The rolling-four-ball test has been used to carry out an exploratory investigation on materials for unlubricated and elevated-temperature rolling bearings. Besides high-speed tool and stainless steels, other hard, wearresistant materials have been compared under unlubricated conditions at ambient and elevated temperatures. A solid material, molybdenum disulphide, has been assessed as an elevated temperature lubricant. Significant differences in performance have been found between different materials. The failure mechanism varied with environmental conditions. With liquid lubrication, plastic deformation and fatigue occur. The amount of deformation, the resistance to fatigue, and the mode of failure are affected by the type of lubricant and the nature of the additives. In the absence of lubricant there was no pitting, the useful life of rolling elements being limited by wear assessed by loss of weight. The term ‘wear’, in this paper, means grooving by removal of material evenly from the surface without pitting or deformation. Use of a solid lubricant reduced the wear rate. Material combination and compatibility of mating material surfaces are particularly significant in resistance to pitting and wear. An examination of failed specimens has been carried out to obtain a better understanding of the failure processes.