Two-dimensional (2D) perovskite single crystals have risen to be prominent in the domain of optoelectronic materials due to their exceptional characteristics including notably low ion migration and defect density. A distinguishing feature is the strategic inclusion of larger organic amine spacer, alternately inserted between inorganic lead halide octahedral layers. This spacer effectively mitigates ion migration, even under higher bias voltages, which is particularly advantageous for X-ray detection. However, the simultaneous realization of multiple functions within this realm remains a formidable challenge. In this work, we have synthesized a high-quality organic spacer-incorporated single layered 2D perovskite single crystal of [CYP]PbBr4 (CYP = 1-cyclohexylpiperazine). Our findings reveal the impressive potential of [CYP]PbBr4 in the domain of X-ray detection, as evidenced by the ultrahigh X-ray sensitivity, long-term stability, and astonishingly low detection limit of 1.72 nGyairs-1. Notably, [CYP]PbBr4 also emits bright broadband yellow light with quantum yield of 30.3%, and the fabricated white LED achieves a high Color Rendering Index of 94.1, which surpasses that of commercially available white LED based on YAG: Ce3+ (< 80).