Sintering of pseudo-boehmite, acicularγ-Al2O3 produced by dehydration of pseudo-boehmite, andγ-Al2O3 ex alum was investigated. The sintering process was studied by X-ray diffraction, transmission electron microscopy with selected area electron diffraction and BET surface area measurements. The solid state reaction toα-Al2O3 causes a steep drop of the surface area to less than 10 m2g−1. The acicular pseudo-boehmite andγ-Al2O3 supports exhibit an intermediate state where the acicular particles assume a rod-like shape and the surface area falls from about 300 to 100 m2g−1. It was established that reaction to α-Al2O3 and, hence, sintering proceeds via a nucleation and growth mechanism. The rate-limiting step is nucleation of α-Al2O3. Consequently, the contacts between the elementary alumina particles dominate the sinter process. The contact between the acicular elementary particles of pseudoboehmite andγ-Al2O3 studied leads to the reaction to α-Al2O3 to be almost complete after keeping samples for 145 h at 1050 °C. Decomposition of alum produces very small particles showing negligible mutual contacts. Consequently an elevated thermal stability is exhibited. Treatment of the alumina ex alum with water and drying results in a xerogel in which contact between elementary particles is much more intimate. Accordingly, treatment at 1050 °C causes a sharp drop in surface area.