This paper examines the effect of fiber orientation angle of composite material (T300/5208) on the phenomenon of humidity diffusion. Using an analytical method, humidity concentration through the thickness of plates of E-glass/epoxy and carbon/epoxy (T300/5208) composites are calculated. This method also predicts the saturation in humidity and the time to saturation. Analytical formulations have been proposed [G. Verchery, Moisture diffusion in polymer matrix composites with cyclic environmental conditions, Developments in the Sciences and Technology of Composite Materials, in: A.R. Bunsell, J.F. Jamet, A. Massiah (Eds.), Proceeding of the 5th European Conference on Composites Materials (ECCM5), European Association For Composite Materials (EACM), Bordeaux, France (1992) 505; E. Adda-Bedia, W.S. Han, G. Verchery, Moisture diffusion in polymer matrix composites with cyclic environmental conditions, Textile composites in building construction (TCIBC 1992), in: P. Hamelin, G. Verchery (Eds.), Proceeding of the International Symposium Textile Composites in Building Construction, Pluralis, Paris, Part. 2, Lyon, France (1992a) 127; W.S. Han, E. Adda-Bedia, G. Verchery, Diffusion de l’humidité dans une plaque composite soumise à des conditions d’environnement cycliques”, Anales des Composites, Publication éditée par l’AMAC (1992) 29; E. Adda-Bedia, W.S. Han, G. Verchery, Simplified methods for prediction of moisture diffusion in polymer matrix composites with cyclic environmental conditions, International Journal of Polymers and Polymer Composites 6 (4) (1998) 189] to solve Fick’s equation which describes the kinematics of hygroscopic absorption in materials. The diffusivity in composites being a very important parameter, the present model is described in detail. In addition, a study of the effects of environmental conditions and fiber orientation angle on saturation values and ageing degradation of E-glass/epoxy composites exposed to hygrothermal conditions is proposed.