Abstract

The electrical properties, resistive switching behavior, and long-term potentiation/depression (LTP/LTD) in a single indium-gallium-zinc-oxide (IGZO) and bi-layer IGZO/ZnO (ZnO: zinc oxide) memristors were investigated for synapse application. The use of the oxide bi-layer memristors, in particular, improved electrical properties such as stability, memristor reliability, and an increase in synaptic weight states. The set voltage of bi-layer IGZO/ZnO memristors was 0.9 V, and the reset voltage was around − 0.7 V, resulting in a low-operating voltage for neuromorphic systems. The oxygen vacancies in the X-ray photoelectron spectroscopy analysis played a role in the modulation of the high-resistance state (HRS) (oxygen-deficient) and the low-resistance state (oxygen-rich) region. The VRESET of the bi-layer IGZO/ZnO memristors was lower than that of a single IGZO, which implied that oxygen-vacancy filaments could be easily ruptured due to the higher oxygen vacancy peak HRS layer. The nonlinearity of the LTP and LTD characteristics in a bi-layer IGZO/ZnO memristor was 6.77% and 11.49%, respectively, compared to those of 20.03% and 51.1% in a single IGZO memristor, respectively. Therefore, the extra ZnO layer in the bi-layer memristor with IGZO was potentially significant and essential to achieve a small set voltage and a reset voltage, and the switching behavior to form the conductive path.

Highlights

  • The electrical properties, resistive switching behavior, and long-term potentiation/depression (LTP/ LTD) in a single indium-gallium-zinc-oxide (IGZO) and bi-layer IGZO/ZnO (ZnO: zinc oxide) memristors were investigated for synapse application

  • The arrows “1” and “2” in the figure are referred to as “SET,” and they indicate that the resistive switching (RS) behaviors of the single IGZO and bi-layer IGZO/ZnO memristors change from high-resistance state (HRS) to low-resistance state (LRS)

  • The process of changing from arrow “3” to “4” in the figure is called “RESET,” and it means that the RS behaviors of the single IGZO and bi-layer IGZO/ ZnO memristors change from LRS to HRS

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Summary

Introduction

The electrical properties, resistive switching behavior, and long-term potentiation/depression (LTP/ LTD) in a single indium-gallium-zinc-oxide (IGZO) and bi-layer IGZO/ZnO (ZnO: zinc oxide) memristors were investigated for synapse application. The set voltage of bi-layer IGZO/ZnO memristors was 0.9 V, and the reset voltage was around − 0.7 V, resulting in a low-operating voltage for neuromorphic systems. The potentiation and depression characteristics of single-layer memristor devices are frequently nonlinear, resulting in less efficient neural network processing. The use of oxide bi-layers improved electrical properties such as stability, memristor reliability, and an increase in synaptic weight s­ tates[26,27,28]. This paper proposed bi-layer IGZO/ZnO memristors to improve the electrical characteristics and synaptic linearity in long-term potentiation/depression (LTP/LTD) characteristics compared with a single IGZO memristor. The high linearity in LTP/ LTD characteristics of the bi-layer IGZO/ZnO memristors is more linear than that of other reported ­devices[29,30,31,32]

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