A (2,6)-fullerene F is a 2-connected cubic planar graph whose faces are only 2-length and 6-length. Furthermore, it consists of exactly three 2-length faces by Euler’s formula. The (2,6)-fullerene comes from Došlić’s (k,6)-fullerene, a 2-connected 3-regular plane graph with only k-length faces and hexagons. Došlić showed that the (k,6)-fullerenes only exist for k=2, 3, 4, or 5, and some of the structural properties of (k,6)-fullerene for k=3, 4, or 5 were studied. The structural properties, such as connectivity, extendability, resonance, and anti−Kekulé number, are very useful for studying the number of perfect matchings in a graph, and thus for the study of the stability of the molecular graphs. In this paper, we study the properties of (2,6)-fullerene. We discover that the edge-connectivity of (2,6)-fullerenes is 2. Every (2,6)-fullerene is 1-extendable, but not 2-extendable (F is called n-extendable (|V(F)|≥2n+2) if any matching of n edges is contained in a perfect matching of F). F is said to be k-resonant (k≥1) if the deleting of any i (0≤i≤k) disjoint even faces of F results in a graph with at least one perfect matching. We have that every (2,6)-fullerene is 1-resonant. An edge set, S, of F is called an anti−Kekulé set if F−S is connected and has no perfect matchings, where F−S denotes the subgraph obtained by deleting all edges in S from F. The anti−Kekulé number of F, denoted by ak(F), is the cardinality of a smallest anti−Kekulé set of F. We have that every (2,6)-fullerene F with |V(F)|>6 has anti−Kekulé number 4. Further we mainly prove that there exists a (2,6)-fullerene F having fF hexagonal faces, where fF is related to the two parameters n and m.