The air-sea gas transfer velocity (K660) is typically assessed as a function of the 10-m neutral wind speed (U10n), but there remains substantial uncertainty in this relationship. HereK660of CO2derived with the eddy covariance (EC) technique from eight datasets (11 research cruises) are reevaluated with consistent consideration of solubility and Schmidt number and inclusion of the ocean cool skin effect.K660shows an approximately linear dependence with the friction velocity (u*) in moderate winds, with an overall relative standard deviation (relative standard error) of about 20% (7%). The largest relative uncertainty inK660occurs at low wind speeds, while the largest absolute uncertainty inK660occurs at high wind speeds. There is an apparent regional variation in the steepness of theK660-u*relationships: North Atlantic ≥ Southern Ocean > other regions (Arctic, Tropics). Accounting for sea state helps to collapse some of this regional variability inK660using the wave Reynolds number in very large seas and the mean squared slope of the waves in small to moderate seas. The grand average of EC-derivedK660(−1.47 + 76.67u*+ 20.48u*2 or 0.36 + 1.203U10n+ 0.167U10n2)is similar at moderate to high winds to widely used dual tracer-basedK660parametrization, but consistently exceeds the dual tracer estimate in low winds, possibly in part due to the chemical enhancement in air-sea CO2exchange. Combining the grand average of EC-derivedK660with the global distribution of wind speed yields a global average transfer velocity that is comparable with the global radiocarbon (14C) disequilibrium, but is ~20% higher than what is implied by dual tracer parametrizations. This analysis suggests that CO2fluxes computed using aU10n2dependence with zero intercept (e.g., dual tracer) are likely underestimated at relatively low wind speeds.
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