Zeolite-Based Process for CO2 Capture from High-Pressure, Moderate-Temperature Gas Streams

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A novel CO2 capture process was developed using a zeolite suitable for CO2 removal at warm-gas temperatures in high-pressure coal gasification gas streams. The process involves sorption of CO2 at 150 °C and regeneration at 350 °C. Regeneration at 350 °C removes the moisture absorbed during CO2 sorption. This sorption temperature is ideal for CO2 removal downstream of the water gas shift reactor in an integrated gasification combined cycle (IGCC) power plant but is also applicable to other warm gas cleanup processes. Most solvent-based processes require energy-intensive drying to remove moisture prior to CO2 removal. Using zeolites for CO2 capture at 150 °C and regeneration at 350 °C eliminates the problem with moisture in the gas stream traditionally causing deactivation of the zeolite. The results of using this capture scheme in an IGCC power plant is advantageous because of the high-pressure CO2 product stream and because removal of CO2 and H2O from the syngas generates high-quality H2 for the combustio...