(Z)-3-(4-Chlorophenyl)-2-{[N-(2-formylphenyl)-4-methylbenzenesulfonamido]methyl}prop-2-enenitrile

D Kannan,M Bakthadoss,S Murugavel,R Madhanraj

doi:10.1107/s160053681105241x

D Kannan, M Bakthadoss + Show 2 more

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https://doi.org/10.1107/s160053681105241x

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Abstract

In the title compound, C24H19ClN2O3S, the sulfonyl-bound benzene ring forms dihedral angles of 38.1 (2) and 81.2 (1)°, respectively, with the formyl benzene and benzene rings. The molecular conformation is stabilized by a weak intramolecular C—H⋯O hydrogen bond, which generates an S(5) ring motif. The crystal packing is stabilized by C—H⋯O hydrogen bonds, which generate C(7) zigzag chains along [010] and R 3 3(19) ring motifs along [010]. The crystal packing is further stabilized by C—Cl⋯π interactions [Cl⋯centroid = 3.456 (2) Å and C—Cl⋯centroid = 173.4 (2)°].

Highlights

In the title compound, C24H19ClN2O3S, the sulfonyl-bound benzene ring forms dihedral angles of 38.1 (2) and 81.2 (1), respectively, with the formyl benzene and benzene rings
The molecular conformation is stabilized by a weak intramolecular
The crystal packing is stabilized by C—H O hydrogen bonds, which generate C(7) zigzag chains along [010] and

Summary

Bruker APEXII CCD diffractometer

Rint = 0.024 a Department of Physics, Ranipettai Engineering College, Thenkadapathangal, Walaja. 632 513, India, bDepartment of Physics, Thanthai Periyar Government Institute of Technology, Vellore 632 002, India, and cDepartment of Organic Chemistry, University of Madras, Maraimalai Campus, Chennai 600 025, India. R factor = 0.041; wR factor = 0.111; data-to-parameter ratio = 17.3. C24H19ClN2O3S, the sulfonyl-bound benzene ring forms dihedral angles of 38.1 (2) and 81.2 (1) , respectively, with the formyl benzene and benzene rings. The molecular conformation is stabilized by a weak intramolecular. C—H O hydrogen bond, which generates an S(5) ring motif. The crystal packing is stabilized by C—H O hydrogen bonds, which generate C(7) zigzag chains along [010] and. The crystal packing is further stabilized by C—Cl interactions [Cl centroid =. 3.456 (2) Å and C—Cl centroid = 173.4 (2) ]

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