Abundant Hydrocarbon Research Articles

A complete structural analysis of the FⅠ17 strike-slip fault and its hydrocarbon enrichment factors, Tarim basin, NW China

The FⅠ17 fault is a prominent strike-slip fault in the central Tarim basin, notable for its hydrocarbon abundance and intricate tectonic attributes, characterized by several deflections in its planar trajectory. Analyzing the FⅠ17 fault offers crucial insights into the role of basement structures on the evolution and formation of intracratonic strike-slip fault systems. This study utilizes the latest seismic data and integrating the foundation of previous research to conduct a detailed investigation into the spatial distribution, deformation intensity, activity phases, and formation mechanisms of the fault. The fault can be divided into three structural layers based on deformation features. The deep layer, situated beneath the TЄ3 interface (the bottom of the Upper Cambrian), shows basement rifts and weak strike-slip activity. The middle layer, spanning from TЄ3 to TO3 (the bottom of the Upper Ordovician), exhibits pronounced deformation with flower-like structures. The upper layer, extending from the TO3 to TP (the bottom of the Permian), is marked by three groups of en-echelon normal faults. Controlled by Precambrian basement heterogeneity, the fault evolved through three stages: weak compressive stress during the Middle -Late Cambrian led to rupture along basement rifts and weak zones that formed the fault’s embryonic shape; strong compressive stress from Middle-Late Ordovician activated and propagated the fault upwards; during the Silurian-Carboniferous, the fault experienced episodic reactivation and result in the emergence of en-echelon normal faults. Hydrocarbon enrichment at the FⅠ17 fault is influenced by source rock distribution, reservoir characteristics, and fault reactivation. Its positioning above the source rock center ensures an ample supply of hydrocarbon. The intense fault activity has created favorable conditions for large-scale fracture-cavity reservoir development, and the reactivation period corresponds with the hydrocarbon accumulation phase, significantly boosts hydrocarbon charging.

Photoinduced Regiodivergent and Enantioselective Cross-Coupling of Glycine Derivatives with Hydrocarbon Feedstocks.

Regiodivergent asymmetric synthesis represents a transformative strategy for the efficient generation of structurally diverse chiral products from a single set of starting materials, significantly enriching their enantiomeric composition. However, the design of radical-mediated regiodivergent and enantioselective reactions that can accommodate a wide range of functional groups and substrates has posed significant challenges. The obstacles primarily lie in switching the regioselectivity and achieving high enantiodiscrimination, especially when dealing with high-energy intermediates. To address these issues, we have developed a new catalytic system that integrates photoinduced hydrogen atom transfer (HAT) and chiral copper catalysis, involving the fine-tuning of chiral ligands, additives, and other reaction parameters. The strategy facilitates regiodivergent and enantioselective cross-couplings between N-aryl glycine ester/amide derivatives and abundant hydrocarbon feedstocks through strong C(sp3)-H bond activation. This approach allows for the controlled and stereoselective formation of C(sp3)-C(sp3) and C(sp3)-N bonds, yielding a rich variety of C- or N-alkylated glycine esters and amides with commendable yields (up to 92% yield), exclusive regioselectivities (typically >20:1 rr), and high enantioselectivities (up to 96% ee). Our methodology not only provides a promising avenue for the stereoselective incorporation of alkyl functionalities onto specific sites of biologically significant molecules but also offers a practical approach for regioselectivity switching while simultaneously achieving high asymmetric induction within photochemical reactions.

A new division of late Cretaceous Erlian Basin tectonic units based on differential basement characteristics

The Erlian Basin, a significant continental sedimentary basin in northeastern China, is renowned for its abundant hydrocarbon resources. Extensive research has been conducted on its sedimentary sequences, hydrocarbon accumulation, and geodynamic background. However, previous tectonic units classifications of the Erlian Basin predominantly reflect its post-Cenozoic tectonic framework, neglecting the Early Cretaceous period. This oversight fails to explain recent petroleum discoveries in the Wulanhua area of the Ondor Sum Uplift. In this study, geological, well log, seismic, gravity, and magnetic data, along with large, deep fault distributions and the regional geology of the Erlian Basin, were utilized to analyze its basement characteristics and propose a new tectonic division. Our findings reveal that the Erlian Basin's basement exhibits composite characteristics, resulting in a north-south zonation of basin depressions. Consequently, the basin's tectonic units were divided into northern, central, and southern depressions, delineated by two major deep faults: Xilinhot and Chifeng–Kaiyuan. This revised tectonic division clarifies the Early Cretaceous tectonic framework, enhances the basin's hydrocarbon exploration potential, and will guide future exploration efforts. Our study identifies nine favorable sags within the Erlian Basin with significant hydrocarbon potential.

Evaluation of the growth, lipid, and hydrocarbon accumulation abilities in five strains of Botryococcus braunii (races A, B, and L) (Trebouxiophyceae, Chlorophyta)

The green alga Botryococcus braunii can photosynthetically fix CO2 and accumulate abundant hydrocarbons, which has driven interest in this species as a sustainable biofuel. In this study, five strains of B. braunii (SAG 807-1, SAG 2532, SAG 30.81, SC-1, and SC-2) were identified based on the nucleotide sequence of 18S rDNA, of which SC-1 and SC-2 were isolated from the water bodies of southern China by our laboratory. Then, the effects of different media and initial nitrogen concentrations on the growth, total lipid contents, fatty acid profiles, and hydrocarbon compositions in these five strains were compared. Molecular identification revealed that B. braunii SC-1 and SC-2 belong to races B and L, respectively, while SAG 807-1, SAG 2532, and SAG 30.81 belong to race A. Compared with mBBM and mEndo media, SAG 807-1, SAG 2532, SC-1, and SC-2 grew faster in mBG-11 media. The highest total lipid content of SAG 807–1, SAG 30.81, and SC-1 reached >45 % of cell dry weight (DW), with the maximum total lipid content of SC-2 reaching 66.52 % of DW. The major fatty acid components of the five strains of B. braunii were palmitic acid (C16:0), oleic acid (C18:1), and erucic acid (C22:1). The maximum hydrocarbon content was 22.13 % DW in B. braunii SC-1, of which 1.4 % DW was squalene. Squalene is widely used as an antioxidant and as an adjuvant in vaccines.

Application of FLAIR technology in evaluation of complex fluids—Taking M structure of Huizhou sag as an example

Abstract Due to the complexity of reservoir fluid types and the difficulty in identifying hydrocarbon abundance in M structure of the Huizhou sag, the conventional gas logging methods are affected by instrument accuracy, resulting in indistrument difference in gas logging response characteristics. Consequently, the traditional evaluation methoda are inadequate.To address these challenges, fluid logging & analysis in real time technology(FLAIR) is applied. This technology quantifies various gas components by detecting the ion mass, offering advantages such as precise detection and wide measurement range.In this paper,the data of FLAIR technology was analyzed. Based on the differences in hydrocarbon components of various fluids, fluid identification charts were developed using the hydrocarbon component ratio, humidity ratio (WH) and equilibrium ratio (BH) parameters, which could effectively distinguish complex fluids such as gas, condensate, oil and volatile oil formations.The oil index and gas index were selected, and the gas-oil ratio index was formulated. A relationship model between this parameter and the gas-oil ratio data, measured through cable sampling and formation testing was established, enabling the prediction of gas-oil ratio data during drilling. By correcting gas data to reduce the influence of factors such as drilling time, displacement volume and bit size through gas data correction, the evaluation chart of oil and gas abundance, based on the anomaly ratio of gas measurement can adress the evaluation challenges of buried hill reservoir. The aforementioned method provides robust technical support for reservoir fluid identification and evaluation in M structure of Huizhou sag, and has significant application value in complex reservoirs and complex fluid conditions.

Egyptian aquaponic celery (Apium graveolens): Phenolic and volatile profiles analysed using HPLC-MS/ms and gc-ms/ms

Recently, water scarcity has been a substantial problem facing agriculture in Egypt, with a great impact on food security and hence makes it a challenge to satisfy food demand. An aquaponic system with minimum water needs is considered a substitute technique to meet the demand of food shortages. Celery (Apium graveolens) is a widely cultivated herb belonging to the family Apiaceae and widely consumed as a popular ingredient in a wide range of dishes and food recipes. A total of 13 phenolic metabolites were detected and quantified using HPLC-ESI-MS/MS. Chlorogenic acid was detected as the most abundant phenolic compound accounting for 3471.58 mg kg−1. Moreover, 65 volatile compounds belonging to 12 different classes were detected using GS-MS with an abundance of aromatic hydrocarbons at ca.68.15%. and the main constituents were 6-phenyltridecane, 6-phenyldodecane, and 5-phenylundecane at ca.6.78%, 6.62%, and 6.13% respectively. It is the first time to report metabolic profile in celery grown in an aquaponic system.

Infrared Spectrum of the Adduct 2-Chloro-2-hydroperoxybut-3-ene [(C2H3)CCl(CH3)OOH] of the Reaction between the Criegee Intermediate Methyl Vinyl Ketone Oxide [C2H3C(CH3)OO] and HCl.

Methyl vinyl ketone oxide (MVKO, C2H3C(CH3)OO) is an important Criegee intermediate produced from ozonolysis of isoprene, which is the most abundant nonmethane hydrocarbon emitted into the atmosphere. Reactions between Criegee intermediate and hydrogen chloride (HCl) are important because of their large rate coefficients. In this work, we photolyzed a mixture of (Z)-(CH2I)HC═C(CH3)I/HCl/O2 at 248 nm to produce MVKO to carry out the reaction MVKO + HCl and recorded infrared spectra of transient species with a step-scan Fourier-transform infrared absorption spectrometer. Eleven bands near 1415, 1381, 1350, 1249, 1178, 1118, 1103, 1065, 978, 931, and 895 cm-1 were observed and assigned to the hydrogen-transferred adduct (C2H3)CCl(CH3)OOH (2-chloro-2-hydroperoxybut-3-ene, CHPB) according to the predicted IR spectrum using the B3LYP/aug-cc-pVTZ method; the conformation could not be definitively determined. According to calculations, most low-energy conformers can interconvert, and the most stable conformers anti-trans-CHPB and syn-trans-CHPB might have the major contributions. Four bands near 1423, 1360, 1220, and 1080 cm-1 were observed and tentatively assigned to the OH-decomposition products (C2H3)CCl(CH3)O (1-chloro-1-methyl-2-propenyloxy, CMP); both trans-CMP and cis-CMP might contribute. Unlike in the case of CH2OO + HCl and CH3CHOO + HCl, in which secondary reactions of the OH-decomposition products reacted readily with O2 to produce the dehydrated products HC(O)Cl and CH3C(O)Cl, respectively, the secondary reaction of CMP with O2 was not observed because there is no feasible H atom in CMP for O2 to abstract.

Tracking the coupling conversion of C1-C4 aldehydes with methanol-to-hydrocarbon reaction

Small-molecule aldehydes are promising additives to regulate product distribution in methanol-to-hydrocarbon (MTH) reaction. Herein, the co-feeding of C1-C4 aldehydes with methanol resulted in a significant increase in aromatic formation with the order: acetaldehyde > formaldehyde > propanal ≈ butanal. The mechanistic basis for this enhancement in aromatic production derived from both a direct participation pathway of aldehydes and an indirect pathway via driving the aromatic-based cycle. C2+ aldehydes could undergo multiple aldol-condensation on Brønsted acid sites to form larger alkenals, followed by sequential cyclization-dehydration reaction to cycloalkenes or aromatic species. The Prins reaction could be extended to all C1-C4 aldehydes with alkenes by generating the corresponding dienes. The hydrogen transfer from methanol to C2+ aldehydes produced C2+ olefins and formaldehyde, which would lead to extra formaldehyde-mediated aromatic formation pathway. The intricate evolution pathway of C1-C4 aldehydes in MTH reaction was constructed by detecting abundant oxygenate and hydrocarbon intermediates.

Space-based observations of tropospheric ethane map emissions from fossil fuel extraction

Ethane is the most abundant non-methane hydrocarbon in the troposphere, where it impacts ozone and reactive nitrogen and is a key tracer used for partitioning emitted methane between anthropogenic and natural sources. However, quantification has been challenged by sparse observations. Here, we present a satellite-based measurement of tropospheric ethane and demonstrate its utility for fossil-fuel source quantification. An ethane spectral signal is detectable from space in Cross-track Infrared Sounder (CrIS) radiances, revealing ethane signatures associated with fires and fossil fuel production. We use machine-learning to convert these signals to ethane abundances and validate the results against surface observations (R2 = 0.66, mean CrIS/surface ratio: 0.65). The CrIS data show that the Permian Basin in Texas and New Mexico exhibits the largest persistent ethane enhancements on the planet, with regional emissions underestimated by seven-fold. Correcting this underestimate reveals Permian ethane emissions that represent at least 4-7% of the global fossil-fuel ethane source.

The enhanced degradation of trichloroethylene in the bioelectrochemical system integrated with iron‑carbon micro-electrolysis

Trichloroethylene (TCE) is one of the most abundant volatile chlorinated hydrocarbons in groundwater which threatens human health and the environment. Utilizing a bioelectrochemical system (BES) to treat TCE is a promising strategy; however, as the ionic strength of the groundwater is low and the extracellular electron transfer of BES is limited, BES degradation of TCE is impeded. In this research, iron and graphite were added to the cathode chamber to form a micro-electrolysis to enhance the degradation of TCE synergistically. The results showed that when the iron and carbon mixture dosage was 70 g/L with the mass ratio (Fe/C) of 1:2 and the initial TCE concentration of 100 mg/L, the degradation efficiency of BES reached 97.8 % at the cathodic potential of −0.3 V (vs.SHE). This was 1.31 times, 1.94 times, and 2.74 times that of Fe/C + open-circuit BES, Fe/C micro-electrolysis, and conventional BES without Fe/C, respectively, which implied that iron‑carbon mediated BES colligated the advantages of microbial degradation and micro-electrolysis, and iron‑carbon provided more electrons and accelerated electron transfer to improve the degradation of TCE significantly. Moreover, through the analysis of the microorganisms of Fe/C + BES, the highest abundances of microorganisms at phylum, class, and genus levels were Proteobacteria, Alphaproteobacteria, and Acetobacterium, respectively. By comparing Fe/C + BES with conventional BES, the addition of iron‑carbon enhanced the microbial diversity and species richness and improved the abundances of Pseudomonas and Geobacter at the genus level. In all, iron‑carbon micro-electrolysis can be integrated with BES to treat TCE and facilitate BES application in the volatile chlorinated hydrocarbon-contaminated sites.

Synergistic Toxicity of Pollutant and Ultraviolet Exposure from a Mitochondrial Perspective.

Ultraviolet (UV) exposure and atmospheric pollution are both independently implicated in skin diseases such as cancer and premature aging. UVA wavelengths, which penetrate in the deep layers of the skin dermis, exert their toxicity mainly through chromophore photosensitization reactions. Benzo[a]pyrene (BaP), the most abundant polycyclic aromatic hydrocarbon originating from the incomplete combustion of organic matter, could act as a chromophore and absorb UVA. We and other groups have previously shown that BaP and UVA synergize their toxicity in skin cells, which leads to important oxidation. Even if mitochondria alterations have been related to premature skin aging and other skin disorders, no studies have focused on the synergy between UV exposure and pollution on mitochondria. Our study aims to investigate the combined effect of UVA and BaP specifically on mitochondria in order to assess the effect on mitochondrial membranes and the consequences on mitochondrial activity. We show that BaP has a strong affinity for mitochondria and that this affinity leads to an important induction of lipid peroxidation and membrane disruption when exposed to UVA. Co-exposure to UVA and BaP synergizes their toxicity to negatively impact mitochondrial membrane potential, mitochondrial metabolism and the mitochondrial network. Altogether, our results highlight the implication of mitochondria in the synergistic toxicity of pollution and UV exposure and the potential of this toxicity on skin integrity.

Characterization of a new Teflon chamber and on-line analysis of isomeric multifunctional photooxidation products

Abstract. The photooxidation of volatile organic compounds (VOCs) in the troposphere has important implications for air quality, weather, and climate. A deeper understanding of the underlying mechanisms can be achieved by studying these reactions under controlled conditions and analysing the emerging photooxidation products. This requires dedicated laboratory infrastructure as well as sensitive and selective analytical techniques. Here, we constructed a new 300 L indoor Teflon atmospheric simulation chamber as part of the Bayreuth ATmospheric simulation CHambers (BATCH) infrastructure. The chamber was irradiated by a bandpass-filtered solar simulator that enabled experiments with realistic photon fluxes and OH radical concentrations. It was coupled to a proton-transfer-reaction time-of-flight mass spectrometer (PTR-ToF-MS) and a solid-phase microextraction–gas chromatography–mass spectrometry (SPME-GC-MS) system for the on-line analysis of the precursor VOC and its oxidation products in the gas phase. As part of the SPME-GC-MS method, multifunctional oxygenated compounds (carbonyls, alcohols, carboxylic acids) were derivatized with O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine (PFBHA) and N-trimethylsilyl-N-methyltrifluoroacetamide (MSTFA). We designed a permeation source for the on-line addition of internal standards to improve method reproducibility. The joint setup was tested and validated by studying the OH-radical-induced photooxidation of toluene, one of the most abundant aromatic hydrocarbons in the atmosphere. For chamber characterization, we first derived the photolysis rates for several typical toluene products in the irradiated BATCH Teflon chamber (1.77 × 10−8–3.02 × 10−4 s−1). Additionally, wall loss rates were determined empirically (4.54 × 10−6–8.53 × 10−5 s−1) and then parameterized according to fundamental molecular properties. For the cresols, we compiled a weighted calibration factor for the PTR-ToF-MS, taking into account isomer-specific sensitivities as well as the relative distribution as determined by the SPME-GC-MS. The weighted calibration improved the instrumental agreement to 14 %, whereas the PTR-ToF-MS overestimated the sum of the isomers by 31 % compared to the SPME-GC-MS concentrations when using the averaged calibration factor. Thus, the combined data set offered insight into both temporal trends and the isomeric composition. Finally, we conducted six toluene photooxidation experiments to evaluate the ring-retaining first-generation products. Based on the loss-corrected concentrations, we derived formation yields for o-cresol (8.0 ± 1.8 %), m-cresol (0.4 ± 0.1 %), p-cresol (2.4 ± 0.6 %), benzyl alcohol (0.5 ± 0.1 %), and benzaldehyde (4.6 ± 1.7 %) under NOx-free conditions at T = 298 ± 1 K. These yields are consistent with previous studies and therefore serve as proof of concept for our applied methods.

Demineralization activating highly-disordered lignite-derived hard carbon for fast sodium storage

Lignite, as one of the coal materials, has been considered a promising precursor for hard carbon anodes in sodium-ion batteries (SIBs) owing to its low cost and high carbon yield. Nevertheless, hard carbon directly derived from lignite pyrolysis typically exhibits highly ordered microstructure with narrow interlayer spacing and relatively unreactive interfacial properties, owing to the abundance of polycyclic aromatic hydrocarbons and inert aromatic rings within its molecular composition. Herein, an innovative demineralization activating strategy is established to simultaneously modulate the interfacial properties and the microstructure of lignite-derived carbon for the development of high-performance SIBs. Demineralization process not only creates numerous void spaces in the matrix of lignite precursor to assist aromatic hydrocarbon rearrangement, thereby reducing the ordering and expanding interlayer spacing, but also exposes more interfacial oxygen-containing functional groups to effectively increasing the sodium storage active sites. As a result, the optimal demineralized lignite-derived hard carbon (DLHC 1300) delivers a high reversible capacity of 335.6 mAh g−1 at 30 mA g−1, superior rate performance of 246.3 mAh g−1 at 6 A g−1 and nearly 100 % capacity retention after 1100 cycles at 1A g−1. Furthermore, the optimized DLHC 1300 material functions as an outstanding anode in sodium ion full cells. This work significantly advances the development of low-cost, high-performance commercial hard carbon anodes for SIBs.

Nitrite-driven anaerobic ethane oxidation

Ethane, the second most abundant gaseous hydrocarbon in vast anoxic environments, is an overlooked greenhouse gas. Microbial anaerobic oxidation of ethane can be driven by available electron acceptors such as sulfate and nitrate. However, despite nitrite being a more thermodynamically feasible electron acceptor than sulfate or nitrate, little is known about nitrite-driven anaerobic ethane oxidation. In this study, a microbial culture capable of nitrite-driven anaerobic ethane oxidation was enriched through the long-term operation of a nitrite-and-ethane-fed bioreactor. During continuous operation, the nitrite removal rate and the theoretical ethane oxidation rate remained stable at approximately 25.0 mg NO2–N L−1 d−1 and 11.48 mg C2H6 L−1 d−1, respectively. Batch tests demonstrated that ethane is essential for nitrite removal in this microbial culture. Metabolic function analysis revealed that a species affiliated with a novel genus within the family Rhodocyclaceae, designated as 'Candidatus Alkanivoras nitrosoreducens', may perform the nitrite-driven anaerobic ethane oxidation. In the proposed metabolic model, despite the absence of known genes for ethane conversion to ethyl-succinate and succinate-CoA ligase, 'Ca. A. nitrosoreducens' encodes a prospective fumarate addition pathway for anaerobic ethane oxidation and a complete denitrification pathway for nitrite reduction to nitrogen. These findings advance our understanding of nitrite-driven anaerobic ethane oxidation, highlighting the previously overlooked impact of anaerobic ethane oxidation in natural ecosystems.

Selective C-H Bond Activation in Propane with Molecular Oxygen over Cu(I)-ZSM-5 at Ambient Conditions.

Selective activation of C-H bonds in light alkanes under mild conditions is challenging but holds the promise of efficient upgrading of abundant hydrocarbons. In this work, we report the conversion of propane to propylene with ∼95% selectivity on Cu(I)-ZSM-5 with O2 at room temperature and pressure. The intraporous Cu(I) species was oxidized to Cu(II) during the reaction but could be regenerated with H2 at 220 °C. Diffuse reflectance ultraviolet spectroscopy indicated the presence of both Cu+-O2 and Cu2(μ-O2)2+ species in the zeolite pores during the reaction, and electron paramagnetic resonance results showed that propane activation occurred via a radical-mediated pathway distinct from that with H2O2 as the oxidant. Correlation between spectroscopic and reactivity results on Cu(I)-ZSM-5 with different Cu loadings suggests that the isolated intraporous Cu(I) species is the main active species in propane activation.

Abundant hydrocarbons in the disk around a very-low-mass star

Very-low-mass stars (those less than 0.3 solar masses) host orbiting terrestrial planets more frequently than other types of stars. The compositions of those planets are largely unknown but are expected to relate to the protoplanetary disk in which they form. We used James Webb Space Telescope mid-infrared spectroscopy to investigate the chemical composition of the planet-forming disk around ISO-ChaI 147, a 0.11-solar-mass star. The inner disk has a carbon-rich chemistry; we identified emission from 13 carbon-bearing molecules, including ethane and benzene. The high column densities of hydrocarbons indicate that the observations probe deep into the disk. The high carbon-to-oxygen ratio indicates radial transport of material within the disk, which we predict would affect the bulk composition of any planets forming in the disk.

Geochemical implications of uranium-bearing thucholite aggregates in the Upper Permian Kupferschiefer shale, Lubin district, Poland

New inorganic and organic geochemical data from thucholite in the Upper Permian (Wuchiapingian) Kupferschiefer (T1) shale collected at the Polkowice-Sieroszowice Cu-Ag mine in Poland are presented. Thucholite, which forms spherical or granular clusters, appears scattered in the T1 dolomitic shale at the oxic-anoxic boundary occurring within the same shale member. The composition of thucholite concretions and the T1 shale differs by a higher content of U- and REE-enriched mineral phases within the thucholite concretions compared to the T1 shale, suggesting a different mineralising history. The differences also comprise higher Ntot, Ctot, Htot, Stot contents and higher C/N, C/S ratios in thucholite than in the T1 shale. The hydrocarbon composition of the thucholite and the surrounding T1 shale also varies. Both are dominated by polycyclic aromatic compounds and their phenyl derivatives. However, higher abundances of unsubstituted polycyclic aromatic hydrocarbons in the thucholite are indicative of its pyrogenic origin. Pyrolytic compounds such as benz[a]anthracene or benzo[a]pyrene are more typical of the thucholite than the T1 shale. Microscopic observations of the thucholite and its molecular composition suggest that it represents well-rounded small charcoal fragments. These charcoals were formed during low-temperature combustion, as confirmed by semifusinite reflectance values, indicating surface fire temperatures of about 400 °C, and the absence of the high-temperature pyrogenic polycyclic aromatic hydrocarbons. Charred detrital particles, likely the main source of insoluble organic matter in the thucholite, migrated to the sedimentary basin in the form of spherical carbonaceous particulates, which adsorbed uranium and REE in particular, which would further explain their different contents and sorption properties in the depositional environment. Finally, the difference in mineral content between thucholite and the T1 shale could also have been caused by microbes, which might have formed biofilms on mineral particles, and caused a change in the original mineral composition.

Elemental quantitation and evaluation of hydrocarbon in shale using fiber-optic laser induced breakdown spectroscopy

To meet the demands of in situ analysis, a fiber-optic laser-induced breakdown spectroscopy (FO-LIBS) system was established to predict the elemental concentrations and pyrolytic parameters. The key parameters, including pulse energy, gate delay, type of surrounding gas, and flow rate of gas, were optimized to improve the signal-to-noise ratio of the spectral lines, and the evolution characteristics of the plasma morphology in different gas atmospheres were investigated. Under the optimized experimental conditions, C, H, Si, Ca, Fe, and Mg were calibrated using pellet samples based on partial least squares regression, and the average relative prediction error of the natural samples was lower than 10%. In addition, the support vector regression method was utilized to predict pyrolytic parameters such as TOC, Pg, and Tmax with the R2 of all calibration curves being higher than 0.97. The abundance and generation potential of hydrocarbons were evaluated using the predicted TOC and Pg, and Tmax could contribute to the thermal maturity of the kerogen.

Characteristics of Jurassic Source Rocks and Evaluation of Hydrocarbon Resources in Tarim Basin, western China

Jurassic strata in Tarim are significant for their hydrocarbon-rich content. However, the distribution of hydrocarbon source rocks in this region is uneven, and the conditions for hydrocarbon accumulation vary significantly among the different structural elements. Therefore, it is essential to investigate the distribution of Jurassic source rocks, the evolution history of hydrocarbon generation, and the mechanisms influencing hydrocarbon accumulation for effective hydrocarbon exploration and development. To achieve this, seismic, geologic, drilling, logging, and testing data were integrated to analyze the distribution and quality of hydrocarbon source rocks, the evolution of hydrocarbon generation, and the factors influencing hydrocarbon accumulation in Jurassic hydrocarbon source rocks in Tarim Basin. The study revealed that the Jurassic effective hydrocarbon source rock centers are mainly located in the piedmont areas of Kuqa depression, southwest depression, and southeast depression, as well as Yingjisu sag and Manjiaer sag in the eastern Tarim area. Based on a comprehensive evaluation and comparison of the potential of Jurassic hydrocarbon potential in each secondary structural unit, it is concluded that Kuqa Depression has the most favorable exploration zone due to its excellent hydrocarbon accumulation conditions and abundant hydrocarbon resources. Although the overall exploration potential of the southwest depression is lower than that of the Kuqa depression, the hydrocarbon resources potential of the piedmont thrust belt and the associated depression is very high. Similarly, the eastern part of the Manjiaer sag and the Altun piedmont zone of the southeastern depression still have promising exploration prospects, although the overall exploration potential of the eastern Tarim area and the southeastern depression is not as good as the former two.

Maximized energy recovery by catalytic co-pyrolysis of dewatered sewage sludge and polystyrene to contribute in bio-circular economy: Synergistic compositional analysis of bio-oil and syngas through artificial neural networking

Sewage sludge and polystyrene are considered very challenging for the waste management authorities in urban centers across the globe. In the current study, catalytic co-pyrolysis of the dewatered sludge (DS) and waste polystyrene (PS) was conducted. The co-pyrolysis of DS and PS; 60% polystyrene+40% dewatered sludge was concluded as optimum ratio with 11.21% higher energy production as compared with other compositions. The produced bio-oil were investigated having higher slags/wax and lower aromatics. Therefore, ZSM-5 (3% weight basis) catalyst was employed, and it had enriched the bio-oil quality, provided higher aromatic hydrocarbon yields with reduced wax and slag formation. To understand the thermodynamic behavior of all dewatered sewage sludge and polystyrene, detailed TGA analysis was carried out. The relative abundance of the aromatic hydrocarbons was identified by GC-MS and FTIR analysis. The synergist compositional analysis of the bio-oil and syngas was carried out by using artificial neural networking techniques. The aromatic components in bio-oil were found to have positive correlations when catalyst were employed. The proposed energy recovery model had capacity of generating 20,863 KWh/d of electrical energy, dealing 10 tons/d of biowaste: and leads the societies towards cleaner environment and positive contribution to bio-circular economy.