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Mechanical and Tribological Behavior of Nitrided AISI/SAE 4340 Steel Coated with NiP and AlCrN

In this study, novel surface engineering strategies to improve the wear performance of AISI 4340 were investigated. The strategies were as follows: (i) NiP deposition on a previously nitrided steel substrate, followed by NiP interdiffusion heat treatment at either 400 °C or 610 °C (referred to as duplex treatment); (ii) the deposition of AlCrN PVD coating on NiP layers on a previously nitrided steel substrate (referred to as triplex treatment). Prior to the deposition of AlCrN, the NiP was subjected to the interdiffusion heat treatment at either 400 °C or 610 °C. These strategies were compared with the performance of the AlCrN coating directly applied on nitrided steel. To characterize the microstructural features of each layer, X-ray diffraction (XRD) and scanning electron microscopy (SEM) coupled with energy-dispersive X-ray spectroscopy (EDS) analysis were conducted. We also carried out mechanical and tribological behavior assessments. The tribological tests were carried out using a ball-on-disc tribometer under a constant load of 20 N and a tangential speed of 25 cm/s; cemented carbide spheres with a diameter of 6 mm were the counterpart body. The friction coefficient was continuously monitored throughout the tests. The results reveal that the wear mechanism for the AlCrN coating is predominantly oxidative. The most wear-resistant surface architecture was the one comprising AlCrN over the NiP layer subjected to interdiffusion heat treatment at either 400 °C or 610 °C.

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Progress in Theoretical Modelling of Macroscopic and Microscopic Dynamics of Bolted Joints in Complex Equipment

Bolt connection structure is a common form of connecting large and complex equipment. Its object contact surfaces under normal and tangential loads will appear in the form of slip and adhesion, which affects the service life of mechanical equipment. Bolted connection structures cause changes in stiffness and damping, which have great impacts on the dynamic characteristics. Experimental studies and numerical simulations have difficulty predicting the overall performance of bolts in a timely manner, hence cannot ensure the reliability and safety of complex equipment. In order to improve the overall performance of complex equipment, it is necessary to study the contact theory model of bolt connection structures. Based on the relationship between friction force and velocity in the classical friction model, the mathematical expressions of restoring force and tangential displacement in the kinetic theory model are deduced to predict the stiffness degradation of the bolted structure and to characterise the kinetic properties and laws of the bolted structure. From the perspective of theoretical calculation, it makes up for the situation in which it is difficult to measure the performance of bolts due to the existence of spanning scale and provides theoretical support for the reliability of connecting complex equipment. This paper summarises and analyses the contact theory model of bolt connection structures, ranging from macroscopic to microscopic; describes the static friction model, kinetic friction model, statistical summation contact model, fractal contact model; and analyses the influencing factors of the microscopic contact mechanism. The advantages and disadvantages of the kinetic theoretical models are described, the manifestation of friction and the relationship between tangential force–displacement are discussed, and the key research directions of the kinetic theoretical models of bolted structures in the future are elucidated.

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Tribological Behavior of Polydiethylsiloxane (PDES) in a Si3N4 and M50 System under Low Temperatures from −80 to 25 °C

Lubricants must exhibit good tribological behavior at low temperatures to ensure reliable startups in very cold regions. This study investigates the performance of lubricants, with a specific focus on their capacity for high-temperature lubrication and ensuring reliable low-temperature startup in engines. Experiments were conducted to assess the friction and wear characteristics of polydiethylsiloxane in conjunction with a Si3N4 ball and M50 (8Cr4Mo4V) steel across a temperature range of −80 °C to 25 °C. The results indicate that the coefficient of friction, as determined through friction and wear tests at various temperatures, remained below 0.1. As temperatures progressively decreased, the system’s friction coefficient increased, and wear volumes recorded at 25 °C and −60 °C were 9749.513 µm³ and 105.006 µm³, respectively, culminating in lubrication failure at −100 °C. This failure is primarily attributed to the increased viscosity and decreased mobility of polydiethylsiloxane at extremely low temperatures. Additionally, the reduced temperature increases the strength of the quenched steel, leading to hard particles or protrusions on the material’s surface, which collide with the Si3N4 ball during friction, causing adhesion and spalling. Despite this, polydiethylsiloxane forms a stable protective oil film on the surface, enhancing the system’s lubrication performance. However, below −80 °C, this oil film begins to tear, leading to diminished lubrication efficacy. This study provides valuable data supporting the field of cryogenic lubrication.

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Effect of Nano-CuO and 2-Mercaptobenzothiazole on the Tribological Properties of Ultra-High Molecular Weight Polyethylene

In this study, the tribological properties of nanocomposites based on ultra-high molecular weight polyethylene (UHMWPE) filled with nano-CuO and 2-mercaptobenzothiazole (CuO/MBT) in mass ratios of 1:1 and 2:1 were investigated. In the supramolecular structure of UHMWPE nanocomposites, spherulites of several hundred micrometers in size are formed. The density of UHMWPE nanocomposites slightly increases relative to the pure polymer, reaching a maximum at 2 wt.% CuO/MBT in both ratios. The Shore D hardness and compressive stress of the UHMWPE nanocomposites showed an improvement of 5–6% and 23–35%, respectively. The wear resistance and coefficient of friction of UHMWPE nanocomposites were tested using a pin-on-disk configuration under dry friction conditions on #45 steel and on P320 sandpaper. It was shown that the wear rate of UHMWPE nanocomposites filled with 2 wt.% CuO/MBT decreased by ~3.2 times compared to the pure polymer, and the coefficient of friction remained at the level of the polymer matrix. Abrasive wear showed an improvement in UHMWPE nanocomposites filled with 1 wt.% CuO/MBT compared to the polymer matrix and other samples. The worn surfaces of the polymer composites after dry friction were examined by scanning electron microscopy and IR spectroscopy. The formation of secondary structures in the form of tribofilms that protect the material from wear was demonstrated. Due to this, the wear mechanism of UHMWPE nanocomposites is transformed from adhesive to fatigue wear. The developed materials, due to improved mechanical and tribological properties, can be used as parts in friction units of machines and equipment.

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Tribological Behavior of Friction Materials Containing Aluminum Anodizing Waste Obtained by Different Industrial Drying Processes

With sustainability dominating the industry, recycling the generated waste from different processes is becoming increasingly important. This study focuses on recycling waste generated during aluminum anodizing waste (AAW) in friction material formulations for automotive braking applications. However, before utilization, the waste needs to be pre-treated, which mainly involves drying. Hence, four different industrial drying methods were studied to dry the AAW, and the corresponding characteristics were observed by evaluating its residual humidity and crushability index. The waste powders were further characterized using FT-IR and SEM/EDXS to understand their constituents. The initial analysis showed that the waste subjected to the drying process P2 and P1 with the lowest final humidity fetched the most desirable results, with P1 having the simpler drying procedure. The AAW powders were added in a commercial friction material formulation at 6 and 12 wt.% and subjected to friction, wear, and non-exhaust particulate matter analysis. The worn surfaces were analyzed using SEM/EDXS evaluation to understand the extension and composition of the deposited secondary contact plateaus. It was seen that the 12 wt.% addition of waste processed using the P1 technique provided the most satisfactory friction, wear, and emission characteristics, along with expansive secondary contact plateaus with a good contribution of the waste in its formation. This study showed a good relationship between the processing method and a formulation’s tribological and emission characteristics, thereby paving the way for using this drying method for other waste requiring pre-treatment.

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