polycyclic aromatic hydrocarbons (PAHs) and three oxygenated derivatives (O-PAHs) in printer toner. Great sensitivity and a good data compression capacity were achieved; therefore, a relatively small number of factors were used. Correlation coefficients above 0.95 for the calibration functions were obtained, and recoveries lie between 70 and 130% in analyzing synthetic samples (13 PCs). For the real samples assayed, recoveries between 81 and 125% were obtained when compared to the results obtained by gas chromatography – tandem mass spectrometry (GC-MS/MS). Despite a certain loss in accuracy when compared to chromatography, the proposed methodology is faster, simpler, and lower in cost. The multivariate tool proved to be an expeditious alternative for screening toner in relation to the presence and abundance of PAHs and derivatives.

Preferential association of PBDEs and PAHs with mineral particles vs. dissolved organic carbon: Implications for groundwater contamination at e-waste sites

Preferential association of PBDEs and PAHs with mineral particles vs. dissolved organic carbon: Implications for groundwater contamination at e-waste sites

Marine Microbiota Responses to Shipping Scrubber Effluent Assessed at Community Structure and Function Endpoints.

The use of novel high-throughput sequencing (HTS) technologies to examine the responses of natural multidomain microbial communities to scrubber effluent discharges to the marine environment is still limited. Thus, we applied metabarcoding sequencing targeting the planktonic unicellular eukaryotic and prokaryotic fraction (phytoplankton, bacterioplankton, and protozooplankton) in mesocosm experiments with natural microbial communities from a polluted and an unpolluted site. Furthermore, metagenomic analysis revealed changes in the taxonomic and functional dominance of multidomain marine microbial communities after scrubber effluent additions. The results indicated a clear shift in the microbial communities after such additions, which favored bacterial taxa with known oil and polycyclic aromatic hydrocarbons (PAHs) biodegradation capacities. These bacteria exhibited high connectedness with planktonic unicellular eukaryotes employing variable trophic strategies, suggesting that environmentally relevant bacteria can influence eukaryotic community structure. Furthermore, Clusters of Orthologous Genes associated with pathways of PAHs and monocyclic hydrocarbon degradation increased in numbers at treatments with high scrubber effluent additions acutely. These genes are known to express enzymes acting at various substrates including PAHs. These indications, in combination with the abrupt decrease in the most abundant PAHs in the scrubber effluent below the limit of detection-much faster than their known half-lives-could point toward a bacterioplankton-initiated rapid ultimate biodegradation of the most abundant toxic contaminants of the scrubber effluent. The implementation of HTS could be a valuable tool to develop multilevel biodiversity indicators of the scrubber effluent impacts on the marine environment, which could lead to improved impact assessment. Environ Toxicol Chem 2024;43:1012-1029. © 2024 The Authors. Environmental Toxicology and Chemistry published by Wiley Periodicals LLC on behalf of SETAC.

Unraveling the atmospheric oxidation mechanism and kinetics of naphthalene: Insights from theoretical exploration

Naphthalene, the most abundant polycyclic aromatic hydrocarbon in the atmosphere, significantly influences OH consumption and secondary organic aerosol (SOA) formation. Naphthoquinone (NQ) is a significant contributor to ring-retaining SOA from naphthalene degradation, impacting the redox properties and toxicity of ambient particles. However, inconsistencies persist regarding concentrations of its isomers, 1,2-NQ and 1,4-NQ. In present work, our theoretical investigation into naphthalene's reaction with OH and subsequent oxygenation unveils their role in SOA formation. The reaction kinetics of initial OH and subsequent O2 oxidation was extensively studied using high-level quantum chemical methods (DLPNO-CCSD(T)/aug-ccpVQZ//M052x-D3/6-311++G(d,p)) combined with RRKM/master equation simulations. The reactions mainly proceed through electrophilic addition and abstraction from the aromatic ring. The total rate coefficient of naphthalene+OH at 300K and 1atm from our calculation (7.2×10-12cm3 molecule-1s-1) agrees well with previous measurements (∼1×10-11cm3 molecule-1s-1). The computed branching ratios facilitate accurate product yield determination. The largest yield of 1-hydroxynaphthalen-1-yl radical (add1) producing the major precursor of RO2 is computed to be 93.8 % in the ambient environment. Our calculated total rate coefficient (5.2×10-16cm3 molecule-1 s-1) for add1+O2 closely matches that of limited experimental data (8.0×10-16cm3 molecule-1 s-1). Peroxy radicals (RO2) generated from add1+O2 include 4-cis/trans-(1-hydroxynaphthalen-1-yl)-peroxy radical (add1-4OOadd-cis/trans, 66.0 %/17.5 %), 2-cis/trans-(1-hydroxynaphthalen-1-yl)-peroxy radical (add1-2OOadd-cis/trans, 10.3 %/6.3 %). Regarding the debated predominance of 1,4-NQ (corresponding to the parent RO2, i.e., add1-4OOadd-cis/trans) and 1,2-NQ (corresponding to the parent RO2, i.e., add1-2OOadd-cis/trans) in the atmosphere, our findings substantiate the dominance of 1,4-NQ. This study also indicates potential weakening of 1,4-NQ's dominance due to competition from decomposition reactions of add1-4OOadd-cis/trans and add1-2OOadd-cis/trans. Precise reaction kinetics data are essential for characterizing SOA transformation derived from naphthalene and assessing their climatic impacts within modeling frameworks.

Characterisation of polycyclic aromatic hydrocarbons associated with indoor PM0.1 and PM2.5 in Hanoi and implications for health risks

Polycyclic aromatic hydrocarbons (PAHs) associated with indoor PM pose a high risk to human health because of their toxicity. A total of 160 daily samples of indoor PM2.5 and PM0.1 were collected in Hanoi and analysed for 15 PAHs. In general, the concentrations of carcinogenic PAHs (car-PAHs) accounted for 21%±2%, 19.1%±2%, and 26%±3% of the concentrations of 15 PAHs in PM2.5, PM0.1-2.5, and PM0.1, respectively. Higher percentages of car-PAHs were found in smaller fractions (PM0.1), which can be easily deposited deep in the pulmonary regions of the human respiratory tract. The concentrations of 15 PAHs were higher in winter than in summer. The most abundant PAH species were naphthalene and phenanthrene, accounting for 11%-21% and 19%-23%, respectively. The PAH content in PM0.1 was almost twice as high as those in PM2.5 and PM0.1-2.5. Principal component analysis found that vehicle emissions and the combustion of biomass and coal were the main outdoor sources of PAHs, whereas indoor sources included cooking activities, the combustion of incense, scented candles, and domestic uses in houses. According to the results, 60%-90% of the PM0.1-bound BaP(eq) was deposited in the alveoli region, whereas 63%-75% of the PM2.5-bound BaP(eq) was deposited in head airways (HA), implying that most of the particles deposited in the HA region were PM0.1-2.5. The contributions of dibenz[a,h]anthracene and benzo[a]pyrene were dominant and contributed from 36% to 51% and 31%-50%, respectively, to the carcinogenic potential, whereas benzo[a]pyrene contributed from 30% to 49% to the mutagenic potential for both size fractions. The incremental lifetime cancer risk, simulated by Monte Carlo simulation, was within the limits set by the US EPA, indicating an acceptable risk for the occupants. These results provide an additional scientific basis for protecting human health from exposure to indoor PAHs.

Polycyclic aromatic hydrocarbons in tropical Australian stalagmites: a framework for reconstructing paleofire activity

Polycyclic aromatic hydrocarbons in tropical Australian stalagmites: a framework for reconstructing paleofire activity

Microplastics reduced bioavailability and altered toxicity of phenanthrene to maize (Zea mays L.) through modulating rhizosphere microbial community and maize growth

Due to its large specific surface area and great hydrophobicity, microplastics can adsorb polycyclic aromatic hydrocarbons (PAHs), affecting the bioavailability and the toxicity of PAHs to plants. This study aimed to evaluate the effects of D550 and D250 (with diameters of 550μm and 250μm) microplastics on phenanthrene (PHE) removal from soil and PHE accumulation in maize (Zea mays L.). Moreover, the effects of microplastics on rhizosphere microbial community of maize grown in PHE-contaminated soil would also be determined. The results showed that D550 and D250 microplastics decreased the removal of PHE from soil by 6.5% and 2.7% and significantly reduced the accumulation of PHE in maize leaves by 64.9% and 88.5%. Interestingly, D550 microplastics promoted the growth of maize and enhanced the activities of soil protease and alkaline phosphatase, while D250 microplastics significantly inhibited the growth of maize and decreased the activities of soil invertase, alkaline phosphatase and catalase, in comparison with PHE treatment. In addition, microplastics changed the rhizosphere soil microbial community and reduced the relative abundance of PAHs degrading bacteria (Pseudomonas, Massilia, Proteobacteria), which might further inhibit the removal of PHE from soil. This study provided a new perspective for evaluating the role of microplastics on the bioavailability of PHE to plants and revealing the combined toxicity of microplastics and PHE to soil microcosm and plant growth.

Fried v2: a new grid of mass-loss rates for externally irradiated protoplanetary discs

ABSTRACT We present a new fried grid of mass-loss rates for externally far-ultraviolet (FUV) irradiated protoplanetary discs. As a precursor to the new grid, we also explore the microphysics of external photoevaporation, determining the impact of polycyclic aromatic hydrocarbon (PAH) abundance, metallicity, coolant depletion (via freeze out and radial drift), and grain growth (depletion of small dust in the outer disc) on disc mass-loss rates. We find that metallicity variations typically have a small effect on the mass-loss rate, since the impact of changes in heating, cooling and optical depth to the disc approximately cancel out. The new fried grid therefore focuses on (i) expanding the basic physical parameter space (disc mass, radius, UV field, stellar mass), (ii) on enabling variation of the the PAH abundance, and (iii) including an option for grain growth to have occurred or not in the disc. What we suggest is the fiducial model is comparable to the original fried grid. When the PAH-to-dust ratio is lower, or the dust in the wind more abundant, the mass-loss rate can be substantially lower. We demonstrate with a small set of illustrative disc evolutionary calculations that this in turn can have a significant impact on the disc mass/radius/ evolution and lifetime.

Insights into ecotoxicity effects of PAHs and ecosystem responses of remediation strategies under cold stress: From PAHs degradation to ecological restoration regulated by signal molecular

Insights into ecotoxicity effects of PAHs and ecosystem responses of remediation strategies under cold stress: From PAHs degradation to ecological restoration regulated by signal molecular

Spatial distribution, source identification and flux estimation of polycyclic aromatic hydrocarbons and organochlorine pesticides in basins of the Eastern Indian Ocean

Although polycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCPs) have been recorded worldwide, information on their presence in the Eastern Indian Ocean (EIO), especially south of 10°S, remains limited. We investigated the distribution and depositional fluxes of PAHs and OCPs, and the major sources and ecological risks of PAHs in EIO surface sediments from the Central Indian Ocean (CIOB) and Wharton Basin (WB). The concentration of Σ18 PAHs and ∑10 OCPs had an average value (± SD) of 138.4 ± 52.34 and 0.8 ± 0.20 ng g-1, respectively. PAHs may mainly affected by traffic emission and biomass and wood combustion. Persistent organic pollutant accumulation rate (PAR) and depositional flux (DF) values showed that abundant PAHs might lost during top-down transport. The low trans- chordane (CHL)/cis-CHL ratio and PAR of OCPs may indicated few OCPs were inputted into the EIO recently. The results of binary isotope mixing modeling indicate the predominance of marine organic matter (MOM) in total organic carbon (TOC) of sediments. Fluoranthene (Flour) and pyrene (Py) might have potential biological effects in the EIO. The study provided background values for PAHs and OCPs in the Indian Ocean, and preliminarily revealed the fate of POPs in the open oceans.

Trophodynamics and bioaccumulation of polycyclic aromatic hydrocarbons (PAHs) in marine food web from Laizhou Bay, China

Here, we collected 16 species (n=298) from Laizhou Bay, China to investigate the trophodynamics, bioaccumulation and cancer risks of polycyclic aromatic hydrocarbons (PAHs). Results demonstrated that naphthalene was the most abundant PAH, followed by phenanthrene and fluorene in the marine organisms. The sum of 16 PAHs concentrations (Ʃ16PAHs) ranked with algae (19,435ng·g-1 lipid weight, lw)>benthonic animals (6599ng·g-1 lw)>fish (1760ng·g-1 lw). Combustion and oil spill are two primary sources, contributing 60.3% and 39.7% of Ʃ16PAHs, respectively. High values of log BAF were found for 4-6 rings PAHs. Algae and benthonic animals showed a high ability to accumulate 2-4 rings PAHs and 5-6 rings PAHs, respectively. A biodilution pattern for PAHs was found in the marine food web. The carcinogenic risks of some benthos and fish were higher than 1×10-6, threatening resident health by consumption of these seafoods.

Shock excitation of H2 in the James Webb Space Telescope era

Context. Molecular hydrogen, H2, is the most abundant molecule in the Universe. Thanks to its widely spaced energy levels, it predominantly lights up in warm gas, T ≳ 102 K, such as shocked regions externally irradiated or not by interstellar UV photons, and it is one of the prime targets of James Webb Space Telescope (JWST) observations. These may include shocks from protostellar outflows, supernova remnants impinging on molecular clouds, all the way up to starburst galaxies and active galactic nuclei. Aims. Sophisticated shock models are able to simulate H2 emission from such shocked regions. We aim to explore H2 excitation using shock models, and to test over which parameter space distinct signatures are produced in H2 emission. Methods. We here present simulated H2 emission using the Paris-Durham shock code over an extensive grid of ~14 000 plane-parallel stationary shock models, a large subset of which are exposed to a semi-isotropic external UV radiation field. The grid samples six input parameters: the preshock density, shock velocity, transverse magnetic field strength, UV radiation field strength, the cosmic-ray-ionization rate, and the abundance of polycyclic aromatic hydrocarbons, PAHs. Physical quantities resulting from our self-consistent calculations, such as temperature, density, and width, have been extracted along with H2 integrated line intensities. These simulations and results are publicly available on the Interstellar Medium Services platform. Results. The strength of the transverse magnetic field, as quantified by the magnetic scaling factor, b, plays a key role in the excitation of H2. At low values of b (≲0.3, J-type shocks), H2 excitation is dominated by vibrationally excited lines; whereas, at higher values (b ≳ 1, C-type shocks), rotational lines dominate the spectrum for shocks with an external radiation field comparable to (or lower than) the solar neighborhood. Shocks with b ≥ 1 can potentially be spatially resolved with JWST for nearby objects. H2 is typically the dominant coolant at lower densities (≲104 cm−3); at higher densities, other molecules such as CO, OH, and H2O take over at velocities ≲20 km s−1 and atoms, for example, H, O, and S, dominate at higher velocities. Together, the velocity and density set the input kinetic energy flux. When this increases, the excitation and integrated intensity of H2 increases similarly. An external UV field mainly serves to increase the excitation, particularly for shocks where the input radiation energy is comparable to the input kinetic energy flux. These results provide an overview of the energetic reprocessing of input kinetic energy flux and the resulting H2 line emission.