Abstract
The experimental K β 5 and L α emission spectra for vanadium and K α spectra for nonmetal are studied for vanadium monoxide, nitride and carbide. Using the spectra unfolding the experimental molecular orbital diagrams have been obtained. By the semiempirical Mulliken-Wolfsberg-Helmholz method with the self-consistency on charges and configurations the calculations of electronic structure of clusters [VO 6] 10−, [VN 6] 15− and [VC 6] 20− have been carried out. The results of calculations are compared with the X-ray data. The effects of chemical bonding and charge densities on metal atoms in VO, VN, VC are discussed.
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