Absolute Temperature Measurements Research Articles

Comparative study on fluorescence intensity ratio and chromatic coordinate temperature measurement using CsPbBr3-Eu3+ co-doped glass

We have fabricated CsPbBr3-Eu3+ co-doped glass for optical temperature measurement. Photoluminescence (PL) spectra, PL excitation (PLE) spectra and PL decay have been measured. The CsPbBr3 and Eu3+ show distinguishable PL spectra and different temperature dependences. Fluorescence intensity ratio (FIR) and chromatic coordinate temperature measurements are investigated. Absolute sensitivity (Sa), relative sensitivity (Sr) and temperature measurement accuracy (UT) are analyzed. For the FIR method, the Sa and Sr are better in comparison with other temperature sensing materials. The chromatic coordinate is calculated by using PL spectra. Comparing with FIR method, the chromatic coordinate method has smaller Sa and Sr, but better UT due to small uncertainty Ur(x). In addition, the chromatic coordinate method has linear temperature dependence, good compatibility and universality. Both FIR mode and chromatic coordinate mode have excellent temperature cycle characteristics..

Absolute thermometry of human brown adipose tissue by magnetic resonance with laser polarized 129Xe

BackgroundAbsolute temperature measurements of tissues inside the human body are difficult to perform non-invasively. Yet, for brown adipose tissue (BAT), these measurements would enable direct monitoring of its thermogenic activity and its association with metabolic health.MethodsHere, we report direct measurement of absolute BAT temperature in humans during cold exposure by magnetic resonance (MR) with laser polarized xenon gas. This methodology, which leverages on the sensitivity of the chemical shift of the 129Xe isotope to temperature-induced changes in fat density, is first calibrated in vitro and then tested in vivo in rodents. Finally, it is used in humans along with positron emission tomography (PET) scans with fluorine-18-fluorodeoxyglucose to detect BAT thermogenic activity during cold exposure.ResultsAbsolute temperature measurements, obtained in rodents with an experimental error of 0.5 °C, show only a median deviation of 0.12 °C against temperature measurements made using a pre-calibrated optical temperature probe. In humans, enhanced uptake of 129Xe in BAT during cold exposure leads to background-free detection of this tissue by MR. Global measurements of supraclavicular BAT temperature, made over the course of four seconds and with an experimental error ranging from a minimum of 0.4 °C to more than 2 °C, in case of poor shimming, reveal an average BAT temperature of 38.8° ± 0.8 °C, significantly higher (p < 0.02 two-sided t test) than 37.7 °C. Hot BAT is also detected in participants with a PET scan negative for BAT.ConclusionsNon-invasive, radiation-free measurements of BAT temperature by MRI with hyperpolarized 129Xe may enable longitudinal monitoring of human BAT activity under various stimulatory conditions.

High resolution seafloor thermometry for internal wave and upwelling monitoring using Distributed Acoustic Sensing

Temperature is an essential oceanographic variable (EOV) that still today remains coarsely resolved below the surface and near the seafloor. Here, we gather evidence to confirm that Distributed Acoustic Sensing (DAS) technology can convert tens of kilometer-long seafloor fiber-optic telecommunication cables into dense arrays of temperature anomaly sensors having millikelvin (mK) sensitivity, thus allowing to monitor oceanic processes such as internal waves and upwelling with unprecedented detail. Notably, we report high-resolution observations of highly coherent near-inertial and super-inertial internal waves in the NW Mediterranean sea, offshore of Toulon, France, having spatial extents of a few kilometers and producing maximum thermal anomalies of more than 5 K at maximum absolute rates of more than 1 K/h. We validate our observations with in-situ oceanographic sensors and an alternative optical fiber sensing technology. Currently, DAS only provides temperature changes estimates, however practical solutions are outlined to obtain continuous absolute temperature measurements with DAS at the seafloor. Our observations grant key advantages to DAS over established temperature sensors, showing its transformative potential for the description of seafloor temperature fluctuations over an extended range of spatial and temporal scales, as well as for the understanding of the evolution of the ocean in a broad sense (e.g. physical and ecological). Diverse ocean-oriented fields could benefit from the potential applications of this fast-developing technology.

Absolute calibration of a streaked optical pyrometer at nanosecond time scale with a luminescent concentrator

The Streaked Optical Pyrometer (SOP) is a visible diagnostic widely used to study the warm dense matter regime at high energy laser facilities, gas guns, or ion accelerators. It is usually coupled with a Velocity Interferometer System for Any Reflector (VISAR) diagnostic for simultaneous shock wave velocity, reflectivity, and temperature measurements to study the Equation of State (EOS) of materials. While VISAR is a well-mastered technology that provides velocity measurements with low relative uncertainties (close to percent), SOP diagnostics still suffer from high imprecision. In this article, we present a new calibration method in order to obtain absolute temperature measurements with reduced uncertainties. This approach is based on a novel light source: a Ce:YAG luminescent concentrator pumped by LEDs. This device produces enough optical power for calibration at the nanosecond sweep duration of the streak camera. As a demonstration, it has first been installed at the LULI facility and tested on quartz samples shocked at temperatures above 4000 K.

Postmortem assessment of the WEST Fiber Bragg grating and thermocouple diagnostic performances with HADES

Plasma facing components temperature measurement is required to ensure safe high power for long pulse tokamak operation and for physics studies. During the WEST phase 1, a set of 20 thermocouples (TC) and 4 fibers Bragg grating (FBG) have been exposed to five experimental campaigns with 3889 plasmas for a total plasma duration of about 7h15 and 21.2 GJ of cumulated injected energy. This paper presents the performances in terms of response time and high temperature sustaining assess with high heat flux tests performed in the HADES facility. The response time of the TC remains at the same level as before their installation in the divertor. However, the FBG have shown clear increase of their response time depending on the location due to a degradation of the thermal contact of the graphite adhesive and the FBG or component. Finally, one regenerated FBG has been exposed to high temperature, showing that absolute temperature measurement is found reliable up to 1100 °C with the start of some spectrum degradations. Full erasure of the grating is obtained after 10 s at 1200 °C well above the stable temperature of 900 °C of the regenerated FBG.

How to Use Fiber Optic Sensors for Accurate Absolute Measurements - INVITED

The scientific community has been exploring new concepts as a result of the usage of optical fibers as absolute measurement sensors. While cross-sensitivity is a common issue with optical fiber sensors, this issue has been mitigated by simultaneous measurement techniques. But when it comes to absolute measurements, these methods have some limitations. The white light interferometer, which offers a superb solution for a range of applications, especially for absolute temperature measurement, is one of the most often used methods for absolute measurements.

Comparison of Raman, Brillouin, and Rayleigh Distributed Temperature Measurements in High-Rate Wells

With the maturity of and demand for fiber-optic sensing technology growing steadily over the last few years across multiple basins, operators are seeking fiber-optic sensing solutions that address the technology challenges associated with the life-of-field monitoring of subsea developments. Single-ended distributed temperature sensing (DTS) measurements have been acquired for decades now, typically using Raman optical time-domain reflectometry (OTDR) on multimode fiber. However, for topside interrogation of subsea completions, Raman DTS performs poorly. This is due to the available optical power budget and the potential wavelength dependency of optical attenuation across multiple connectors and splices comprising the optical subsea infrastructure. Any wavelength-dependent attenuation as the signals pass through connectors, splices, and optical feedthrough systems will generate step changes in the measured Raman DTS temperature profile. Brillouin OTDR can provide a DTS alternative that overcomes these challenges and operates on single-mode fiber. Brillouin OTDR operates with a large dynamic range to measure a wavelength (frequency) shift of the Stokes/anti-Stokes components that is proportional to both strain and temperature. Since downhole cables are manufactured with optical fibers suspended in a gel and with appropriate extra fiber length (EFL), any fiber strain relaxes, and the Brillouin wavelength shift is an absolute temperature measurement. An additional alternative is also explored here. We typically associate coherent Rayleigh OTDR with distributed acoustic sensing (DAS) on single-mode fibers, but low frequencies also contain a relative temperature dependence. The low-pass filtering of DAS data can then be used as a form of Rayleigh DTS with appropriate data processing. In this paper, we report on a comparison of Raman, Brillouin, and Rayleigh DTS simultaneously acquired in the same high-rate producer and injector wells. We validate that, with appropriate cable design, Brillouin DTS can be simultaneously operated on the same single-mode fiber with DAS and can deliver absolute temperature measurements suitable for production analysis. We also use a laboratory experiment to show that Rayleigh DTS provides an accurate measure of temperature changes comparable in precision to a traditional thermocouple. We conclude with a discussion about the implementation of this DAS-DTS solution for sensing subsea completions.

Generalized and wavelength-dependent temperature calibration function for multipoint regenerated fiber Bragg grating sensors.

A new calibration methodology for regenerated fiber Bragg grating (RFBG) temperature sensors up to 700 °C is proposed and demonstrated. A generalized, wavelength-dependent temperature calibration function is experimentally determined that describes the temperature-induced wavelength shifts for all RFBG sensor elements that are manufactured with the same fabrication parameters in the wavelength range from 1465 nm to 1605 nm. Using this generalized calibration function for absolute temperature measurements, each RFBG sensor element only needs to be calibrated at one reference temperature, representing a considerable simplification of the conventional calibration procedure. The new calibration methodology was validated with 7 RFBGs, and uncertainties were found to be compliant with those of Class 1 thermocouples (< ±1.5 K or < ±0.4% of the measured temperature). The proposed calibration technique overcomes difficulties with the calibration of spatially extended multipoint RFBG sensor arrays, where setting up an adequate calibration facility for large sensor fibers is challenging and costly. We assume that this calibration method can also be adapted to other types of FBG temperature sensors besides RFBGs. An accurate and practical calibration approach is essential for the acceptance and dissemination of the fiber-optic multipoint temperature sensing technology.

Emissivity evaluation of human enamel and dentin.

Background: Human enamel and dentin temperatures have been assessed with non-contact infrared imaging devices for safety and diagnostic capacity and require an emissivity parameter to enable absolute temperature measurements. Emissivity is a ratio of thermal energy emitted from an object of interest, compared to a perfect emitter at a given temperature and wavelength, being dependent on tissue composition, structure, and surface texture. Evaluating the emissivity of human enamel and dentin is varied in the literature and warrants review. The primary aim of this study was to evaluate the emissivity of the external and internal surface of human enamel and dentin, free from acquired or developmental defects, against a known reference point. The secondary aim was to assess the emissivity value of natural caries in enamel and dentin. Method: Fourteen whole human molar teeth were paired within a thermally stable chamber at 30°C. Two additional teeth (one sound and one with natural occlusal caries-ICDAS caries score 4 and radiographic score RB4) were sliced and prepared as 1-mm-thick slices and placed on a hot plate at 30°C within the chamber. A 3M Scotch Super 33 + Black Vinyl Electrical Tape was used for the known emissivity reference-point of 0.96. All samples were allowed to reach thermal equilibrium, and a FLIR SC305 infrared camera recorded the warming sequence. Emissivity values were calculated using the Tape reference point and thermal camera software. Results: The external enamel surface mean emissivity value was 0.96 (SD 0.01, 95% CI 0.96-0.97), whereas the internal enamel surface value was 0.97 (SD 0.01, 95% CI 0.96-0.98). The internal crown-dentin mean emissivity value was 0.94 (SD 0.02, 95% CI 0.92-0.95), whereas the internal root-dentin value was 0.93 (SD 0.02, 95% CI 0.91-0.94) and the surface root-dentin had a value of 0.84 (SD 0.04, 95% CI 0.77-0.91). The mean emissivity value of the internal enamel surface with caries was 0.82 (SD 0.05, 95% CI 0.38-1.25), and the value of the internal crown-dentin with caries was 0.73 (SD 0.08, 95% CI 0.54-0.92). Conclusion: The emissivity values of sound enamel, both internal and external, were similar and higher than those of all sound dentin types in this study. Sound dentin emissivity values diminished from the crown to the root and root surface. The lowest emissivity values were recorded in caries lesions of both tissues. This methodology can improve emissivity acquisition for comparison of absolute temperatures between studies which evaluate thermal safety concerns during dental procedures and may offer a caries diagnostic aid.

A thermometer circuit for hot temperature adjusts Drosophila behavior to persistent heat

Small poikilotherms such as the fruit fly Drosophila depend on absolute temperature measurements to identify external conditions that are above (hot) or below (cold) their preferred range and to react accordingly. Hot and cold temperatures have a different impact on fly activity and sleep, but the circuits and mechanisms that adjust behavior to specific thermal conditions are not well understood. Here, we use patch-clamp electrophysiology to show that internal thermosensory neurons located within the fly head capsule (the AC neurons1) function as a thermometer active in the hot range. ACs exhibit sustained firing rates that scale with absolute temperature-but only for temperatures above the fly's preferred ∼25°C (i.e., "hot" temperature). We identify ACs in the fly brain connectome and demonstrate that they target a single class of circadian neurons, the LPNs.2 LPNs receive excitatory drive from ACs and respond robustly to hot stimuli, but their responses do not exclusively rely on ACs. Instead, LPNs receive independent drive from thermosensory neurons of the fly antenna via a new class of second-order projection neurons (TPN-IV). Finally, we show that silencing LPNs blocks the restructuring of daytime "siesta" sleep, which normally occurs in response to persistent heat. Our previous work described a distinct thermometer circuit for cold temperature.3 Together, the results demonstrate that the fly nervous system separately encodes and relays absolute hot and cold temperature information, show how patterns of sleep and activity can be adapted to specific temperature conditions, and illustrate how persistent drive from sensory pathways can impact behavior on extended temporal scales.

Electrical resistance tomography-based multi-modality sensor and drift flux model for measurement of oil–gas–water flow

This paper proposes a novel method to measure each constituent of an oil–gas–water mixture in a water continuous flow, typically encountered in many processes. It deploys a dual-plane electrical resistance tomography sensor for measuring dispersed phase volume fraction and velocity; a gradiomanometer flow density meter and a drift flux model to estimate slip velocities; with absolute pressure and temperature measurements. These data are fused to estimate constituent volume flow rates. Other commonly used operational parameters can be further derived: water cut or water liquid ratio (WLR) and gas volume fraction (GVF). Trials are described for flow rates of water 5–10 m3 h−1; oil 2–10 m3 h−1 and gas 1–15 m3 h−1. The comparative results are included with published data from the Schlumberger Gould Research flow facility. The paper proposes the use of the described configuration for measurement of volume flow rates in oil–gas–water flows with an absolute error of ±10% within GVF 9%–85% and WLR > 45%.

Active thermo-reflectometry for absolute temperature measurement by infrared thermography on specular materials

Knowledge of material emissivity maps and their true temperatures is of great interest for contactless process monitoring and control with infrared cameras when strong heat transfer and temperature change are involved. This approach is always followed by emissivity or reflections issues. In this work, we describe the development of a contactless infrared imaging technique based on the pyro-reflectometry approach and a specular model of the material reflection in order to overcome emissivities and reflections problems. This approach enables in situ and real-time identification of emissivity fields and autocalibration of the radiative intensity leaving the sample by using a black body equivalent ratio. This is done to obtain the absolute temperature field of any specular material using the infrared wavelength. The presented set up works for both camera and pyrometer regardless of the spectral range. The proposed method is evaluated at room temperature with several heterogeneous samples covering a large range of emissivity values. From these emissivity fields, raw and heterogeneous measured radiative fluxes are transformed into complete absolute temperature fields.

Optical Hydrogen Nanothermometry of Plasmonic Nanoparticles under Illumination.

The temperature of nanoparticles is a critical parameter in applications that range from biology, to sensors, to photocatalysis. Yet, accurately determining the absolute temperature of nanoparticles is intrinsically difficult because traditional temperature probes likely deliver inaccurate results due to their large thermal mass compared to the nanoparticles. Here we present a hydrogen nanothermometry method that enables a noninvasive and direct measurement of absolute Pd nanoparticle temperature via the temperature dependence of the first-order phase transformation during Pd hydride formation. We apply it to accurately measure light-absorption-induced Pd nanoparticle heating at different irradiated powers with 1 °C resolution and to unravel the impact of nanoparticle density in an array on the obtained temperature. In a wider perspective, this work reports a noninvasive method for accurate temperature measurements at the nanoscale, which we predict will find application in, for example, nano-optics, nanolithography, and plasmon-mediated catalysis to distinguish thermal from electronic effects.

Enhancement of Imperfection Detection Capabilities in TIG Welding of the Infrared Monitoring System

For a low cost, there are industrial infrared monitoring systems used for imperfection detection and identification in welded joints. The key drawback that impedes real life industrial applications is the low spatial resolution, as well as the temporal resolution of low-cost infrared (IR) cameras. This is also the case in tungsten inert gas (TIG) welding. Taking into consideration the influence of voltage on the arc energy and heat input, high frequency sampled voltage was used to evaluate the interpolated temporal resolution of IR sequences. Additionally, a reflected temperature correction method was proposed to reduce the uncertainty of absolute temperature measurement with a thermographic camera. The proposed method was applied to detect several imperfection types, such as lack of or incomplete penetration as well as incorrect weld shape and size (including burnouts). Results obtained for different interpolation factors were compared. The obtained results emphasize the validity of reflected temperature correction method. For the weld defects detection task, the smallest detectable defect was found for various interpolation factors. Moreover, the correspondence of arc voltage and the joint temperature was checked. Additionally, a set of decision rules was elaborated on and applied to distinguish between various joint conditions. It was found that defects that do not have symmetrical temperature distribution with respect to the joint axis are harder to identify.

Two-photon absorption laser induced fluorescence measurements of absolute neutral deuterium density, temperature, and bulk flow in Proto-MPEX

Neutral particle control is critical for fusion fueling and confinement. Neutral diagnostics for fusion-relevant plasmas are commonly restricted to line-integrated or ex situ methods. A non-perturbative, two-photon absorption laser induced fluorescence (TALIF) diagnostic is implemented on the Prototype Material Plasma Exposure eXperiment (Proto-MPEX) to probe neutral atomic deuterium in a fusion-relevant plasma at 1 cm intervals along the radius of the vacuum vessel. The diagnostic is situated ∼20 m from the vacuum vessel, and a signal is collected along the laser injection axis, requiring only one line-of-sight. TALIF measurements are absolutely calibrated using xenon and krypton. Absolute atomic densities derived from xenon calibration are compared to absolute atomic densities derived from krypton calibration. Here, preliminary measurements of absolute atomic deuterium density, temperature, and local bulk flow dependence on radial location and input power in Proto-MPEX are presented. Neutral atomic deuterium velocity distribution functions are measured throughout a one-second plasma pulse with a time resolution of 250 ms.

Absolute temperature measurement on tungsten surfaces with monochrome and bicolor IR thermography

ITER (www.iter.org) will take advantage of tungsten (W) actively cooled plasma facing units (PFUs) in the lower divertor. These PFUs will receive a steady state plasma heat flux of 10 MW m−2 and up to 20 MW m−2 in slow transients, pushing these components to their limit. For machine protection reasons and for the study of the plasma wall interactions, temperature measurements are foreseen with mid wave infra-red (MWIR: 3–5 μm) thermography systems to cover most of the ITER chamber, including the divertor (tungsten material) and first wall (beryllium material) []. Absolute temperature measurements from 70 °C and the cooling temperature of the PFUs, up to 3500 °C (W melting temperature at 3422 °C), are considered. Those measurements require knowledge of the emissivity of the tungsten PFU surfaces as a function of the temperature and wavelength used for the IR monochrome thermography system. This paper summarizes the emissivity measurements performed on tungsten surfaces in high heat flux test beds and the WEST tokamak [] and uses the experimental emissivity values to compute the expected uncertainties in ITER (ΔT/T) using monochrome and bicolor thermography techniques. The results show that the monochrome technique is not able to fulfill the ΔT/T < 10% requirement, while the bicolor technique is able to reduce the temperature uncertainty below 10%. Laboratory bicolor thermography measurements using a filter wheel (including six MWIR interference filters) have been successfully performed up to 830 °C with temperature uncertainty ΔT/T < 3%. In the WEST tokamak, the two dimensions emissivity map is varying by a factor of five within 27 cm along a PFU, from 0.13 to 0.65, showing that the monochrome IR thermography will have difficulties staying within the ITER requirements ΔT/T < 10% from 70 °C up to 3500 °C.

Absolute OH density and gas temperature measurements by laser induced fluorescence in a microsecond pulsed discharge generated in a conductive NaCl solution

Electrical discharges in bubbles in liquid water have been extensively investigated for many applications including water treatment and often the OH radical is considered to be a key enabler of many applications. Nonetheless, to date, no OH density measurements have been reported for discharges in bubbles or in liquids in general. In this paper, we report an investigation of discharges in bubbles by laser-induced fluorescence (LIF). The plasma was generated by applying a microsecond voltage pulse to a needle electrode submerged in an aqueous NaCl solution in a Hele-Shaw cell. To determine the gas temperature and OH radical density, a LIF model resolving the energy transfer at the rotational level was implemented. Gas compositions at different gas temperature were obtained with a 0-D kinetics model. The LIF model also enabled us to explain the non-equilibrium rotational distribution of the OH ground state by LIF. Gas temperatures and OH radical densities up to 4900 ± 800 K and 3.2 ± 0.5 × 1017 cm−3 are consistent with conditions favoring thermally driven reactions in the plasma-filled vapor bubble.

System-on-chip upgrade of millimeter-wave imaging diagnostics for fusion plasma.

Monolithic, millimeter wave "system-on-chip" technology has been employed in chip heterodyne radiometers in a newly developed Electron Cyclotron Emission Imaging (ECEI) system on the DIII-D tokamak for 2D electron temperature and fluctuation diagnostics. The system employs 20 horn-waveguide receiver modules each with customized W-band (75-110GHz) monolithic microwave integrated circuit chips comprising a W-band low noise amplifier, a balanced mixer, a ×2 local oscillator (LO) frequency doubler, and two intermediate frequency amplifier stages in each module. Compared to previous quasi-optical ECEI arrays with Schottky mixer diodes mounted on planar antennas, the upgraded W-band array exhibits >30 dB additional gain and 20× improvement in noise temperature; an internal eight times multiplier chain is used to provide LO coupling, thereby eliminating the need for quasi-optical coupling. The horn-waveguide shielding housing avoids out-of-band noise interference on each module. The upgraded ECEI system plays an important role for absolute electron temperature and fluctuation measurements for edge and core region transport physics studies. An F-band receiver chip (up to 140GHz) is under development for additional fusion facilities with a higher toroidal magnetic field. Visualization diagnostics provide multi-scale and multi-dimensional data in plasma profile evolution. A significant aspect of imaging measurement is focusing on artificial intelligence for science applications.

Centimeter Spatial Resolution Distributed Temperature Sensor Based on Polarization-Sensitive Optical Frequency Domain Reflectometry

A centimeter-level spatial resolution distributed temperature sensor (DTS) based on polarization-sensitive optical frequency domain reflectometry (OFDR) is proposed. Polarization-maintaining fiber (PMF) is employed as the sensing fiber. The birefringence along the PMF is detected from the Rayleigh backscattering (RBS) spectral difference between the two orthogonal polarization axes, which is retrieved by short-time Fourier transform and distributed cross-correlation algorithm, and thus the large error induced by the auto-correlation is eliminated. Since the birefringence is roughly uniform for the same type of PMF, relationship between the absolute temperature and the birefringence calibrated on a small fiber section can be applied to the whole fiber, or even the same batch of fiber, which brings convenience in practice. The linear relationship between the absolute temperature and the RBS spectral difference is experimentally verified, and distributed temperature measurements are implemented with a high spatial resolution of 1.3 cm along the 94 m sensing fiber. The absolute temperature measurement uncertainty is $\boldsymbol {\pm 4.5\, ^{\circ}\text{C}}$ in the experiment, which is mainly limited by the birefringence non-uniformity. In some cases the impact of birefringence non-uniformity can be eliminated, and thus the temperature measurement uncertainty can be improved up to $\boldsymbol {\pm 0.8\, ^{\circ}\text{C}}$ , which is limited by the random noise in the proposed system.

Miniature fiber-optic sensor based on Si microresonator for absolute temperature measurements

We report development of a miniature fiber-optic temperature sensor. For the sensing element we used a silicon Fabry-Perot microresonator fused to the tip of an optical fiber. An original two-wave technique enabled measurements of absolute temperature to an accuracy of 0.3 °C (RMS). The system sensitivity to minor variations of temperature was 0.1 °C (RMS).