Abstract

Abstract Spectral holes have been burned on the 0,0 fluorescence excitation (T0 → T1) line of 2-naphthylphenylcarbene in n-hexane at 1.8 K. A complicated spectrum of holes reflects zero-field splitting of both the triplet states, T0 and T1, and provides a way to estimate their splitting parameters D0, E0, D1 and E1. Comparison of the real hole burning spectrum with the simulated one suggests possibility of a distribution of burning yields and/or a distribution of homogeneous linewidths of 2-naphthylphenylcarbene molecules located in different sites of a Shpol'skii matrix.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.