ZIF-67 blended PVDF membrane for improved Congo red removal and antifouling properties: A correlation establishment between morphological features and ultra-filtration parameters

Abstract

Dye effluents from various sectors have constantly imperilled the environment and ecosystem. Nano-composite membrane technology incorporating metal-organic frameworks (MOFs) has shown tremendous potential for toxic pollutant remediation. This study details the impact of ZIF-67 MOF nanoparticles on the structural properties of polyvinylidene fluoride (PVDF) ultrafiltration membrane during the non-solvent induced phase separation (NIPS) process. In order to outline the properties that determine the performance parameters in a MOF-modified mixed matrix membrane, the corresponding changes in mean pore size (MPS), surface porosity, solvent viscosity, and hydrophilicity have been discussed with appropriate surface characterization analysis. The suitability of ZIF-67 as filler nanoparticles were established based on polymer compatibility, dispersibility, and water stability studies. The ZIF-67 incorporated PVDF mixed matrix membranes (MMM) showed 99.5% CR dye removal with 2.6 times DI water permeability than the neat. The flux recovery ratio (FRR) improved by 1.9 times and the membranes were found suitable for up to 5 filtration cycles. Based on the overall results, a correlation analysis between the MMM surface properties and membrane performance parameters were established to determine the key performance parameters. It was observed that in comparison to MPS, surface porosity was more correlated to Jd/Jw (r = 0.96) and FRR (r = 0.95).