Abstract
Colloidal-sized hematite spheroids exposed to aqueous NaCl solutions were investigated by X-ray photoelectron spectroscopy using the fast-frozen technique. The O1s region provided evidence for (de)protonation reactions of surface (hydr)oxo groups of OH-enriched/O-depleted hematite surfaces. These results were also correlated to changes in sodium (Na 1s) and chloride (Cl 2p) contents with pH. Electrolyte ion surface loadings were successfully predicted using a classic thermodynamic adsorption model normalized for surface site density. These efforts pointed to ion-specific inner-Helmholtz plane capacitances.
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