Abstract
In the title compound, C22H26N4S, the dihedral angles formed by the triazole ring with the two benzene rings are 87.51 (3) and 20.98 (3)°. The benzene rings are inclined at 71.88 (2)°. An intramolecular C—H⋯S hydrogen bond generates an S(6) ring motif. The crystal packing is strengthened by intermolecular N—H⋯S hydrogen bonding and π–π stacking interactions between the triazole and benzene rings, with a centroid–centroid distance of 3.6618 (5) Å, together with N⋯N [2.1299 (9)–2.2121 (9) Å] short contacts and C—H⋯π interactions. In the crystal packing, molecules are stacked along the a axis.
Highlights
C22H26N4S, the dihedral angles formed by the triazole ring with the two benzene rings are 87.51 (3)
The crystal packing is strengthened by intermolecular N—H S hydrogen bonding and – stacking interactions between the triazole and benzene rings, with a centroid–centroid distance of 3.6618 (5) Å, together with
H atoms treated by a mixture of independent and constrained refinement max = 0.62 e Å3
Summary
R factor = 0.038; wR factor = 0.110; data-to-parameter ratio = 34.1. C22H26N4S, the dihedral angles formed by the triazole ring with the two benzene rings are 87.51 (3). The benzene rings are inclined at 71.88 (2). The crystal packing is strengthened by intermolecular N—H S hydrogen bonding and – stacking interactions between the triazole and benzene rings, with a centroid–centroid distance of 3.6618 (5) Å, together with. Molecules are stacked along the a axis
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