ZnCo2O4 composite catalyst accelerated removal of phenylic contaminants containing of Cr(VI) in dielectric barrier discharge reactor: Process and mechanism study

Abstract

The degradation of phenylic contaminants (phenol, hydroquinone, nitrobenzene, p-nitrophenol) containing Cr(VI) has been investigated in a dielectric barrier discharge (DBD) system using a ZnCo2O4 composite catalyst. The ZnCo2O4 nanowires combined with multi-walled carbon nanotubes (MWNTs) on a sponge substrate in the discharge system can induce a decrease in the corona inception voltage and discharge becomes more stable resulting in an improvement in the energy utilization efficiency. With the synergistic degradation of phenylic species containing Cr(VI), the total elimination efficiency was further improved. The active substances (H2O2 and O3) were detected in the discharged solution, and some of them were consumed in the phenylic system. The effects of ·OH, O2·- and e− were also verified using free radical trapping experiments in which ·OH exhibited the main oxidation effect for the degradation of phenylic pollutants, and e−, H2O2 and H· affect the reduction of Cr(VI). The intermediate products were determined in order to analyze the degradation process of phenylic pollutants by the ZnCo2O4 composite catalyst in combination with the DBD system. The electron transfer process in the ZnCo2O4 composite catalyst during discharge was analyzed. Finally, the biotoxicity of the phenylic pollutants before and after degradation was compared.