Abstract
XAFS of atomic, clustered, and solid krypton is reported in the Kr(2p) regime (1660–1760 eV) using monochromatized synchrotron radiation. Spectral features are observed in the near-edge regime corresponding to low lying exciton states in clusters and in the solid. These are characteristically blueshifted by 0.5 eV compared to the atomic Rydberg states. Additional features in the Kr(2p) continuum are assigned to EXAFS oscillations, which are analyzed with FEFF6 calculations.
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