Abstract
The reaction of Cp 2Ti(AsF 6) 2 ( 1) in liquid sulfur dioxide with XCN gave the cationic titanocene complexes [Cp 2Ti(XCN) 2][AsF 6] 2 (X H, 2; D, 3). The bonding situation between the Lewis acid (CP 2Ti 2+) and the Lewis base (XCN) is discussed on the basis of IR data and qualitative MO considerations. A convenient laboratory-scale synthesis of DCN is reported.
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