14C Dates Research Articles

Dating the Egyptian Old Kingdom: The reign of Djedkare (5th dynasty)

Abstract This study aims to discuss the chronology of the Egyptian 5th dynasty of the Old Kingdom and the tentative date of accession of king Djedkare based on material from his royal necropolis at South Saqqara and non-royal cemetery of Abusir South, Egypt. A series of radiocarbon (14C) dates were established through analysis of archaeological material from several monuments at the necropolis, including the king’s pyramid complex, pyramid complex of his queen, and two elite tombs (Isesiankh and Khuwy). In addition, two samples from non-royal tombs in the Abusir South cemetery, were taken into consideration for further precision during the modeling, associated with king Huni (end 3rd dynasty) and king Niuserre (5th dynasty). The contextualized 14C dates together with re-evaluation of historical evidence on Djedkare’s rule, results in a new model of temporal probability density which can be further refined with any new data from archaeological research. It shows that Djedkare’s reign can be currently modelled between 2503 and 2449 BCE (95.4%), thus slightly older than expected by literature. This presented model provides a more precise chronological frame for the late 5th dynasty period of Egyptian history, which was period of a significant socio-economic transformation.

Radiocarbon ageing of Indigenous culturally‐significant trees for bushfire management on Minjerribah (North Stradbroke Island), southeast Queensland

SummaryPartnerships between Indigenous People and governments for joint management of ancestral lands, designated as protected conservation areas for biodiversity and cultural heritage, provide an opportunity to leverage accumulated traditional land management knowledge with emerging science. In Australia, veteran or large old trees in natural landscapes are of significant ecological importance, and among the Indigenous communities, they are living monuments to historical cultural practices, but their survival, endurance and long lives are rarely acknowledged to afford them protection. In sub‐tropical Australia, the lack of consistent annual growth rings in stem wood makes it difficult to estimate the age of large trees using methods such as the periodic diameter increment. Ngugi et al., 2020 published radiocarbon (14C) dates using wood core (‘pith‐wood’) samples from 12 Indigenous culturally‐significant trees covering five species on Minjerribah (North Stradbroke Island). Due to the imprecise calendar age results of the single samples used in the original study (Ngugi et al., 2020), subsequent radiocarbon dating of an additional three wood core samples from each tree was undertaken to age the trees more precisely. The revised tree ages ranged from 63 to 531 years and suggest an important role of past Indigenous land management practices into protecting Bugari (Cypress Pine, Callitris columellaris F. Muell.) from deadly crown scorching fires. These results underscore the importance of incorporating Indigenous practices in current fire management strategies and plans. Estimating tree ages based on the periodic diameter increment method overestimated the age relative to that derived from radiocarbon dating. New bias correction factors were developed for adjusting the recorded periodic tree diameter increments.

Preliminary investigation of the local marine reservoir effect in port JOLI harbour, NOVA scotia using archaeological M. arenaria shells

Port Joli Harbour, situated on the southwest coast of the maritime province of Nova Scotia, Canada, has the highest density of shell midden deposits in Atlantic Canada. The terrestrial radiocarbon chronology points to continuous human occupation of the harbour from 1685 cal yr BP to 250 cal yr BP. Despite the abundance of the soft-shell clams Mya arenaria at shell midden sites throughout the harbour they have not been incorporated into the chronology, nor have they been used to study the local marine reservoir effect in the harbour. We report 12 new 14C measurements on archived Mya arenaria from the same depositional contexts as previously dated charcoal and terrestrial mammal bone samples from two shell middens in Port Joli Harbour. From these shell-charcoal and shell-bone pairs, we present preliminary calculations of local marine reservoir corrections (ΔR) for the harbour. The ΔR values are highly variable and are overall more positive than the pre-bomb values reported for the Scotian Shelf. The variability of these values highlights the challenges in calculating ΔR values from archived archaeological samples but also the opportunities to include high-resolution analysis of ΔR variations in discussions on human-environment interactions in coastal settings during the late Holocene. We suggest that the chondrophore may be more favourable for calculating first order estimates of ΔR to be used in future archaeological calibrations, while high resolution analysis of the ventral margin region is useful for climate reconstructions. We recommend that more 14C measurements from M. arenaria shells be obtained from either distinct features or rapidly deposited middens in Port Joli Harbour. A suite of temporally and geographically precise ΔR values for the harbour will not only allow for the study of middens that are at risk of coastal erosion and lack charcoal for 14C dating but will also allow for the reconstruction of past climate conditions and refine our understanding of late Holocene human-environment interactions in the North Atlantic.

From the Northern Hajar Foothills to the Batinah Coast – a Geoarchaeological Survey at Saham and Dahwa (Northern Oman)

This geoarchaeological survey was dedicated to (i) the Umm an-Nar (2700–2000 BCE) settlement site of Dahwa and surrounding areas in the foothills of the Hajar Mountains as well as (ii) the coastal area near Saham on the Batinah coastal plain in northern Oman, the latter without focus on a specific cultural epoch. Stratigraphic sections from the proximal coastal plain provide insights into highly dynamic episodic sedimentation patterns with thick units of variable grain sizes and sorting. In one of the stratigraphic profiles in the town of Saham, a small anthropogenic pit or channel was found, interpreted as a pit hearth used by the Samad culture (300 BCE–100/200 CE) based on granulometry, thin-section analysis, clustered macro-charcoals, amorphous organic remains, as well as luminescence and 14C dating. Our coincidental discovery of this site indicates that there might be abundant traces of the Samad culture buried in the thick alluvium, from a period of hydrologically favourable conditions c. 50–300 CE. The Umm an-Nar dating of the Dahwa archaeological site in the foothills of the Hajar Mountains was confirmed for the first time by luminescence dating, although the low dose rate and high scatter of equivalent doses pose substantial challenges to the regional application of this method.

Unravelling 6000 years of interplay among environmental changes, anthropogenic activities, and Vesuvius eruptions in the upper Sarno Plain (Campania, Italy)

Abstract Pollen analysis was carried out on the infilling succession of the Fossa San Vito sinkhole, at the NE foothills of the Sarno Plain (Italy). Four 14C dates and six tephra layers constrain the pollen sequence between ca. 6000 and 500 cal yr BP. A forested environment, with a few signs of human activities, characterizes the pre-protohistoric period (ca. 6000–2750 yr BP). Stability of the arboreal pollen grains to non-arboreal pollen grains (AP/NAP) curve is due to climate-related opposite oscillations of deciduous and evergreen forest. In this period, the pyroclastic products from Neapolitan volcanoes that reached the upper Sarno Plain seem to have affected neither vegetation nor human activities. In the archaic and classic periods (ca. 2750–1500 yr BP), intensive deforestation and increase in anthropogenic indicators indicate the occurrence of grazing and crop activities managed by the main urban centers located in the plain: Pompeii, Stabiae, and Nuceria. After the Pompeii eruption in CE 79, a rapid re-afforestation and decline in all anthropogenic indicators testify to the temporary abandonment of the area, linked to the disastrous demise of the main economic centers. The upper plain was repopulated and exploited in the Late Ancient and Middle Ages (ca. 1700–500 yr BP), as indicated by the increase in all crop and grazing indicators.

To date or not to date? A comparison of different 14C pretreatment methods applied to archeological marine shells from Vale Boi (Portugal)

Abstract Mollusk shells are often found in archeological sites, given their great preservation potential and high value as a multipurpose resource, and they can often be the only available materials useful for radiocarbon (14C) dating. However, dates obtained from shells are often regarded as less reliable compared to those from bones, wood, or charcoals due to different factors (e.g., Isotope fractionation, reservoir effects etc.). The standard acid etching pretreatment for mollusk shells is the most used in many 14C laboratories, although another protocol known as CarDS (Carbonate Density Separation) was introduced just over a decade ago. We compare these two methods with two newly proposed methods for intracellular organic matrix extraction. We applied all four methods to samples selected from different archeological layers of the well-known Upper Paleolithic site of Vale Boi, rich in mollusk specimens throughout the stratigraphic sequence. Here we compare our results to previous dates to determine which of these pretreatment methods results in the most reliable 14C dates. Based on the results of this study, all four methods gave inconsistent ages compared to previous dates and the stratigraphic attribution.

RADIOCARBON CHRONOLOGY OF THE OCCUPATION OF THE SOUTHERN COAST OF NAYARIT, MEXICO

ABSTRACT Despite chronicles from the 16th century describing fertile alluvial plains and densely populated wetlands, archaeology in western Mexico has been little studied. The Directorate of Archaeological Salvage (DSA) of National Institute of Anthropology and History (INAH) has initiated a study of two sites in Costa Canuva, at the southern part of Nayarit state: Becerros and Naranjos. Thirty charcoal and shell samples were radiocarbon (14C) dated to determine occupation history. A Bayesian approach was used to build a chronological modeling from charcoal samples. Charcoal and shell samples found in the same context allowed us to calculate the ΔR values of marine offset for this period. In general, the archaeological sites of this area are divided into three major periods: Formative, Classic, and Postclassic. The 14C dating of Becerros recovered materials provided a chronological framework for the site’s occupation, from cal AD 169–1025, corroborating the ceramic studies in the sense that human settlement activities date from the Formative (300 BC–AD 600) to the Early Postclassic (AD 900–1200). Naranjos started in the Classic period and reached its occupancy peak in the Late Classic. The site’s occupation may have persisted for at least two centuries after the conquest of the Altiplano in 1521. The comparison of charcoal dates and associated shell samples from the Naranjos Unit gave a probability distribution for ΔR, that ranged from 118.5 to 199.5 with a mean value of 159 ± 4, slightly higher than other values obtained at nearby sites.

A multi-embankment Chalcolithic walled enclosure

Ota, a key part of the Chalcolithic walled enclosure phenomenon in Portuguese Estremadura, represents a unique settlement strategy within the actual territory of Portugal. The architecture and social dynamics of this site remained largely unexplored until 2019. This study marks a significant shift in its study, utilizing a synergistic approach of archaeology and geotechnologies, embodied in the using an Unmanned Aerial Vehicle equipped with LiDAR. This innovative combination successfully penetrated the dense vegetation, revealing 21 previously unknown archaeological features. The results from the fieldwork unveiled a novel type of walled enclosure at Ota, characterized by a series of four embankments. This discovery prompts a re-evaluation of the roles and practices of 3rd millennium BC communities in Portuguese Estremadura. Furthermore, the proven efficacy of this methodology paves the way for its application in similar archaeological contexts. The paper presents a comprehensive analysis of the recent fieldwork, integrating interpretations from LiDAR data, material studies and 14C dating.

Dwarfism-related skeletal dysplasia in Italy. Multi-analytic study of 8th century CE human remains from Azzio (Varese) and biocultural implications of a pathology

Skeletal dysplasias are a broad family of genetic disorders, often challenging to diagnose even in clinical literature without molecular analysis. Some cases of possible skeletal dysplasia have also been identified in osteoarchaeological samples, although achieving a definitive diagnosis is fraught with difficulties. This paper presents the analysis of the osteological remains of AZ-III-3, discovered in the archaeological context of the Church of Sant’Antonio and Eusebio in Azzio (Varese province, Italy). The study aims to demonstrate that even with limited skeletal elements, a diagnosis can be hypothesised using macroscopic morphometric and radio diagnostic techniques. These methods, compared with clinical and paleopathological literature, have allowed for the identification of a rare Italian case of dwarfism-related skeletal dysplasia. This contribution seeks to address the biocultural presence of individuals affected by these skeletal dysplasias, listing and discussing all published Italian cases, including that of AZ-III-3, whose chronological framework was established through both archaeological context analysis and 14C dating.

Made of flint, bone and boar’s tusks – burial goods from male grave No. 2 in Świerszczów (Kolonia) 28, Hrubieszów District – attributed to the Malice culture – in the light of traceological analysis

The article presents the results of a traceological analysis conducted on artefacts made of bone, boar’s tusks and flint – the only funerary goods discovered in Grave No. 2 at Świerszczów (Kolonia) Site 28, in which an adult male was buried. Despite the lack of pottery vessels that could indicate cultural affiliation, the grave is attributed to the Rzeszów phase of the Malice culture, i.e., the final, Eneolithic, stage of that culture. This attribution is based on 14C dating and on the presence in the grave of artefacts made of boar’s tusks and flint burins. Microscopic analysis conducted on the discovered artefacts revealed traces related to their production, use and repair on their surfaces. Most items bear traces indicating their usage in processing soft materials, like siliceous (wild and domesticated) plants and hide. Interestingly, the artefacts with holes for hanging – traditionally regarded as adornments in archaeological literature – were also employed in different activities.

NOthing goes toWAste (NOWA): A protocol to optimise sampling of ancient teeth

Advancements in archaeological sciences through innovative scientific techniques applied to ancient human remains have increasingly been transforming the study of the past. Destructive analyses of bioarchaeological or palaeontological specimens such as dental histology, isotopic or elemental analysis of dental mineralised tissues, 14C dating, proteomic analysis or ancient DNA are increasingly being applied to obtain ever more refined past life histories. In tandem with spatially-resolved analyses, mineralised dental tissues, especially enamel, have proven to be ideal archives. The main concern with any of these techniques is the need for some level of destructive sampling and thus damage to specimens. In compliance with the ALARA (As Low [damage] As Reasonably Achievable) principle, we present a standardised protocol (the NOWA protocol) for the optimisation, in terms of minimising the destructive approach, of tooth sampling for histology, biomolecular and biogeochemical analyses. The NOWA protocol enables the collection of multiple datasets through optimised sampling of a single dental specimen, ensuring the preservation of most of the tooth and, to a substantial degree, its morphology. Overall, this approach balances the significant scientific insights from such investigations against the inevitable conservation requirements of valuable archaeological and palaeontological specimens, thus maximising the feasibility of future analyses of individual specimens that need to be evaluated on a case-to-case basis.

AMS 14C Dating of the Sites of Digaru-Kolong River Valley, Assam-Meghalaya Foothills, India

Abstract The present study aims to determine the chronology of the past settlement of the different archaeological sites of the Digaru–Kolong River valley (Assam-Meghalaya Foothills), India, based on accelerator mass spectrometry (AMS) 14C dates of seven charcoal samples, five potsherds, and five sediment samples. The archaeological record of the study area consists of ground and polished stone axes and adzes, pottery, and standing or buried megaliths. The samples analyzed were excavated from test pits, and an attempt has been made to correlate the findings with the chronology of the neighboring archaeological region. A site reported in the vicinity of the study area is primarily Neolithic. However, the results from our excavations indicate a time frame for the analyzed artifacts of ca. 240 CE to 1379 CE.

Storminess reconstruction in the northeastern Baltic Sea region over the past 7600 years based on aeolian sand influx into coastal bogs

This study aims to reconstruct the changes in storminess during the past 7600 years in the northeastern Baltic Sea region. For storminess reconstructions, aeolian sand influx (ASI) in coastal peat bog deposits was applied as an indicator of the past storminess. We analyzed cores from four peat bogs in the western and northern coastal areas of Estonia: the cores from Hiiumaa N, Hiiumaa SW, Saaremaa and Juminda study sites covered the past 3700, 3750, 2400, and 8400 years, respectively. The sediment chronologies were established using 36 14C dates. Image-analysis method ( ImageJ) was used to count and measure the grain size of all sand particles at every centimeter to gain high-resolution ASI records. Although minor site-to-site variations exist, all four ASI records were in general consistent, suggesting that stormier periods occurred around 7300, 6600, 5900, 4600, 3600, 2900, 2400, 2100, and 1600 cal yr BP and over the last 1200 years. The results and comparisons with other storminess and climate studies indicate a shift in climatic conditions around 2500 cal yr BP when stormy periods became more frequent. The ASI values were also high during the last millennium, suggesting either higher storminess or more suitable transport mechanisms for sand into the coastal bogs: the niveo-aeolian transport mode could have been favored in winters, especially during the Little Ice Age, and human impact on landscapes has probably increased over the past centuries.

Investigation of submarine groundwater discharge into the Baltic Sea through varved glacial clays

Submarine groundwater discharge (SGD) is an important process responsible for transporting terrestrial dissolved chemical substances into the coastal ocean, thereby impacting the marine ecosystem. Despites its significance, there are few studies addressing SGD in the northern Baltic Sea. Here we investigate the potential occurrence of SGD in an area characterized by seafloor terraces formed in varved glacial clay located around Fifång Island, Southern Stockholm Archipelago. We analyzed 222Rn activity and porewater geochemistry in both marine and terrestrial sediment cores retrieved from Fifång Island and its surrounding offshore areas. Results from 222Rn mass-balance calculations, water isotopes, salinity, chloride concentration, and dating (including 14C and helium-tritium dating) indicate that modern groundwater flows through varved glacial clay layers and fractured rocks on Fifång Island and discharges into Fifång Bay. Additionally, the offshore cores reveal a saline groundwater source that, dating of the dissolved inorganic carbon, appears systematically younger than the hosting clay varves dated using the Swedish clay varve chronology. Acoustic blanking in our acquired sub-bottom profiles may be related to this fluid migration. The occurrence of this saline groundwater seems to be independent from the distance to the submarine terraces. Collectively, our study confirms the occurrence of submarine groundwater in the varved glacial clay close to Fifång Island and further offshore. Our findings help establish the significance of submarine groundwater discharge in influencing the past and present coastal environment in the Baltic Sea region.

RADIOCARBON MORTAR DATING INTERCOMPARISON MODIS2—APPROACH FROM THE ZAGREB RADIOCARBON LABORATORY, CROATIA

ABSTRACT The Second International Mortar Dating Intercomparison Study (MODIS2) took place in 2020. Three mortar samples from different sites and chronologies were distributed among various research groups in form of bulk mortar and grain fraction smaller than 150 µm. This is the first time the Zagreb Radiocarbon Laboratory, with support of the Center of Applied Isotope Studies, University of Georgia, took part in the international mortar intercomparison. The initial approach of the Laboratory to mortar dating was to separate 32–63 µm grain fraction and collect three CO2 gas portions by sequential dissolution with acid. After checking the 14C date trends of the gas portions, which should be ascending with later fractions, the one for the first and shortest gas portion was reported as the age of the mortar. However, the first gas portion might not be true age of the mortar, since it still might contain some “dead” carbon. Therefore, data extrapolation from the first two initial CO2 portions was also conducted on the results, but not reported to the intercomparison. Though in general, all the intercomparison reported dates fit the expected historical ages, for one sample, the extrapolated result showed a better match to the historical data.

Peak Height Comparison K-Ar Method Applied to Zao Volcano Bomb Samples Younger than ca. 35 ka

The peak height comparison K-Ar dating method was applied to very young (younger than ca. 35 ka) vesiculated bombs from three pyroclastic units (Komakusadaira Pyroclastics, Kattadake Pyroclastics, and Umanose Agglutinate) from Zao Volcano in northeast Japan. Because the 38Ar/36Ar ratios differed from 0.187, the mass fractionation was corrected for all measurement data. The obtained K-Ar ages are 30.0 ± 32.2 ka (no. 1-1, weakly vesiculated), 37.4 ± 64.8 ka, and 33.0 ± 58.0 ka (nos. 2-1, 2-2, weakly vesiculated) for the samples from Komakusadaira Pyroclastics; 12.6 ± 46.7 ka (no. 3-1, highly vesiculated) for a sample from Kattadake Pyroclastics; and 5.3 ± 44.9 ka, 5.7 ± 14.3 ka (no. 4-1, 4-2, weakly vesiculated), and 17.3 ± 79.3 ka (no. 5-1, moderately vesiculated) for the samples from Umanose Agglutinate on a 1σ error basis. For all cases, the obtained ages’ errors exceed 100%, with none involved within the error range. Therefore, the following age value upper limits are considered statistically significant: no. 1-1 is ≤94.4 ka, 2-1 is ≤167.0 ka, 2-2 is ≤149.0 ka, 3-1 is ≤106.0 ka, 4-1 is ≤95.1 ka, 4-2 is ≤34.3 ka, and 5-1 is ≤175.9 ka, considering 2σ errors. The obtained ages are generally consistent with those previously estimated using 14C dating.

Palynological, tephra, and 14C records from southern Kaitoke, Great Barrier (Aotea) Island, New Zealand, since c. 30,000 cal. yr BP

ABSTRACT Here we present results of the last remaining three, unreported pollen and stratigraphic profiles from our previous investigations on Great Barrier Island from southern Kaitoke. The 14C and pollen data extend the island’s previous maximum pollen-vegetation date from c. 7000 cal. yr BP to close to the end of MIS 3 c. 30,000 cal. yr BP. The oldest 14C date (34,380-28,190 cal. yr BP) and the presence of secondary deposition fragments of Rotoehu Tephra in the basal brown sands and nearby dune deposits implies their formation between c. 30,000 and 45,000 yr BP. The basal sand deposits and palynology in Profile 1 indicate that the site was close to sea-level at the time. Subsequently, the sediments reflect the Last Glacial Coldest Period, characterised by increased Fuscospora pollen. Following the relative stability of the mid-Holocene high sea-level stand, alternations between drier and wetter (freshwater) conditions, with depositional hiatuses, are congruent with evidence for erratic sea-level falls causing blockage of coastal drainage and rear-dune flooding since c. 2,700 cal. yr BP; layers of preserved wood and in-situ stumps overlying firmer palaeosols were followed by fresh-water peats at two of the sites reported here and other, previously reported sites. Polynesian settlement and forest clearance occurs around the time of the 1314 ± 12 AD Kaharoa Tephra, consistent with the project’s previous reports, and with the timing from elsewhere in New Zealand.

Paleo-climatic control on recharge and fresh-salt groundwater distribution in the Red River delta plain, Vietnam

Paleo-climatic induced sedimentation controls present-day recharge and the fresh-salt groundwater distribution in Quaternary delta systems. During sea-level highstands, marine clays with saline pore water were deposited and are interbedded with aquifers of coarse-grained sandy fluvial and shallow marine deposits, laid down during lowstands. The low-permeable marine layers may inhibit recent recharge to deeper aquifers, and thereby limit sustainable use of these freshwater resources. This phenomenon has been investigated in the Red River delta plain, using geophysical borehole logging, transient electromagnetic soundings, groundwater chemistry, stable isotope analysis and 3H and 14C dating of groundwater. Results reveal that marine saline pore water is still present in the Holocene marine clays, implying that fresh water has not entered the clays since their deposition. Therefore, recharge within the delta plain is not occurring and the deeper aquifers are hydraulically disconnected from the upper sandy layers. Today, recharge only occurs from the hinterland. Recharge during the last glacial period has flushed saline pore water from Pleistocene marine clays, but these clays were again affected by saline water during the Holocene transgression. The use of the groundwater resources in the delta plain must be adjusted to the present recharge to be sustainable.

Westerly and Laurentide ice sheet fluctuations during the last glacial maximum

The last glacial maximum (LGM) is widely acknowledged as the most recent cold period representing maximum global ice conditions. However, substantial warming is observed over Northern Hemisphere. Here, we show that the LGM climate shifted from very cold to fairly warm, followed by less cold conditions in the early Heinrich Stadial 1 (HS1) phases. Our synthesis of accurate AMS 14C dates refines the exact timing of Laurentide Ice Sheet (LIS) advances during the early LGM/HS1, constraining the chronology of the LIS decay during the late LGM. The summertime soil temperatures near ice fronts were found to increase by 1.3 °C from the early to late LGM and to decrease by 0.5 °C to the early HS1 phases, consistent with the cold-warm-cool climate patterns. The early/late LGM and early HS1 climates are found to be characterized by frequent cold/warm summers and cold winters since the world’s largest LIS began to decay.

Radiocarbon dating of the natural groundwater in the Ob-Zaisan folded region (Russia)

Groundwater in the Ob-Zaisan folded region (Russia) has significant differences in the stable isotope composition of oxygen and hydrogen, which cannot be explained by the geographical and relief features of the region. A probable reason for these differences could be climatic changes in the study area over the past tens of thousands of years. The method of the radiocarbon dating can be perfectly suited in order to determine such small geological ages. The dating of waters using 14C data gives an understanding of their residence time. It will make it possible to differentiate periods of recharge and accumulation of water in aquifers and track the changes of the water stable isotope composition over time. The estimated water age ranges from 650 to 19,000 years. The enrichment of δD and δ18O values with the decreasing of the water age indicates a gradual warming of the Novosibirsk region climate. These results logically complement the meteorological observations over the last century and may be useful for paleoclimate reconstructions of the region.